Metal-catalyzed reductive coupling of olefin-derived nucleophiles: Reinventing carbonyl addition

Iron-Catalyzed Regioselective Transfer Hydrogenative Couplings of Unactivated Aldehydes with Simple Alkenes

(2016) Yan-Long Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Osmium(0)-Catalyzed C–C Coupling of Ethylene and α-Olefins with Diols, Ketols, or Hydroxy Esters via Transfer Hydrogenation

(2016) Boyoung Y. Park et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids

(2016) Jeffrey S. Bandar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-BINAP Catalyzed Alcohol C–H tert-Prenylation via 1,3-Enyne Transfer Hydrogenation: Beyond Stoichiometric Carbanions in Enantioselective Carbonyl Propargylation

(2016) Khoa D. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones

(2016) Y. Yang et al.   SCIENCE

A Metallacycle Fragmentation Strategy for Vinyl Transfer from Enol Carboxylates to Secondary Alcohol C–H Bonds via Osmium- or Ruthenium-Catalyzed Transfer Hydrogenation

(2015) Boyoung Y. Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Asymmetric Hydrohydroxyalkylation of Butadiene: The Role of the Formyl Hydrogen Bond in Stereochemical Control

(2015) Matthew N. Grayson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective CH Functionalization of Alcohols by Redox-Triggered Carbonyl Addition: Borrowing Hydrogen, Returning Carbon

(2014) John M. Ketcham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Paraformaldehyde and Methanol as C1 Feedstocks in Metal-Catalyzed CC Couplings of π-Unsaturated Reactants: Beyond Hydroformylation

(2014) Brannon Sam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Post-Metallocenes in the Industrial Production of Polyolefins

(2014) Moritz C. Baier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Diastereoselective CC Coupling of α-Olefins and Styrenes to 3-Hydroxy-2-oxindoles by Ru-Catalyzed Hydrohydroxyalkylation

(2013) Eiji Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C═N-Containing Azaarenes as Activating Groups in Enantioselective Catalysis

(2013) Daniel Best et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed Hydrohydroxyalkylation of Acrylates with Diols and α-Hydroxycarbonyl Compounds To Form Spiro- and α-Methylene-γ-butyrolactones

(2013) Emma L. McInturff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium Catalyzed Hydrohydroxyalkylation of Isoprene with Heteroaromatic Secondary Alcohols: Isolation and Reversible Formation of the Putative Metallacycle Intermediate

(2013) Boyoung Y. Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Ruthenium Catalyzed Hydrohydroxyalkylation of Dienes with 3-Hydroxy-2-oxindoles: Prenylation, Geranylation, and Beyond

(2013) Te-Yu Chen et al.   ORGANIC LETTERS

Diastereo- and Enantioselective Iridium-Catalyzed Carbonyl Propargylation from the Alcohol or Aldehyde Oxidation Level: 1,3-Enynes as Allenylmetal Equivalents

(2012) Laina M. Geary et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Reductive Coupling of 1,3-Enynes and Aldehydes by Transfer Hydrogenation:anti-Diastereoselective Carbonyl Propargylation

(2012) Laina M. Geary et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

(2012) Emma L. McInturff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Copper-Catalyzed Reductive Coupling of Alkenylazaarenes with Ketones

(2012) Aakarsh Saxena et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct, Redox-Neutral Prenylation and Geranylation of Secondary Carbinol C–H Bonds: C4-Regioselectivity in Ruthenium-Catalyzed C–C Couplings of Dienes to α-Hydroxy Esters

(2012) Joyce C. Leung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene

(2012) J. R. Zbieg et al.   SCIENCE

Catalytic intermolecular hydroacylation of C–C π-bonds in the absence of chelation assistance

(2012) Joyce C. Leung et al.   Chemical Science

Diastereo- and Enantioselective Ruthenium-Catalyzed Hydrohydroxyalkylation of 2-Silyl-butadienes: Carbonylsyn-Crotylation from the Alcohol Oxidation Level

(2011) Jason R. Zbieg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-catalysed direct C–C coupling of methanol and allenes

(2011) Joseph Moran et al.   Nature Chemistry

Unlocking Hydrogenation for C–C Bond Formation: A Brief Overview of Enantioselective Methods

(2011) Abbas Hassan et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Iridium-Catalyzed Hydrohydroxyalkylation of Butadiene: Carbonyl Crotylation

(2010) Jason R. Zbieg et al.   ADVANCED SYNTHESIS & CATALYSIS

All-Carbon Quaternary Centers via Ruthenium-Catalyzed Hydroxymethylation of 2-Substituted Butadienes Mediated by Formaldehyde: Beyond Hydroformylation

(2009) Tomas Smejkal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbonyl Propargylation from the Alcohol or Aldehyde Oxidation Level Employing 1,3‐Enynes as Surrogates to Preformed Allenylmetal Reagents: A Ruthenium‐Catalyzed CC Bond‐Forming Transfer Hydrogenation

(2008) Ryan L. Patman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereo- and Enantioselective Hydrogenative Aldol Coupling of Vinyl Ketones:  Design of Effective Monodentate TADDOL-Like Phosphonite Ligands

(2008) Cisco Bee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Branch-Selective Reductive Coupling of 2-Vinyl Pyridines and IminesviaRhodium Catalyzed C−C Bond Forming Hydrogenation

(2008) Venukrishnan Komanduri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed C−C Bond Forming Transfer Hydrogenation: Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Employing Acyclic 1,3-Dienes as Surrogates to Preformed Allyl Metal Reagents

(2008) Fumitoshi Shibahara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed C−C Coupling via Transfer Hydrogenation:  Carbonyl Addition from the Alcohol or Aldehyde Oxidation Level Employing 1,3-Cyclohexadiene

(2008) John F. Bower et al.   ORGANIC LETTERS