Enantioselective Synthesis of Silicon‐Stereogenic Monohydrosilanes by Rhodium‐Catalyzed Intramolecular Hydrosilylation

Asymmetric Synthesis of Silicon-Stereogenic Monohydrosilanes by Dehydrogenative C–H Silylation

(2021) Wei Yuan et al.   ORGANIC LETTERS

Enantioselective construction of six- and seven-membered triorgano-substituted silicon-stereogenic heterocycles

(2021) Shuyou Chen et al.   Nature Communications

Catalytic Enantioselective Dehydrogenative Si–O Coupling to Access Chiroptical Silicon-Stereogenic Siloxanes and Alkoxysilanes

(2021) Jiefeng Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis and Application of Chiral Spirosilabiindanes

(2020) Xin Chang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Silicon‐Stereogenic Silanes by Copper‐Catalyzed Desymmetrizing Protoboration of Vinylsilanes

(2020) Ge Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed enantioselective desymmetrization of prochiral tetrasubstituted siladiols: Access toward optically active silicon-stereogenic silylmethanols

(2020) Qing Wang et al.   CATALYSIS COMMUNICATIONS

Enantioselective Si–H Insertion Reactions of Diarylcarbenes for the Synthesis of Silicon-Stereogenic Silanes

(2020) Jake R. Jagannathan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Streamlined Construction of Silicon-Stereogenic Silanes by Tandem Enantioselective C–H Silylation/Alkene Hydrosilylation

(2020) Delong Mu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric trans-Selective Hydrosilylation of Bisalkynes to Access AIE and CPL-Active Silicon-Stereogenic Benzosiloles

(2020) Ren-He Tang et al.   iScience

Enantioselective Silylation of Aliphatic C−H Bonds for the Synthesis of Silicon‐Stereogenic Dihydrobenzosiloles

(2020) Bo Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Construction of Si‐Stereogenic Center via Rhodium‐Catalyzed Intermolecular Hydrosilylation of Alkene

(2020) Wei He et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium‐Catalyzed Synthesis of Chiral Monohydrosilanes by Intramolecular C−H Functionalization of Dihydrosilanes

(2020) Wenpeng Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Reaction of Silacyclobutanes with Unactivated Alkynes to Afford Silacyclohexenes

(2019) Hua Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Desymmetrization‐Oriented Enantioselective Synthesis of Silicon‐Stereogenic Silanes by Palladium‐Catalyzed C−H Olefinations

(2019) Yan Lin et al.   Chemistry-An Asian Journal

Enantioselective Rhodium-Catalyzed Desymmetric Hydrosilylation of Cyclopropenes

(2019) Zhi-Yuan Zhao et al.   ACS Catalysis

Asymmetric Synthesis of Silicon-Stereogenic Vinylhydrosilanes by Cobalt-Catalyzed Regio- and Enantioselective Alkyne Hydrosilylation with Dihydrosilanes

(2018) Huanan Wen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Construction of Silicon-Stereogenic Silanes by Scandium-Catalyzed Intermolecular Alkene Hydrosilylation

(2018) Gu Zhan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to Chiral Silicon Centers for Application to Circularly Polarized Luminescence Materials

(2017) Shinya Koga et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent Progress in Catalytic Enantioselective Desymmetrization of Prochiral Organosilanes for the Synthesis of Silicon-Stereogenic Compounds

(2017) Ryo Shintani   SYNLETT

Enantioselective Synthesis of Silacyclopentanes

(2016) Kazunobu Igawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Chiral Tetraorganosilicons by Tandem Desymmetrization of Silacyclobutanes/Intermolecular Dehydrogenative Silylation

(2016) Qing-Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silicon-Containing Amino Acids: Synthetic Aspects, Conformational Studies, and Applications to Bioactive Peptides

(2016) Emmanuelle Rémond et al.   CHEMICAL REVIEWS

Planar Chiral, Ferrocene-Stabilized Silicon Cations

(2016) Ruth K. Schmidt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Synthesis of Chiral Spiro-9-silabifluorenes by Dehydrogenative Silylation: Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters

(2016) Masahito Murai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Progress in Asymmetric Synthesis and Application of Difunctionalized Silicon-Stereogenic Silanes

(2016) Jonathan O. Bauer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic silicon-bridged arylpyridinones

(2016) Ryo Shintani et al.   Chemical Science

Construction of a Chiral Silicon Center by Rhodium-Catalyzed Enantioselective Intramolecular Hydrosilylation

(2015) Yuki Naganawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel(0)-Catalyzed Enantio- and Diastereoselective Synthesis of Benzoxasiloles: Ligand-Controlled Switching from Inter- to Intramolecular Aryl-Transfer Process

(2015) Ravindra Kumar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in C–Si bond activation via a direct transition metal insertion

(2015) Linjie Li et al.   TETRAHEDRON LETTERS

Recent Advances in the Transition-Metal-Catalyzed Enantioselective Synthesis of Silicon-Stereogenic Organosilanes

(2015) Ryo Shintani   Asian Journal of Organic Chemistry

Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles by Enantioselective [2+2+2] Cycloaddition

(2014) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insight into the Mechanism of Carbonyl Hydrosilylation Catalyzed by Brookhart’s Cationic Iridium(III) Pincer Complex

(2014) Toni T. Metsänen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric Synthesis of Spirosilabifluorene Derivatives

(2012) Yoichiro Kuninobu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Synthesis of Alkenylhydrosilanes

(2012) Kazunobu Igawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of optically active tertiary silanes via Pd-catalyzed enantioselective arylation of secondary silanes

(2012) Yu Kurihara et al.   CHEMICAL COMMUNICATIONS

Organosilicon Molecules with Medicinal Applications

(2012) Annaliese K. Franz et al.   JOURNAL OF MEDICINAL CHEMISTRY

Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C–H Bond Functionalization

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzooxasilines via Enantioselective Transmetalation

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Carbon–Silicon Bond Activation for Synthesis of Benzosilole Derivatives

(2012) Masahiro Onoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Desymmetrization of Silacyclobutanes with Alkynes: Enantioselective Synthesis of Silicon-Stereogenic 1-Sila-2-cyclohexenes and Mechanistic Considerations

(2012) Ryo Shintani et al.   ORGANIC LETTERS

Palladium-Catalyzed Enantioselective Desymmetrization of Silacyclobutanes: Construction of Silacycles Possessing a Tetraorganosilicon Stereocenter

(2011) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantioselective dehydrogenative Si–O coupling of oxime ether-functionalized alcohols

(2011) Andreas Weickgenannt et al.   TETRAHEDRON

The recent synthesis and application of silicon-stereogenic silanes: A renewed and significant challenge in asymmetric synthesis

(2010) Li-Wen Xu et al.   CHEMICAL SOCIETY REVIEWS

Iridium(III)-Catalyzed Enantioselective Si−H Bond Insertion and Formation of an Enantioenriched Silicon Center

(2010) Yoichi Yasutomi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Chiral Silacarboxylic Acids and Their Ester Derivatives

(2009) Kazunobu Igawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile preparation of CF3-substituted carbinols with an azine donor and subsequent kinetic resolution through stereoselective Si–O coupling

(2009) Anne Steves et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Control of stereochemical structures of silicon-containing polymeric systems

(2009) Yusuke Kawakami et al.   POLYMER INTERNATIONAL

Conjugate phosphination of cyclic and acyclic acceptors using Rh(I)–phosphine or Rh(I)–carbene complexes. Probing the mechanism with chirality at the silicon atom or the phosphorus atom of the Si–P reagent

(2009) Verena T. Trepohl et al.   TETRAHEDRON

Stereoselective Alcohol Silylation by Dehydrogenative Si-O Coupling: Scope, Limitations, and Mechanism of the Cu-H-Catalyzed Non-Enzymatic Kinetic Resolution with Silicon-Stereogenic Silanes

(2008) Sebastian Rendler et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantio- and Diastereotopos Differentiation in the Palladium(II)-Catalyzed Hydrosilylation of Bicyclo[2.2.1]alkene Scaffolds with Silicon-Stereogenic Silanes

(2008) Sebastian Rendler et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of Silanol

(2008) Kazunobu Igawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane

(2008) Betül Karatas et al.   ORGANIC & BIOMOLECULAR CHEMISTRY