Desymmetrization‐Oriented Enantioselective Synthesis of Silicon‐Stereogenic Silanes by Palladium‐Catalyzed C−H Olefinations

Asymmetric Synthesis of Silicon-Stereogenic Vinylhydrosilanes by Cobalt-Catalyzed Regio- and Enantioselective Alkyne Hydrosilylation with Dihydrosilanes

(2018) Huanan Wen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Enantioselective C−H Olefination of Diaryl Sulfoxides through Parallel Kinetic Resolution and Desymmetrization

(2018) Yu-Chao Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective C(sp3)‒H bond activation by chiral transition metal catalysts

(2018) Tyler G. Saint-Denis et al.   SCIENCE

Enantioselective Construction of Silicon-Stereogenic Silanes by Scandium-Catalyzed Intermolecular Alkene Hydrosilylation

(2018) Gu Zhan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to Chiral Silicon Centers for Application to Circularly Polarized Luminescence Materials

(2017) Shinya Koga et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent Progress in Catalytic Enantioselective Desymmetrization of Prochiral Organosilanes for the Synthesis of Silicon-Stereogenic Compounds

(2017) Ryo Shintani   SYNLETT

Synthesis of Stereoselectively Functionalized Silacyclopentanes

(2017) Kazunobu Igawa et al.   SYNLETT

Enantioselective Synthesis of Silacyclopentanes

(2016) Kazunobu Igawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Chiral Tetraorganosilicons by Tandem Desymmetrization of Silacyclobutanes/Intermolecular Dehydrogenative Silylation

(2016) Qing-Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Synthesis of Chiral Spiro-9-silabifluorenes by Dehydrogenative Silylation: Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters

(2016) Masahito Murai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Progress in Asymmetric Synthesis and Application of Difunctionalized Silicon-Stereogenic Silanes

(2016) Jonathan O. Bauer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Ligand-Promoted Meta-C–H Arylation of Anilines, Phenols, and Heterocycles

(2016) Peng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes

(2016) Jun Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic silicon-bridged arylpyridinones

(2016) Ryo Shintani et al.   Chemical Science

A Constellation of Deuterium-Labeled Silanes as a Simple Mechanistic Probe not Requiring Absolute Configuration Determination

(2015) Thomas Fallon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General Method for the Synthesis of Salicylic Acids from Phenols through Palladium-Catalyzed Silanol-Directed CH Carboxylation

(2015) Yang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of a Chiral Silicon Center by Rhodium-Catalyzed Enantioselective Intramolecular Hydrosilylation

(2015) Yuki Naganawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Oxirane-Opening Reaction with Arenes via C–H Bond Activation

(2015) Zhen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel(0)-Catalyzed Enantio- and Diastereoselective Synthesis of Benzoxasiloles: Ligand-Controlled Switching from Inter- to Intramolecular Aryl-Transfer Process

(2015) Ravindra Kumar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereocontrol in Nucleophilic Substitution Reactions at Silicon: The Role of Permutation in Generating Silicon-Centered Chirality

(2015) Jonathan O. Bauer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Enantioselective Synthesis of P-Stereogenic Phosphinamides via Desymmetric C–H Arylation

(2015) Zhi-Jun Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Complete Switch of Selectivity in the C–H Alkenylation and Hydroarylation Catalyzed by Iridium: The Role of Directing Groups

(2015) Jiyu Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in the Transition-Metal-Catalyzed Enantioselective Synthesis of Silicon-Stereogenic Organosilanes

(2015) Ryo Shintani   Asian Journal of Organic Chemistry

Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles by Enantioselective [2+2+2] Cycloaddition

(2014) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From an α-Functionalized Silicon-Stereogenic N,O-Silane to a Monomeric and TetracoordinatetBuLi Adduct with Lithium-Centered Chirality

(2014) Jonathan O. Bauer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes

(2014) Jun Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Synthesis of Silicon-Stereogenic Aminomethoxysilanes: Easy Access to Highly Enantiomerically Enriched Siloxanes

(2013) Jonathan O. Bauer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Synthesis of Functional Silicon-Stereogenic Silanes throughCandida antarcticaLipase B Catalyzed Remote Desymmetrization of Silicon-Centered Diols

(2013) Xing Lu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Recent development of direct asymmetric functionalization of inert C–H bonds

(2013) Chao Zheng et al.   RSC Advances

Desymmetrization Catalyzed by Transition-Metal Complexes: Enantioselective Formation of Silicon-Stereogenic Silanes

(2012) Li-Wen Xu   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Synthesis of Spirosilabifluorene Derivatives

(2012) Yoichiro Kuninobu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Synthesis of Alkenylhydrosilanes

(2012) Kazunobu Igawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of optically active tertiary silanes via Pd-catalyzed enantioselective arylation of secondary silanes

(2012) Yu Kurihara et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C–H Bond Functionalization

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzooxasilines via Enantioselective Transmetalation

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Carbon–Silicon Bond Activation for Synthesis of Benzosilole Derivatives

(2012) Masahiro Onoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Desymmetrization of Silacyclobutanes with Alkynes: Enantioselective Synthesis of Silicon-Stereogenic 1-Sila-2-cyclohexenes and Mechanistic Considerations

(2012) Ryo Shintani et al.   ORGANIC LETTERS

PdII-Catalyzed CH Olefination of N-(2-Pyridyl)sulfonyl Anilines and Arylalkylamines

(2011) Alfonso García-Rubia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conformational aspects in the studies of organic compounds by electronic circular dichroism

(2011) Gennaro Pescitelli et al.   CHEMICAL SOCIETY REVIEWS

Ligand-Promoted C-3 Selective C–H Olefination of Pyridines with Pd Catalysts

(2011) Mengchun Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Enantioselective Desymmetrization of Silacyclobutanes: Construction of Silacycles Possessing a Tetraorganosilicon Stereocenter

(2011) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silanol: A Traceless Directing Group for Pd-Catalyzedo-Alkenylation of Phenols

(2011) Chunhui Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The recent synthesis and application of silicon-stereogenic silanes: A renewed and significant challenge in asymmetric synthesis

(2010) Li-Wen Xu et al.   CHEMICAL SOCIETY REVIEWS

Thorpe–Ingold effect in organosilicon chemistry

(2010) Tien-Yau Luh et al.   DALTON TRANSACTIONS

PyDipSi: A General and Easily Modifiable/Traceless Si-Tethered Directing Group for C−H Acyloxylation of Arenes

(2010) Natalia Chernyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium(III)-Catalyzed Enantioselective Si−H Bond Insertion and Formation of an Enantioenriched Silicon Center

(2010) Yoichi Yasutomi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Si–O coupling of alcohols

(2010) Andreas Weickgenannt et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Synthesis of Chiral Silacarboxylic Acids and Their Ester Derivatives

(2009) Kazunobu Igawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

(2009) Ramesh Giri et al.   CHEMICAL SOCIETY REVIEWS

PdII-Catalyzed Enantioselective Activation of C(sp2)H and C(sp3)H Bonds Using Monoprotected Amino Acids as Chiral Ligands

(2008) Bing-Feng Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modular Approach to Silicon-Bridged Biaryls: Palladium-Catalyzed Intramolecular Coupling of 2-(Arylsilyl)aryl Triflates

(2008) Masaki Shimizu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION