Copper‐Catalyzed Intermolecular Enantioselective Radical Oxidative C(sp 3 )−H/C(sp)−H Cross‐Coupling with Rationally Designed Oxazoline‐Derived N,N,P(O)‐Ligands

Catalytic enantioselective C(sp3)–H functionalization involving radical intermediates

(2021) Chi Zhang et al.   Nature Communications

Hydrogen Atom Transfer-Driven Enantioselective Minisci Reaction of Amides

(2021) Rupert S. J. Proctor et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of Vicinal Quaternary Carbon Stereocenters Through Diastereo‐ and Enantioselective Oxidative 1,6‐Conjugate Addition

(2021) Xigong Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Further Developments and Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis

(2021) Robert Connon et al.   CHEMICAL REVIEWS

Synthesis of Chiral Triarylmethanes Bearing All-Carbon Quaternary Stereocenters: Catalytic Asymmetric Oxidative Cross-Coupling of 2,2-Diarylacetonitriles and (Hetero)arenes

(2020) Zehua Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalysed benzylic C–H coupling with alcohols via radical relay enabled by redox buffering

(2020) Huayou Hu et al.   Nature Catalysis

Intermolecular Radical C–H Bond Activation: A Powerful Tool for Late Stage Functionalization

(2020) Fabrice Dénès   CHIMIA

Copper-Catalyzed Asymmetric Radical 1,2-Carboalkynylation of Alkenes with Alkyl Halides and Terminal Alkynes

(2020) Xiao-Yang Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)–H trifluoromethylation

(2020) Patrick J. Sarver et al.   Nature Chemistry

Late-Stage Diversification of Natural Products

(2020) Benke Hong et al.   ACS Central Science

Cu-catalysed intramolecular radical enantioconvergent tertiary β-C(sp3)–H amination of racemic ketones

(2020) Chang-Jiang Yang et al.   Nature Catalysis

Photoinduced Copper‐Catalyzed Asymmetric Decarboxylative Alkynylation with Terminal Alkynes

(2020) Hai-Dong Xia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper-Catalyzed Alkynylation of Benzylic C–H Bonds via Radical Relay

(2020) Liang Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Copper-Catalyzed Azidation of Benzylic C–H Bonds

(2020) Sung-Eun Suh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Late-Stage Functionalization

(2020) Jonas Börgel et al.   Chem

Copper‐Catalyzed Asymmetric Coupling of Allenyl Radicals with Terminal Alkynes to Access Tetrasubstituted Allenes

(2020) Xiao-Yang Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Three-Coordinate Copper(II) Alkynyl Complex in C–C Bond Formation: The Sesquicentennial of the Glaser Coupling

(2020) Abolghasem Bakhoda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Intermolecular Radical C–H Amination

(2020) Li-Mei Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Radical-Involved Alkynylation of Unactivated C(sp3)–H Bonds by Hydrogen Atom Abstraction

(2020) Zheng-Hua Zhang et al.   SYNLETT

Pd(II)-Catalyzed Enantioselective Alkynylation of Unbiased Methylene C(sp3)–H Bonds Using 3,3′-Fluorinated-BINOL as a Chiral Ligand

(2019) Ye-Qiang Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Arylation of Benzylic C-H bonds via Copper-Catalyzed Radical Relay

(2019) Guosheng Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral acid-catalysed enantioselective C−H functionalization of toluene and its derivatives driven by visible light

(2019) Fuyuan Li et al.   Nature Communications

Identifying Amidyl Radicals for Intermolecular C–H Functionalizations

(2019) Matthew M. Tierney et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper(I)-Catalyzed Asymmetric Reactions Involving Radicals

(2019) Qiang-Shuai Gu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Copper(I)/Chiral Phosphoric Acid Catalyzed Intramolecular Amination of Allylic and Benzylic C−H Bonds

(2019) Liu Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-specific allylic C–H bond functionalization with a copper-bound N-centred radical

(2019) Jiayuan Li et al.   NATURE

A general asymmetric copper-catalysed Sonogashira C(sp3)–C(sp) coupling

(2019) Xiao-Yang Dong et al.   Nature Chemistry

Enantioselective benzylic C–H arylation via photoredox and nickel dual catalysis

(2019) Xiaokai Cheng et al.   Nature Communications

Photocatalytic regio- and stereoselective C(sp3)–H functionalization of benzylic and allylic hydrocarbons as well as unactivated alkanes

(2019) Yanjun Li et al.   Nature Catalysis

Direct Decarboxylative Functionalization of Carboxylic Acids via O–H Hydrogen Atom Transfer

(2019) Christina G. Na et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed enantioselective Sonogashira-type oxidative cross-coupling of unactivated C(sp3)−H bonds with alkynes

(2019) Zhen-Hua Zhang et al.   Nature Communications

Copper-Catalyzed Allylic C−H Alkynylation by Cross-Dehydrogenative Coupling

(2018) Ahmad A. Almasalma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Multi-Metal-Catalyzed Oxidative Radical Alkynylation with Terminal Alkynes: A New Strategy for C(sp3)–C(sp) Bond Formation

(2018) Shan Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(Guanidine)copper Complex-Catalyzed Enantioselective Dynamic Kinetic Allylic Alkynylation under Biphasic Condition

(2018) Xi-Yang Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese-catalysed benzylic C(sp3)–H amination for late-stage functionalization

(2018) Joseph R. Clark et al.   Nature Chemistry

Enantioselective C(sp3)‒H bond activation by chiral transition metal catalysts

(2018) Tyler G. Saint-Denis et al.   SCIENCE

Copper-Catalyzed Radical Relay for Asymmetric Radical Transformations

(2018) Fei Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Quest for Selectivity in Hydrogen Atom Transfer Based Aliphatic C–H Bond Oxygenation

(2018) Michela Milan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Allylic C–H Alkylation via Palladium(II)/cis-ArSOX Catalysis

(2018) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis

(2018) Anhua Hu et al.   SCIENCE

Site-selective and stereoselective functionalization of non-activated tertiary C–H bonds

(2017) Kuangbiao Liao et al.   NATURE

Formation of α-chiral centers by asymmetric β-C(sp 3 )–H arylation, alkenylation, and alkynylation

(2017) Qing-Feng Wu et al.   SCIENCE

Asymmetric Aerobic Oxidative Cross-Coupling of Tetrahydroisoquinolines with Alkynes

(2017) Tianyu Huang et al.   ACS Catalysis

Enantioselective Allylic C−H Oxidation of Terminal Olefins to Isochromans by Palladium(II)/Chiral Sulfoxide Catalysis

(2016) Stephen E. Ammann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Aerobic Enantioselective Cross-Dehydrogenative Coupling of N-Aryl Glycine Esters with Terminal Alkynes

(2016) Zhiyu Xie et al.   ORGANIC LETTERS

Enantioselective cyanation of benzylic C–H bonds via copper-catalyzed radical relay

(2016) Wen Zhang et al.   SCIENCE

Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes

(2016) Shan Tang et al.   Nature Communications

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

(2016) John F. Hartwig et al.   ACS Central Science

Direct Catalytic Enantio- and Diastereoselective Ketone Aldol Reactions of Isocyanoacetates

(2015) Raquel de la Campa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Catalytic Cross-Dehydrogenative Coupling of N-Carbamoyl Tetrahydroisoquinolines and Terminal Alkynes

(2015) Shutao Sun et al.   ORGANIC LETTERS

Direct Catalytic Enantio- and Diastereoselective Mannich Reaction of Isocyanoacetates and Ketimines

(2014) Irene Ortín et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Practical and Highly Selective CH Functionalization of Structurally Diverse Ethers

(2014) Miao Wan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective Aliphatic C–H Bromination Using N-Bromoamides and Visible Light

(2014) Valerie A. Schmidt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles

(2014) Ayumi Harada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Observation of Reduction of Cu(II) to Cu(I) by Terminal Alkynes

(2014) Guanghui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed γ-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes

(2013) Yusuke Makida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photo-Induced Sonogashira CC Coupling Reaction Catalyzed by Simple Copper(I) Chloride Salt at Room Temperature

(2012) Arunachalam Sagadevan et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Regioselective Copper-Catalyzed Benzylic CH Amination by N-Fluorobenzenesulfonimide

(2011) Zhikun Ni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective functionalisation of saturated C–H bonds with metalloporphyrin catalysts

(2011) Chi-Ming Che et al.   CHEMICAL SOCIETY REVIEWS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

A New Family of Cinchona-Derived Amino Phosphine Precatalysts: Application to the Highly Enantio- and Diastereoselective Silver-Catalyzed Isocyanoacetate Aldol Reaction

(2011) Filippo Sladojevich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sub-Mol % Catalyst Loading and Ligand-Acceleration in the Copper-Catalyzed Coupling of Aryl Iodides and Terminal Alkyenes

(2010) Erik Zuidema et al.   CHEMISTRY-A EUROPEAN JOURNAL

SN2-Selective allylic substitution of chiral γ-aryl substituted allylic picolinates with alkynylcopper reagents

(2010) Qian Wang et al.   TETRAHEDRON LETTERS

Mechanisms of Mn(OAc)3-based oxidative free-radical additions and cyclizations

(2009) Barry B. Snider   TETRAHEDRON

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Substitution Reaction of Aryl Fluorides with Disulfides:p-Orientation in the Polyarylthiolation of Polyfluorobenzenes

(2008) Mieko Arisawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY