Journal
DALTON TRANSACTIONS
Volume 47, Issue 33, Pages 11290-11297Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt02572j
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Funding
- CREST, JST [JPMJCR1541]
- JSPS [JP17H01201, JP15H05798]
- MEXT
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This paper describes our recent progress in catalytic nitrogen fixation using transition metal-dinitrogen complexes as catalysts. Our research group has recently developed novel reaction systems for the catalytic transformation of molecular dinitrogen into ammonia and hydrazine using molybdenum-, iron-, cobalt- and vanadium-dinitrogen complexes under mild reaction conditions. The new findings presented in this paper may provide a new approach to the development of economical nitrogen fixation to replace the energy-consuming Haber-Bosch process.
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