Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 10, Pages 3800-3802Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja5007355
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Funding
- DOE [DE-SC0009376]
- Alexander von Humboldt Foundation
- U.S. Department of Energy (DOE) [DE-SC0009376] Funding Source: U.S. Department of Energy (DOE)
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Transition metal complexes featuring a metal nitrogen multiple bond have been widely studied due to their implication in dinitrogen fixation and catalytic nitrogen carbon bond formation. Terminal copper and silver-nitrene complexes have long been proposed to be the key intermediates in aziridination and amination reactions using azides as the nitrogen source. However, due to their high reactivity, these species have eluded isolation and spectroscopic characterization even at low temperatures. In this paper we report that a stable phosphinonitrene reacts with coinage metal trifluoro-methanesulfonates, affording bridging and terminal copper- and silver-nitrene complexes, which are characterized by NMR spectroscopy and single crystal X-ray diffraction analysis.
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