Carbon–fluorine bond cleavage in fluoroarenes via a niobium(iii) imido complex: from stoichiometric to catalytic hydrodefluorination

Copper-Catalyzed Hydrodefluorination of Fluoroarenes by Copper Hydride Intermediates

(2013) Hongbin Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Solvent dependent reductive defluorination of aliphatic C–F bonds employing Sm(HMDS)2

(2013) Mario Janjetovic et al.   CHEMICAL COMMUNICATIONS

Group 5 Imides and Bis(imide)s as Selective Hydrogenation Catalysts

(2013) Thomas L. Gianetti et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Vanadium Bisimide Bonding Investigated by X-ray Crystallography, 51V and 13C Nuclear Magnetic Resonance Spectroscopy, and V L3,2-Edge X-ray Absorption Near-Edge Structure Spectroscopy

(2013) Henry S. La Pierre et al.   INORGANIC CHEMISTRY

Diniobium Inverted Sandwich Complexes with μ-η6:η6-Arene Ligands: Synthesis, Kinetics of Formation, and Electronic Structure

(2013) Thomas L. Gianetti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Arene–Metal π-Complexation as a Traceless Reactivity Enhancer for C–H Arylation

(2013) Paolo Ricci et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zirconocene Dichloride Catalyzed Hydrodefluorination of C sp 2F bonds

(2012) Shuhui Yow et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Titanium-Catalyzed Vinylic and Allylic CF Bond Activation-Scope, Limitations and Mechanistic Insight

(2012) Moritz F. Kuehnel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbon Monoxide, Isocyanide, and Nitrile Complexes of Cationic, d0 Vanadium Bisimides: π-Back Bonding Derived from the π Symmetry, Bonding Metal Bisimido Ligand Orbitals

(2012) Henry S. La Pierre et al.   INORGANIC CHEMISTRY

NiCl2(PCy3)2-catalyzed hydrodefluorination of fluoroarenes with LiAl(O-t-Bu)3H

(2012) Juan Xiao et al.   JOURNAL OF FLUORINE CHEMISTRY

An Update on Recent Stoichiometric and Catalytic C–F Bond Cleavage Reactions by Lanthanide and Group 4 Transition-Metal Complexes

(2012) Marcus Klahn et al.   ORGANOMETALLICS

Low-Coordinate Cobalt Fluoride Complexes: Synthesis, Reactions, and Production from C–F Activation Reactions

(2012) Thomas R. Dugan et al.   ORGANOMETALLICS

C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales

(2011) Eric Clot et al.   ACCOUNTS OF CHEMICAL RESEARCH

Z-Selective Semihydrogenation of Alkynes Catalyzed by a Cationic Vanadium Bisimido Complex

(2011) Henry S. La Pierre et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and reactivity of cationic niobium and tantalum methyl complexes supported by imido and β-diketiminato ligands

(2011) Neil C. Tomson et al.   DALTON TRANSACTIONS

C-F Bond Activation of Highly Fluorinated Molecules at Rhodium: From Model Reactions to Catalysis

(2011) Thomas Braun et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Z-Selective, Catalytic Internal Alkyne Semihydrogenation under H2/CO Mixtures by a Niobium(III) Imido Complex

(2011) Thomas L. Gianetti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Masked Two-Coordinate Cobalt(I) Complex That Activates C–F Bonds

(2011) Thomas R. Dugan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Suzuki–Miyaura Reaction of Aryl Fluorides

(2011) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Alkyl C–F Bonds by B(C6F5)3: Stoichiometric and Catalytic Transformations

(2011) Christopher B. Caputo et al.   ORGANOMETALLICS

A Highly Reactive Rhodium(I)-Boryl Complex as a Useful Tool for CH Bond Activation and Catalytic CF Bond Borylation

(2010) Michael Teltewskoi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Titanium-Catalyzed C-F Activation of Fluoroalkenes

(2010) Moritz F. Kühnel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CF Activation of Fluorobenzene by Silylium Carboranes: Evidence for Incipient Phenyl Cation Reactivity

(2010) Simon Duttwyler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross coupling reactions of polyfluoroarenes via C–F activation

(2010) Alex D. Sun et al.   DALTON TRANSACTIONS

Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon−Halogen Bonds Using Silylium Catalysis

(2010) Christos Douvris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Characterization, and Reactions of Isolable (β-Diketiminato)niobium(III) Imido Complexes†

(2010) Neil C. Tomson et al.   ORGANOMETALLICS

Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the β-Diketiminato Ligand

(2010) Neil C. Tomson et al.   ORGANOMETALLICS

Dehalogenation and Hydrogenation of Aromatic Compounds Catalyzed by Nanoparticles Generated from Rhodium Bis(imino)pyridine Complexes§

(2010) María L. Buil et al.   ORGANOMETALLICS

Niobium-Catalyzed Activation of Aryl Trifluoromethyl Groups and Functionalization of CH Bonds: An Efficient and Convergent Approach to the Synthesis of N-Heterocycles

(2009) Tom G. Driver   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic CF Activation and Hydrodefluorination of Fluoroalkyl Groups

(2009) Gregor Meier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CF Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene

(2009) Thomas Braun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Conversion of Carbon-Fluorine Bonds α to Transition Metal Centers to Carbon-Hydrogen, Carbon-Carbon, and Carbon-Heteroatom Bonds

(2009) Russell P. Hughes   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Catalytic Hydrodefluorination of Aromatic Fluorocarbons by Ruthenium N-Heterocyclic Carbene Complexes

(2009) Steven P. Reade et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon−Carbon Coupling of C(sp3)−F Bonds Using Alumenium Catalysis

(2009) Weixing Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Combined Experimental and Computational Study of Unexpected C−F Bond Activation Intermediates and Selectivity in the Reaction of Pentafluorobenzene with a (PEt3)2Ni Synthon

(2009) Samuel A. Johnson et al.   ORGANOMETALLICS

C–F Activation of hydrofluorocarbons (HFCs) mediated by aluminum reagents

(2009) Majeid Ali et al.   TETRAHEDRON LETTERS

An Unusally Diverse Array of Products Formed upon Carbonylation of a Dialkylniobium Complex

(2008) Neil C. Tomson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorine for Hydrogen Exchange in the Hydrofluorobenzene Derivatives C6HxF(6-x),wherex= 2, 3, 4 and 5 by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: The Solid State Isomerization of [1,2,4-(Me3C)3C5H2]2Ce(2,3,4,5-C6HF4) to [1,2,4-(Me3C)3C5H2]2Ce(2,3,4,6-C6HF4)

(2008) Evan L. Werkema et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations

(2008) Thomas Schaub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrofluorination of Hydrofluorocarbons by Titanium Alkylidynes via Sequential C−H/C−F Bond Activation Reactions. A Synthetic, Structural, and Mechanistic Study of 1,2-CH Bond Addition and β-Fluoride Elimination

(2008) Alison R. Fout et al.   ORGANOMETALLICS

Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts

(2008) C. Douvris et al.   SCIENCE