Terminal Imido Complexes of the Groups 9–11: Electronic Structure and Developments in the Last Decade

Enantioselective C–H Amination Catalyzed by Nickel Iminyl Complexes Supported by Anionic Bisoxazoline (BOX) Ligands

(2021) Yuyang Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Tailoring Toward an Air-Stable Iron(V) Nitrido Complex

(2021) Martin Keilwerth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt Diazo−Compounds: From Nitrilimide to Isocyanoamide via a Diazomethanediide Fleeting Intermediate

(2021) Sadig Aghazada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Electronic Structure, and Reactivity of a Planar Four‐Coordinate, Cobalt‐Imido Complex

(2021) Paul James Chirik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Pair of Cobalt(III/IV) Terminal Imido Complexes

(2021) Karsten Meyer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High‐Spin Imido Cobalt Complexes with Imidyl Radical Character

(2021) Alexander Reckziegel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Charge frustration in ligand design and functional group transfer

(2021) Dominik Munz et al.   Nature Reviews Chemistry

C−H bond activation by an Imido Cobalt(III) and the Resulting Amido Cobalt(II) Complex

(2020) Alexander Reckziegel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactivity of terminal imido complexes of group 4–6 metals: Stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules

(2020) Kento Kawakita et al.   COORDINATION CHEMISTRY REVIEWS

Where Is the Fluoro Wall?: A Quantum Chemical Investigation

(2020) Julian D. Rolfes et al.   INORGANIC CHEMISTRY

Efficient C-H amination catalysis using nickel-dipyrrin complexes

(2020) Yuyang Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N‐Heterocyclic Carbene Analogues of Nucleophilic Phosphinidene Transition Metal Complexes

(2020) Matthias Tamm et al.   CHEMISTRY-A EUROPEAN JOURNAL

Main Group Multiple Bonds for Bond Activations and Catalysis

(2020) Catherine Weetman   CHEMISTRY-A EUROPEAN JOURNAL

Progress Toward the Isolation of Late Metal Terminal Sulfides

(2020) Miguel Á. Baeza Cinco et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Electronically Asynchronous Transition States for C–N Bond Formation by Electrophilic [CoIII(TAML)]-Nitrene Radical Complexes Involving Substrate-to-Ligand Single-Electron Transfer and a Cobalt-Centered Spin Shuttle

(2020) Nicolaas P. van Leest et al.   ACS Catalysis

Iron and manganese oxo complexes, oxo wall and beyond

(2020) Virginia A. Larson et al.   Nature Reviews Chemistry

Fluoro Nitrenoid Complexes FN=MF 2 (M=Co, Rh, Ir): Electronic Structure Dichotomy and Formation of Nitrido Fluorides N≡MF 3

(2020) Tony Stüker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A platinum(ii) metallonitrene with a triplet ground state

(2020) Jian Sun et al.   Nature Chemistry

Copper-Catalyzed C(sp3 )−H Amidation: Sterically Driven Primary and Secondary C−H Site-Selectivity

(2019) Abolghasem Gus Bakhoda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Adducts of Main Group Elements and Their Use as Ligands in Transition Metal Chemistry

(2019) Adinarayana Doddi et al.   CHEMICAL REVIEWS

Chasing Multiple Bonding Interactions between Alkaline‐Earth Metals and Main‐Group Fragments

(2019) Benjamin M. Wolf et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic C–H Amination Mediated by Dipyrrin Cobalt Imidos

(2019) Yunjung Baek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Nitrene/Alkyne Metathesis: An Enantioselective Process for the Synthesis of N-Heterocycles

(2019) Kemiao Hong et al.   ORGANIC LETTERS

Metal–Oxyl Species and Their Possible Roles in Chemical Oxidations

(2019) Yoshihiro Shimoyama et al.   INORGANIC CHEMISTRY

Synthesis of a copper-supported triplet nitrene complex pertinent to copper-catalyzed amination

(2019) Kurtis M. Carsch et al.   SCIENCE

A Mechanistic Study of the Stereochemical Outcomes of Rhodium‐Catalysed Styrene Aziridinations

(2019) Emna Azek et al.   ADVANCED SYNTHESIS & CATALYSIS

A Terminal Iron Nitrilimine Complex: Accessing the Terminal Nitride through Diazo N−N Bond Cleavage

(2019) Sadig Aghazada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Characterization of a Linear, Two-Coordinate Pt(II) Ketimide Complex

(2019) Andrew W. Cook et al.   INORGANIC CHEMISTRY

Direct Manipulation of Metal Imido Geometry: Key Principles to Enhance C–H Amination Efficacy

(2019) Yunjung Baek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterization of a Reactive Rh2 Nitrenoid by Crystalline Matrix Isolation

(2019) Anuvab Das et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkoxide ligand controlled self-assembling of (imido)vanadium(V) compounds having a tetrahedral VO3N geometry

(2019) Toshiyuki Moriuchi et al.   JOURNAL OF INORGANIC BIOCHEMISTRY

Designed To React: Terminal Copper Nitrenes and Their Application in Catalytic C−H Aminations

(2018) Julian Moegling et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbenes and Nitrenes: Recent Developments in Fundamental Chemistry

(2018) Curt Wentrup   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

How to tame a palladium terminal imido

(2018) Annette Grünwald et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Pushing Electrons—Which Carbene Ligand for Which Application?

(2018) Dominik Munz   ORGANOMETALLICS

How to tame a palladium terminal oxo

(2018) Dominik Munz   Chemical Science

An iridium(iii/iv/v) redox series featuring a terminal imido complex with triplet ground state

(2018) Markus Kinauer et al.   Chemical Science

Observation of a Photogenerated Rh2 Nitrenoid Intermediate in C–H Amination

(2018) Anuvab Das et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimentally Calibrated Analysis of the Electronic Structure of CuO+ : Implications for Reactivity

(2018) Martin Srnec et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Isolable Terminal Imido Complex of Palladium and Catalytic Implications

(2018) Annette Grünwald et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Structure, and Reactivity of Low-Spin Cobalt(II) Imido Complexes [(Me3P)3Co(NAr)]

(2017) Yang Liu et al.   INORGANIC CHEMISTRY

Reactions of Neutral Cobalt(II) Complexes of a Dianionic Tetrapodal Pentadentate Ligand: Cobalt(III) Amides from Imido Radicals

(2017) Lucie Nurdin et al.   INORGANIC CHEMISTRY

N-Heterocyclic Carbene-Phosphinidene and Carbene-Phosphinidenide Transition Metal Complexes

(2017) Marius Peters et al.   INORGANIC CHEMISTRY

Electronic Effects on Room-Temperature, Gas-Phase C–H Bond Activations by Cluster Oxides and Metal Carbides: The Methane Challenge

(2017) Helmut Schwarz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Unique Gas-Phase Chemistry of the [AuO]+ /CH4 Couple: Selective Oxygen-Atom Transfer to, Rather than Hydrogen-Atom Abstraction from, Methane

(2016) Shaodong Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Characterization and Reactivity Studies of a Terminal Copper-Nitrene Species

(2016) Teresa Corona et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Widely Accepted Concepts in Coordination Chemistry to Inverted Ligand Fields

(2016) Roald Hoffmann et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Alkene Difunctionalization with Nitrenes

(2016) Jennifer Ciesielski et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Unusual Cobalt Azide Adduct That Produces a Nitrene Species for Carbon–Hydrogen Insertion Chemistry

(2016) Lauren N. Grant et al.   INORGANIC CHEMISTRY

Reversible Redox Chemistry and Catalytic C(sp3)–H Amination Reactivity of a Paramagnetic Pd Complex Bearing a Redox-Active o-Aminophenol-Derived NNO Pincer Ligand

(2016) Daniël L. J. Broere et al.   INORGANIC CHEMISTRY

A Synthetic Oxygen Atom Transfer Photocycle from a Diruthenium Oxyanion Complex

(2016) Amanda R. Corcos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh2(II,III) Catalysts with Chelating Carboxylate and Carboxamidate Supports: Electronic Structure and Nitrene Transfer Reactivity

(2016) Adrián Varela-Álvarez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Penetrating the Elusive Mechanism of Copper-Mediated Fluoromethylation in the Presence of Oxygen through the Gas-Phase Reactivity of Well-Defined [LCuO]+ Complexes with Fluoromethanes (CH(4–n)Fn, n = 1–3)

(2016) Nicole J. Rijs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Two-Coordinate Co(II) Imido Complexes as Outstanding Single-Molecule Magnets

(2016) Xiao-Nan Yao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dirhodium-catalyzed C-H arene amination using hydroxylamines

(2016) M. P. Paudyal et al.   SCIENCE

Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

(2015) Kwangmin Shin et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Two-Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis, Structure, and Reactivity

(2015) Jingzhen Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper and Silver Carbene Complexes without Heteroatom-Stabilization: Structure, Spectroscopy, and Relativistic Effects

(2015) Matthias W. Hussong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold Carbene or Carbenoid: Is There a Difference?

(2015) Yahui Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Homolytic N–H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species

(2015) Markus G. Scheibel et al.   INORGANIC CHEMISTRY

Synthesis of Sulfoximine Carbamates by Rhodium-Catalyzed Nitrene Transfer of Carbamates to Sulfoxides

(2015) Marina Zenzola et al.   JOURNAL OF ORGANIC CHEMISTRY

Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions

(2015) Monalisa Goswami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Phosphinidyne Transition Metal Complexes

(2014) Adinarayana Doddi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acis-Divacant Octahedral and Mononuclear Iron(IV) Imide

(2014) Keith Searles et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Terminal Imido Rhodium Complexes

(2014) Ana M. Geer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evidence of two-state reactivity in alkane hydroxylation by Lewis-acid bound copper–nitrene complexes

(2014) Sarah-Luise Abram et al.   CHEMICAL COMMUNICATIONS

Carbon–Hydrogen Bond Activation, C–N Bond Coupling, and Cycloaddition Reactivity of a Three-Coordinate Nickel Complex Featuring a Terminal Imido Ligand

(2014) Daniel J. Mindiola et al.   INORGANIC CHEMISTRY

Formation of Heterobimetallic Zirconium/Cobalt Diimido Complexes via a Four-Electron Transformation

(2014) Bing Wu et al.   INORGANIC CHEMISTRY

EPR, ENDOR, and Electronic Structure Studies of the Jahn–Teller Distortion in an FeV Nitride

(2014) George E. Cutsail III et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of Bridging and Terminal Coinage Metal–Nitrene Complexes

(2014) Fabian Dielmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Three-Coordinate Cobalt(IV) and Cobalt(V) Imido Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Structure, and Their Distinct Reactivity in C–H Bond Amination

(2014) Long Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex

(2014) Daniël L. J. Broere et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Intermolecular Amidation of sp3 C–H Bonds: Late-Stage Functionalization of an Unactivated Methyl Group

(2014) Taek Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition metal complexes supported by highly basic imidazolin-2-iminato and imidazolin-2-imine N-donor ligands

(2013) Xian Wu et al.   COORDINATION CHEMISTRY REVIEWS

Terminal Oxo and Imido Transition-Metal Complexes of Groups 9-11

(2013) Kallol Ray et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A General Mechanism for the Copper- and Silver-Catalyzed Olefin Aziridination Reactions: Concomitant Involvement of the Singlet and Triplet Pathways

(2013) Lourdes Maestre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Insights into C–H Amination via Dicopper Nitrenes

(2013) Mae Joanne B. Aguila et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir(III)-Catalyzed Mild C–H Amidation of Arenes and Alkenes: An Efficient Usage of Acyl Azides as the Nitrogen Source

(2013) Jaeyune Ryu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Strongly bent nickel imides supported by a chelating bis(N-heterocyclic carbene) ligand

(2013) Nicole D. Harrold et al.   Chemical Science

Spectroscopic Observation of a Group 12 Oxyfluoride: A Matrix-Isolation and Quantum-Chemical Investigation of Mercury Oxyfluorides

(2012) Lester Andrews et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thermal Hydrogen-Atom Transfer from Methane: The Role of Radicals and Spin States in Oxo-Cluster Chemistry

(2012) Nicolas Dietl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal–ligand multiple bonds as frustrated Lewis pairs for C–H functionalization

(2012) Matthew T Whited   Beilstein Journal of Organic Chemistry

Simple Ligand-Field Theory of d4 and d6 Transition Metal Complexes with a C3 Symmetry Axis

(2012) Bruce R. McGarvey et al.   INORGANIC CHEMISTRY

Co(III) Imidos Exhibiting Spin Crossover and C–H Bond Activation

(2012) Evan R. King et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh2(II)-Catalyzed Intramolecular Aliphatic C–H Bond Amination Reactions Using Aryl Azides as the N-Atom Source

(2012) Quyen Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Closed-shell and open-shell square-planar iridium nitrido complexes

(2012) Markus G. Scheibel et al.   Nature Chemistry

Capturing fleeting intermediates in a catalytic C-H amination reaction cycle

(2012) R. H. Perry et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Crystalline Singlet Phosphinonitrene: A Nitrogen Atom-Transfer Agent

(2012) F. Dielmann et al.   SCIENCE

Diatomic [CuO]+ and Its Role in the Spin-Selective Hydrogen- and Oxygen-Atom Transfers in the Thermal Activation of Methane

(2011) Nicolas Dietl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates

(2011) John F. Berry   DALTON TRANSACTIONS

Matrix Infrared Spectroscopic and Theoretical of the Difluoroamino Metal Fluoride Molecules: F2NMF (M = Cu, Ag, Au)

(2011) Yu Gong et al.   INORGANIC CHEMISTRY

Detailed Ab Initio First-Principles Study of the Magnetic Anisotropy in a Family of Trigonal Pyramidal Iron(II) Pyrrolide Complexes

(2011) Mihail Atanasov et al.   INORGANIC CHEMISTRY

Quantum chemical assessment of the binding energy of CuO+

(2011) Elixabete Rezabal et al.   JOURNAL OF CHEMICAL PHYSICS

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of Three-Coordinate Ni(III)-Imide Complexes

(2011) Vlad M. Iluc et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Cobalt-Porphyrin–Catalyzed Aziridination

(2011) Kathrin H. Hopmann et al.   ACS Catalysis

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

Hydrogen-Atom Abstraction from Ni(I) Phosphido and Amido Complexes Gives Phosphinidene and Imide Ligands

(2010) Vlad M. Iluc et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Two-Coordinate Nickel Imido Complex That Effects C−H Amination

(2010) Carl A. Laskowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

What Does it Really Take to Stabilize Complexes of Late Transition Metals with Terminal Oxo Ligands?

(2009) Christian Limberg   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amidinato- and Guanidinato-Cobalt(I) Complexes: Characterization of Exceptionally Short Co-Co Interactions

(2009) Cameron Jones et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in High Oxidation State Mo and W Imido Alkylidene Chemistry

(2009) Richard R. Schrock   CHEMICAL REVIEWS

Selective Activation of Alkanes by Gas-Phase Metal Ions†

(2009) Jana Roithová et al.   CHEMICAL REVIEWS

TERMINAL NITRIDO AND IMIDO COMPLEXES OF THE LATE TRANSITION METALS

(2009) John F. Berry   COMMENTS ON INORGANIC CHEMISTRY

Group-Transfer Reactions of Nickel−Carbene and −Nitrene Complexes with Organoazides and Nitrous Oxide that Form New C═N, C═O, and N═N Bonds

(2009) Nicole D. Harrold et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Early Transition-Metal Hydrazido Complexes: Masked Metallanitrenes from NN Bond Scission

(2008) Daniel J. Mindiola   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Asymmetric Olefin Aziridination with Diphenylphosphoryl Azide

(2008) Jess E. Jones et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Tuning of a Phosphinoethane Ligand for Enhanced C−H Activation

(2008) Thomas R. Cundari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

η2-Organoazide Complexes of Nickel and Their Conversion to Terminal Imido ComplexesviaDinitrogen Extrusion

(2008) Rory Waterman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural and Spectroscopic Characterization of an Electrophilic Iron Nitrido Complex

(2008) Jeremiah J. Scepaniak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Evidence for a terminal Pt(iv)-oxo complex exhibiting diverse reactivity

(2008) Elena Poverenov et al.   NATURE