An iridium(iii/iv/v) redox series featuring a terminal imido complex with triplet ground state

Reactions of Neutral Cobalt(II) Complexes of a Dianionic Tetrapodal Pentadentate Ligand: Cobalt(III) Amides from Imido Radicals

(2017) Lucie Nurdin et al.   INORGANIC CHEMISTRY

Catalytic Synthesis of N-Heterocycles via Direct C(sp3)–H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand

(2017) Bidraha Bagh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Four- and Five-Coordinate Osmium(IV) Nitrides and Imides: Circumventing the “Nitrido Wall”

(2017) Josh Abbenseth et al.   ORGANOMETALLICS

Redox-Active-Ligand-Mediated Formation of an Acyclic Trinuclear Ruthenium Complex with Bridging Nitrido Ligands

(2016) Bidraha Bagh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Terminal Osmium(IV) Nitride: Ammonia Formation and Ambiphilic Reactivity

(2016) Florian S. Schendzielorz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Why is the Ir(III)-Mediated Amido Transfer Much Faster Than the Rh(III)-Mediated Reaction? A Combined Experimental and Computational Study

(2016) Yoonsu Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

What Factors Control the Reactivity of Cobalt–Imido Complexes in C–H Bond Activation via Hydrogen Abstraction?

(2016) Lianrui Hu et al.   ACS Catalysis

Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

(2015) Kwangmin Shin et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Two-Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis, Structure, and Reactivity

(2015) Jingzhen Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Activation of Benzene by a Photoactivated NiII(azide): Formation of a Transient Nickel Nitrido Complex

(2015) Vincent Vreeken et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

First principles approach to the electronic structure, magnetic anisotropy and spin relaxation in mononuclear 3d-transition metal single molecule magnets

(2015) Mihail Atanasov et al.   COORDINATION CHEMISTRY REVIEWS

Homolytic N–H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species

(2015) Markus G. Scheibel et al.   INORGANIC CHEMISTRY

Oxyfunctionalization with Cp*IrIII(NHC)(Me)(Cl) with O2: Identification of a Rare Bimetallic IrIV μ-Oxo Intermediate

(2015) Matthew C. Lehman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions

(2015) Monalisa Goswami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Isolated Nitridyl Radical-Bridged {Rh(N.)Rh} Complex

(2014) Yann Gloaguen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spectroscopic Capture and Reactivity of a Low-Spin Cobalt(IV)-Oxo Complex Stabilized by Binding Redox-Inactive Metal Ions

(2014) Seungwoo Hong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Terminal Imido Rhodium Complexes

(2014) Ana M. Geer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Square-Planar Ruthenium(II) Complexes: Control of Spin State by Pincer Ligand Functionalization

(2014) Bjorn Askevold et al.   CHEMISTRY-A EUROPEAN JOURNAL

Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex

(2014) Daniël L. J. Broere et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Complexes with Nitrogen-Centered Radical Ligands: Classification, Spectroscopic Features, Reactivity, and Catalytic Applications

(2013) Alma I. Olivos Suarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[IrCl{N(CHCHPtBu2)2}]−: a versatile source of the IrI(PNP) pincer platform

(2013) Markus Kinauer et al.   DALTON TRANSACTIONS

Precursor Transformation during Molecular Oxidation Catalysis with Organometallic Iridium Complexes

(2013) Ulrich Hintermair et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of a Transient, Terminal Nitrido Complex of Rhodium

(2013) Markus G. Scheibel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

(2012) Jennifer L. Roizen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nitrene Chemistry in Organic Synthesis: Still in Its Infancy?

(2012) Geoffroy Dequirez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Acid Trapping of an Elusive Copper–Tosylnitrene Intermediate Using Scandium Triflate

(2012) Subrata Kundu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Assembly and Properties of Heterobimetallic CoII/III/CaII Complexes with Aquo and Hydroxo Ligands

(2012) David C. Lacy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Closed-shell and open-shell square-planar iridium nitrido complexes

(2012) Markus G. Scheibel et al.   Nature Chemistry

Square-Planar Iridium(II) and Iridium(III) Amido Complexes Stabilized by a PNP Pincer Ligand

(2011) Jenni Meiners et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A four coordinate parent imidevia a titanium nitridyl

(2011) Ba L. Tran et al.   CHEMICAL COMMUNICATIONS

Nitrogen Atom Transfer from Iron(IV) Nitrido Complexes: A Dual-Nature Transition State for Atom Transfer

(2011) Jeremiah J. Scepaniak et al.   INORGANIC CHEMISTRY

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cp* Iridium Precatalysts for Selective C–H Oxidation via Direct Oxygen Insertion: A Joint Experimental/Computational Study

(2011) Meng Zhou et al.   ACS Catalysis

An Oxocobalt(IV) Complex Stabilized by Lewis Acid Interactions with Scandium(III) Ions

(2010) Florian Felix Pfaff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−H Bond Activations by Metal Oxo Compounds

(2010) Ahmet Gunay et al.   CHEMICAL REVIEWS

Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis

(2010) James D. Blakemore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Two-Coordinate Nickel Imido Complex That Effects C−H Amination

(2010) Carl A. Laskowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation and Hydrogenation of a Complex with a Terminal Iridium-Nitrido Bond

(2009) Julia Schöffel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

TERMINAL NITRIDO AND IMIDO COMPLEXES OF THE LATE TRANSITION METALS

(2009) John F. Berry   COMMENTS ON INORGANIC CHEMISTRY

Evidence for a terminal Pt(iv)-oxo complex exhibiting diverse reactivity

(2008) Elena Poverenov et al.   NATURE