Development of catalytic nitrogen fixation using transition metal complexes not relevant to nitrogenases

Electron Transfer in Nitrogenase

(2020) Hannah L. Rutledge et al.   CHEMICAL REVIEWS

Reactivity, Mechanism, and Assembly of the Alternative Nitrogenases

(2020) Andrew J. Jasniewski et al.   CHEMICAL REVIEWS

(Electro-)chemical Splitting of Dinitrogen with a Rhenium Pincer Complex

(2020) Richt S. van Alten et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis of a T-Shaped Cobalt(I) Complex and Its Dinitrogen Adduct

(2020) Corey A. Sanz et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Dinitrogen Activation and Functionalization with Chromium

(2020) Alexander J. Kendall et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Evaluating Metal Ion Identity on Catalytic Silylation of Dinitrogen Using a Series of Trimetallic Complexes

(2020) Mary C. Eaton et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

N2 Silylation Catalyzed by a Bis(silylene)-Based [SiCSi] Pincer Hydrido Iron(II) Dinitrogen Complex

(2020) Shengyong Li et al.   ORGANOMETALLICS

The Spectroscopy of Nitrogenases

(2020) Casey Van Stappen et al.   CHEMICAL REVIEWS

Activation of Dinitrogen by Polynuclear Metal Complexes

(2020) Devender Singh et al.   CHEMICAL REVIEWS

Reduction of Substrates by Nitrogenases

(2020) Lance C. Seefeldt et al.   CHEMICAL REVIEWS

Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes

(2020) Matthew J. Chalkley et al.   CHEMICAL REVIEWS

Beyond Ammonia: Nitrogen–Element Bond Forming Reactions with Coordinated Dinitrogen

(2020) Sangmin Kim et al.   CHEMICAL REVIEWS

Metal–Sulfur Compounds in N2 Reduction and Nitrogenase-Related Chemistry

(2020) Kazuki Tanifuji et al.   CHEMICAL REVIEWS

Iridium-Catalyzed Formation of Silylamine from Dinitrogen under Ambient Reaction Conditions

(2020) Ryosuke Kawakami et al.   CHEMISTRY LETTERS

Metallacyclic actinide catalysts for dinitrogen conversion to ammonia and secondary amines

(2020) Polly L. Arnold et al.   Nature Chemistry

Dinitrogen Cleavage by a Heterometallic Cluster Featuring Multiple Uranium–Rhodium Bonds

(2020) Xiaoqing Xin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coupling dinitrogen and hydrocarbons through aryl migration

(2020) Sean F. McWilliams et al.   NATURE

Facile Dinitrogen and Dioxygen Cleavage by a Uranium(III) Complex: Cooperativity Between the Non‐innocent Ligand and the Uranium Center

(2020) Penglong Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cp* Noninnocence Leads to a Remarkably Weak C–H Bond via Metallocene Protonation

(2019) Matthew J. Chalkley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen Functionalization Affording Chromium Hydrazido Complex

(2019) Jianhao Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molybdenum-catalysed ammonia production with samarium diiodide and alcohols or water

(2019) Yuya Ashida et al.   NATURE

Recent advances in catalytic silylation of dinitrogen using transition metal complexes

(2019) Yoshiaki Tanabe et al.   COORDINATION CHEMISTRY REVIEWS

Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands

(2019) Yuya Ashida et al.   INORGANIC CHEMISTRY

Synthesis and Catalytic Reactivity of Bis(molybdenum-trihalide) Complexes Bridged by Ferrocene Skeleton toward Catalytic Nitrogen Fixation

(2019) Takayuki Itabashi et al.   ORGANOMETALLICS

A Practical Synthesis of Ammonia from Nitrogen Gas, Samarium Diiodide and Water Catalyzed by a Molybdenum–PCP Pincer Complex

(2019) Yuya Ashida et al.   SYNTHESIS-STUTTGART

Dinitrogen Reduction to Ammonium at Rhenium Utilizing Light and Proton-Coupled Electron Transfer

(2019) Quinton J. Bruch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Dinitrogen Reduction to Ammonia at a Triamidoamine-Titanium Complex

(2018) Laurence R. Doyle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Reduction of Molecular Dinitrogen to Ammonia and Hydrazine Using Vanadium Complexes

(2018) Yoshiya Sekiguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

QM/MM calculations reveal a bridging hydroxo group in a vanadium nitrogenase crystal structure

(2018) Bardi Benediktsson et al.   CHEMICAL COMMUNICATIONS

Preparation and reactivity of iron complexes bearing anionic carbazole-based PNP-type pincer ligands toward catalytic nitrogen fixation

(2018) Junichi Higuchi et al.   DALTON TRANSACTIONS

Nitrogen Fixation Catalyzed by Transition Metal Complexes: Recent Developments

(2018) Nadja Stucke et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Catalytic Silylation of N2 and Synthesis of NH3 and N2H4 by Net Hydrogen Atom Transfer Reactions Using a Chromium P4 Macrocycle

(2018) Alexander J. Kendall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fe-Mediated Nitrogen Fixation with a Metallocene Mediator: Exploring pKa Effects and Demonstrating Electrocatalysis

(2018) Matthew J. Chalkley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis(dinitrogen)cobalt(−1) Complexes with NHC Ligation: Synthesis, Characterization, and Their Dinitrogen Functionalization Reactions Affording Side-on Bound Diazene Complexes

(2018) Yafei Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A bound reaction intermediate sheds light on the mechanism of nitrogenase

(2018) Daniel Sippel et al.   SCIENCE

Beyond fossil fuel–driven nitrogen transformations

(2018) Jingguang G. Chen et al.   SCIENCE

Catalytic Silylation of Dinitrogen by a Family of Triiron Complexes

(2018) Ricardo B. Ferreira et al.   ACS Catalysis

Efficient Catalytic Conversion of Dinitrogen to N(SiMe3)3 Using a Homogeneous Mononuclear Cobalt Complex

(2018) Tatsuya Suzuki et al.   ACS Catalysis

Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions

(2018) Yoshiaki Nishibayashi   DALTON TRANSACTIONS

The role of bridging ligands in dinitrogen reduction and functionalization by uranium multimetallic complexes

(2018) Marta Falcone et al.   Nature Chemistry

Recent advances in nitrogen fixation upon vanadium complexes

(2018) Yoshiaki Tanabe et al.   COORDINATION CHEMISTRY REVIEWS

Synthesis and Reactivity of Iron- and Cobalt-Dinitrogen Complexes Bearing PSiP-Type Pincer Ligands toward Nitrogen Fixation

(2017) Ryuji Imayoshi et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Catalytic Nitrogen-to-Ammonia Conversion by Osmium and Ruthenium Complexes

(2017) Javier Fajardo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reduction of Dinitrogen to Ammonia Catalyzed by Molybdenum Diamido Complexes

(2017) Lasantha A. Wickramasinghe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrogen reduction and functionalization by a multimetallic uranium nitride complex

(2017) Marta Falcone et al.   NATURE

The structure of vanadium nitrogenase reveals an unusual bridging ligand

(2017) Daniel Sippel et al.   Nature Chemical Biology

Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation

(2017) Aya Eizawa et al.   Nature Communications

Catalytic N2-to-NH3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET

(2017) Matthew J. Chalkley et al.   ACS Central Science

Examining the relationship between coordination mode and reactivity of dinitrogen

(2017) Richard J. Burford et al.   Nature Reviews Chemistry

Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands

(2016) Shogo Kuriyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conversion of Dinitrogen into Acetonitrile under Ambient Conditions

(2016) Isabel Klopsch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes

(2016) Yoshiaki Tanabe et al.   CHEMICAL RECORD

Insight into the Iron–Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands

(2016) Ilija Čorić et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Catalytic Reduction of N2 to N2H4 by a Simple Fe Complex

(2016) Peter J. Hill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench 57Fe Mössbauer Data, and a Hydride Resting State

(2016) Trevor J. Del Castillo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand

(2016) Shogo Kuriyama et al.   Nature Communications

Cobalt-Catalyzed Transformation of Molecular Dinitrogen into Silylamine under Ambient Reaction Conditions

(2015) Ryuji Imayoshi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers

(2015) Nitesh Khoenkhoen et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Evaluating Molecular Cobalt Complexes for the Conversion of N2 to NH3

(2015) Trevor J. Del Castillo et al.   INORGANIC CHEMISTRY

Recent Progress in Transition-Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions

(2015) Yoshiaki Nishibayashi   INORGANIC CHEMISTRY

Catalytic Silylation of Dinitrogen with a Dicobalt Complex

(2015) Randall B. Siedschlag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of Dinitrogen to Ammonia by Use of Molybdenum–Nitride Complexes Bearing a Tridentate Triphosphine as Catalysts

(2015) Kazuya Arashiba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site

(2015) Shogo Kuriyama et al.   Chemical Science

Catalysis-dependent selenium incorporation and migration in the nitrogenase active site iron-molybdenum cofactor

(2015) Thomas Spatzal et al.   eLife

Differential Reduction of CO2by Molybdenum and Vanadium Nitrogenases

(2014) Johannes G. Rebelein et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum–Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand

(2014) Shogo Kuriyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of a (Dinitrogen)Tricopper(I) Complex

(2014) Leslie J. Murray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium

(2014) Isabel Klopsch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand binding to the FeMo-cofactor: Structures of CO-bound and reactivated nitrogenase

(2014) T. Spatzal et al.   SCIENCE

Late Metal Scaffolds that Activate Both, Dinitrogen and Reduced Dinitrogen Species NxHy

(2014) Claudia Köthe et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Unique behaviour of dinitrogen-bridged dimolybdenum complexes bearing pincer ligand towards catalytic formation of ammonia

(2014) Hiromasa Tanaka et al.   Nature Communications

Dinitrogen Reduction by a Chromium(0) Complex Supported by a 16-Membered Phosphorus Macrocycle

(2013) Michael T. Mock et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boryl-Mediated Reversible H2 Activation at Cobalt: Catalytic Hydrogenation, Dehydrogenation, and Transfer Hydrogenation

(2013) Tzu-Pin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of N2 to NH3 by an Fe–N2 Complex Featuring a C-Atom Anchor

(2013) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron

(2013) K. Cory MacLeod et al.   Nature Chemistry

Dihydrogen Binding to Isostructural S = 1/2 and S = 0 Cobalt Complexes

(2012) Daniel L. M. Suess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands

(2011) Hiromasa Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Extending the Carbon Chain: Hydrocarbon Formation Catalyzed by Vanadium/Molybdenum Nitrogenases

(2011) Y. Hu et al.   SCIENCE

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

(2011) T. Spatzal et al.   SCIENCE

X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

(2011) K. M. Lancaster et al.   SCIENCE

Access to Well-Defined Ruthenium(I) and Osmium(I) Metalloradicals

(2010) Ayumi Takaoka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photolysis of Aqueous [(NH3)5Os(μ-N2)Os(NH3)5]5+: Cleavage of Dinitrogen by an Intramolecular Photoredox Reaction

(2010) Horst Kunkely et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Homogeneous iron complexes for the conversion of dinitrogen into ammonia and hydrazine

(2010) Nilay Hazari   CHEMICAL SOCIETY REVIEWS

Iron–dinitrogen coordination chemistry: Dinitrogen activation and reactivity

(2010) Justin L. Crossland et al.   COORDINATION CHEMISTRY REVIEWS

Synthesis of DiamidoPyrrolyl Molybdenum Complexes Relevant to Reduction of Dinitrogen to Ammonia

(2010) J. M. Chin et al.   INORGANIC CHEMISTRY

Synthesis of [(DPPNCH2CH2)3N]3−Molybdenum Complexes (DPP = 3,5-(2,5-Diisopropylpyrrolyl)2C6H3) and Studies Relevant to Catalytic Reduction of Dinitrogen

(2010) Michael R. Reithofer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron

(2010) Yunho Lee et al.   Nature Chemistry

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

(2010) Kazuya Arashiba et al.   Nature Chemistry

The Evolution and Future of Earth’s Nitrogen Cycle

(2010) Donald E. Canfield et al.   SCIENCE

Dinitrogen Complexes Supported by Tris(phosphino)silyl Ligands

(2009) Matthew T. Whited et al.   INORGANIC CHEMISTRY

Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum: Theory versus Experiment

(2008) Richard R. Schrock   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION