The Fluorine Gauche Effect: A Brief History

The influence of electronic perturbations on the Sulfur–Fluorine Gauche Effect

(2016) Christian Thiehoff et al.   JOURNAL OF FLUORINE CHEMISTRY

Catalytic Difluorination of Olefins

(2016) István Gábor Molnár et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic, Diastereoselective 1,2-Difluorination of Alkenes

(2016) Steven M. Banik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalysis Intermediates as Platforms to Study Noncovalent Interactions: Integrating Fluorine Gauche Effects in Iminium Systems to Facilitate Acyclic Conformational Control

(2016) Ryan Gilmour et al.   SYNLETT

Catalytic, Stereoselective Dihalogenation of Alkenes: Challenges and Opportunities

(2015) Alexander J. Cresswell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Origin of Fluorine/Sulfur Gauche Effect of β-Fluorinated Thiol, Sulfoxide, Sulfone, and Thionium Ion

(2015) Jovana Aleksić et al.   JOURNAL OF ORGANIC CHEMISTRY

All-cis 1,2,3,4,5,6-hexafluorocyclohexane is a facially polarized cyclohexane

(2015) Neil S. Keddie et al.   Nature Chemistry

A Janus cyclohexane ring

(2015) Nico Santschi et al.   Nature Chemistry

Can acyclic conformational control be achieved via a sulfur–fluorine gauche effect?

(2015) C. Thiehoff et al.   Chemical Science

Translating the Enantioselective Michael Reaction to a Continuous Flow Paradigm with an Immobilized, Fluorinated Organocatalyst

(2015) Irina Sagamanova et al.   ACS Catalysis

A Computational Study of Vicinal Fluorination in 2,3-Difluorobutane: Implications for Conformational Control in Alkane Chains

(2014) Stephen J. Fox et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molecular Design Exploiting a FluorinegaucheEffect as a Stereoelectronic Trigger

(2014) Yannick P. Rey et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Gauche preference in 1,2-difluoroethane originates from both orbital and electrostatic stabilization interactions

(2014) Marija Baranac-Stojanović   RSC Advances

Modulating NHC catalysis with fluorine

(2013) Yannick P Rey et al.   Beilstein Journal of Organic Chemistry

The influence of fluorine in asymmetric catalysis

(2013) Dominique Cahard et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Aziridination of Cyclic Enals Facilitated by the Fluorine-Iminium IonGaucheEffect

(2013) István Gábor Molnár et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sequential Deoxyfluorination Approach for the Synthesis of Protected α,β,γ-Trifluoro-δ-amino Acids

(2013) Raju Cheerlavancha et al.   ORGANIC LETTERS

The fluorine-NHC gauche effect: a structural and computational study

(2013) Susann Paul et al.   TETRAHEDRON

1,2-Difluoroethane: the angular dependance on 1JCF coupling constants is independent of hyperconjugation

(2012) Matheus P. Freitas et al.   CHEMICAL COMMUNICATIONS

Fluorinated Organocatalysts for the Enantioselective Epoxidation of Enals: Molecular Preorganisation by the Fluorine-Iminium Ion Gauche Effect

(2012) Eva-Maria Tanzer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Designing Fluorinated Cinchona Alkaloids for Enantioselective Catalysis: Controlling Internal Rotation by a Fluorine-Ammonium Ion gauche Effect (φNCCF)

(2012) Eva-Maria Tanzer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organofluorine Chemistry: Synthesis and Conformation of Vicinal Fluoromethylene Motifs

(2012) David O’Hagan   JOURNAL OF ORGANIC CHEMISTRY

Fluorine Conformational Effects in Organocatalysis: An Emerging Strategy for Molecular Design

(2011) Lucie E. Zimmer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The enantiomers of syn-2,3-difluoro-4-aminobutyric acid elicit opposite responses at the GABACreceptor

(2011) Izumi Yamamoto et al.   CHEMICAL COMMUNICATIONS

Theoretical and X-ray Crystallographic Evidence of a Fluorine-Imine Gauche Effect: An Addendum to Dunathan’s Stereoelectronic Hypothesis

(2011) Christof Sparr et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fluoro-Organocatalysts: Conformer Equivalents as a Tool for Mechanistic Studies

(2010) Christof Sparr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The C–F bond as a conformational tool in organic and biological chemistry

(2010) Luke Hunter   Beilstein Journal of Organic Chemistry

Fluorosugars: synthesis of the 2,3,4-trideoxy-2,3,4-trifluoro hexose analogues of d-glucose and d-altrose and assessment of their erythrocyte transmembrane transport

(2010) Stefano Bresciani et al.   CHEMICAL COMMUNICATIONS

A DFT study on the origin of the fluorine gauche effect in substituted fluoroethanes

(2010) David Y. Buissonneaud et al.   TETRAHEDRON

Synthesis and Structure of Stereoisomeric Multivicinal Hexafluoroalkanes

(2009) Luke Hunter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Fluorine-Iminium IonGaucheEffect: Proof of Principle and Application to Asymmetric Organocatalysis

(2009) Christof Sparr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Three step synthesis of single diastereoisomers of the vicinal trifluoro motif

(2009) Vincent A Brunet et al.   Beilstein Journal of Organic Chemistry

Fluorinated Quinine Alkaloids: Synthesis, X-ray Structure Analysis and Antimalarial Parasite Chemotherapy

(2009) Christoph Bucher et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diastereoselective Synthesis of 2,3,4,5,6-Pentafluoroheptanes

(2009) Daniel Farran et al.   JOURNAL OF ORGANIC CHEMISTRY

The multi-vicinal fluoroalkane motif: an examination of 2,3,4,5-tetrafluorohexane stereoisomers

(2008) Luke Hunter et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Multi-vicinal fluoroalkanes: a new class of organofluorine compounds

(2008) Luke Hunter et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS