Catalytic Hydrodefluorination via Oxidative Addition, Ligand Metathesis, and Reductive Elimination at Bi(I)/Bi(III) Centers

Main Group Redox Catalysis of Organopnictogens: Vertical Periodic Trends and Emerging Opportunities in Group 15

(2021) Jeffrey M. Lipshultz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen complexation and reduction at low-valent calcium

(2021) B. Rösch et al.   SCIENCE

Fluorination of arylboronic esters enabled by bismuth redox catalysis

(2020) Oriol Planas et al.   SCIENCE

Relativistic Heavy-Neighbor-Atom Effects on NMR Shifts: Concepts and Trends Across the Periodic Table

(2020) Jan Vı́cha et al.   CHEMICAL REVIEWS

Well‐defined, molecular bismuth compounds: catalysts in photochemically‐induced radical dehydrocoupling reactions

(2020) Jacqueline Ramler et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bismuth-Catalyzed Oxidative Coupling of Arylboronic Acids with Triflate and Nonaflate Salts

(2020) Oriol Planas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Probing the Limits of Oxidative Addition of C(sp3)–X Bonds toward Selected N,C,N-Chelated Bismuth(I) Compounds

(2020) Martin Hejda et al.   ORGANOMETALLICS

Round-Trip Oxidative Addition, Ligand Metathesis, and Reductive Elimination in a PIII/PV Synthetic Cycle

(2020) Soohyun Lim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative Bond Activation by a Bimetallic Main-Group Complex

(2020) Oleksandr Kysliak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frontiers in molecular p-block chemistry: From structure to reactivity

(2019) Rebecca L. Melen   SCIENCE

Bi(I)-Catalyzed Transfer-Hydrogenation with Ammonia-Borane

(2019) Feng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intermolecular Aryliodination of Internal Alkynes

(2019) Yong Ho Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex

(2019) Guocang Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reduction of Activated Alkenes by PIII /PV Redox Cycling Catalysis

(2019) Lars Longwitz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heavy Carbene Analogues: Donor-Free Bismuthenium and Stibenium Ions

(2018) Marian Olaru et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic oxidative coupling promoted by bismuth TEMPOxide complexes

(2018) R. J. Schwamm et al.   CHEMICAL COMMUNICATIONS

Oxidative Addition and Reductive Elimination at Main-Group Element Centers

(2018) Terry Chu et al.   CHEMICAL REVIEWS

Nitrogen fixation and reduction at boron

(2018) Marc-André Légaré et al.   SCIENCE

The Road Travelled: After Main-Group Elements as Transition Metals

(2018) Catherine Weetman et al.   ChemCatChem

Synthesis, structure and reaction chemistry of a nucleophilic aluminyl anion

(2018) Jamie Hicks et al.   NATURE

Intermolecular Reductive C–N Cross Coupling of Nitroarenes and Boronic Acids by PIII/PV═O Catalysis

(2018) Trevor V. Nykaza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mixed triorganobismuthines RAr2Bi [Ar = C6F5, 2,4,6-(C6F5)3C6H2] and hypervalent racemic Bi-chiral diorganobismuth(iii) bromides RArBiBr (Ar = C6F5, Mes, Ph) with the ligand R = 2-(Me2NCH2)C6H4. Influences of the organic substituent

(2016) Marian Olaru et al.   DALTON TRANSACTIONS

“π-Hole−π” Interaction Promoted Photocatalytic Hydrodefluorination via Inner-Sphere Electron Transfer

(2016) Jingzhi Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) Bond: An Equivalent of Grignard Formation in Solution

(2016) Clare Bakewell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mitsunobu Reactions Catalytic in Phosphine and a Fully Catalytic System

(2015) Joseph A. Buonomo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Branch-Selective Alkene Hydroarylation by Cooperative Destabilization: Iridium-Catalyzedortho-Alkylation of Acetanilides

(2015) Giacomo E. M. Crisenza et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative addition of carbon–fluorine and carbon–oxygen bonds to Al(i)

(2015) Mark R. Crimmin et al.   CHEMICAL COMMUNICATIONS

Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical

(2015) Steffen Styra et al.   CHEMISTRY-A EUROPEAN JOURNAL

From Dibismuthenes to Three- and Two-Coordinated Bismuthinidenes by Fine Ligand Tuning: Evidence for Aromatic BiC3N Rings through a Combined Experimental and Theoretical Study

(2015) Iva Vránová et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Phosphetane Catalyzes Deoxygenative Condensation of α-Keto Esters and Carboxylic Acids via PIII/PV═O Redox Cycling

(2015) Wei Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal-like Oxidative Addition of C–F and C–O Bonds to an Aluminum(I) Center

(2015) Terry Chu et al.   ORGANOMETALLICS

Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics

(2014) Sameera M. Senaweera et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–F Bond Hydrogenolysis of Fluoroaromatics by [(η5-C5Me5)RhI(2,2′-bipyridine)]

(2014) Hidetaka Nakai et al.   ORGANOMETALLICS

Carbon–fluorine bond cleavage in fluoroarenes via a niobium(iii) imido complex: from stoichiometric to catalytic hydrodefluorination

(2014) Thomas L. Gianetti et al.   Chemical Science

Catalytic Hydrodefluorination with Late Transition Metal Complexes

(2014) Michael K. Whittlesey et al.   ACS Catalysis

Copper-Catalyzed Hydrodefluorination of Fluoroarenes by Copper Hydride Intermediates

(2013) Hongbin Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-CatalyzedOrtho-Selective CF Activation of Polyfluoroarenes with Triethylsilane: A Facile Access to Partially Fluorinated Aromatics

(2013) Zhao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions

(2013) Moritz F. Kuehnel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selectively catalytic hydrodefluorination of perfluoroarenes by Co(PMe3)4 with sodium formate as reducing agent and mechanism study

(2013) Junye Li et al.   DALTON TRANSACTIONS

Oxidative Addition Versus Substitution Reactions of Group 14 Dialkylamino Metalylenes with Pentafluoropyridine

(2013) Prinson P. Samuel et al.   INORGANIC CHEMISTRY

Main-Group Lewis Acids for C–F Bond Activation

(2013) Timo Stahl et al.   ACS Catalysis

Catalytic C-F Bond Activation of Perfluoroarenes by Tricoordinated Gold(I) Complexes

(2012) Jin-Hui Zhan et al.   ADVANCED SYNTHESIS & CATALYSIS

Organophosphorus-Catalysed Staudinger Reduction

(2012) Henri A. van Kalkeren et al.   ADVANCED SYNTHESIS & CATALYSIS

Zirconocene Dichloride Catalyzed Hydrodefluorination of C sp 2F bonds

(2012) Shuhui Yow et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

π–π Interaction Assisted Hydrodefluorination of Perfluoroarenes by Gold Hydride: A Case of Synergistic Effect on C–F Bond Activation

(2012) Hongbin Lv et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main Group Redox Catalysis: Reversible PIII/PV Redox Cycling at a Phosphorus Platform

(2012) Nicole L. Dunn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decisive Steps of the Hydrodefluorination of Fluoroaromatics using [Ni(NHC)2]

(2012) Peter Fischer et al.   ORGANOMETALLICS

A highly active and selective palladium pincer catalyst for the formation of α-aryl ketones via cross-coupling

(2011) Alejandro Bugarin et al.   CHEMICAL COMMUNICATIONS

In Situ Phosphine Oxide Reduction: A Catalytic Appel Reaction

(2011) Henri A. van Kalkeren et al.   CHEMISTRY-A EUROPEAN JOURNAL

Monomeric Organoantimony(I) and Organobismuth(I) Compounds Stabilized by an NCN Chelating Ligand: Syntheses and Structures

(2010) Petr Šimon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluoropyridine

(2010) David Breyer et al.   DALTON TRANSACTIONS

Selective Aromatic C−F and C−H Bond Activation with Silylenes of Different Coordinate Silicon

(2010) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Ligand Electronic Effect on Reductive Elimination of Biphenyl fromcis-[Pt(Ph)2(diphosphine)] Complexes Bearing Electron-Poor Diphosphine: Correlation Study between Experimental and Theoretical Results

(2010) Toshinobu Korenaga et al.   ORGANOMETALLICS

Recycling the Waste: The Development of a Catalytic Wittig Reaction

(2009) Christopher J. O'Brien et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Hydrodefluorination of Aromatic Fluorocarbons by Ruthenium N-Heterocyclic Carbene Complexes

(2009) Steven P. Reade et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhancement of Reaction Efficiency by Functionalized Alcohols on Gold(I)-Catalyzed Intermolecular Hydroalkoxylation of Unactivated Olefins

(2009) Toshifumi Hirai et al.   ORGANIC LETTERS

Molecular Single-Bond Covalent Radii for Elements 1-118

(2008) Pekka Pyykkö et al.   CHEMISTRY-A EUROPEAN JOURNAL

C−F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations

(2008) Thomas Schaub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Nickel(II) and Palladium(II) NCN-Pincer Complexes Based on Substituted Benzene: Synthesis, Structure, and Lewis Acidity

(2008) Alejandro Bugarin et al.   ORGANOMETALLICS