Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand

A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench 57Fe Mössbauer Data, and a Hydride Resting State

(2016) Trevor J. Del Castillo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Fe-N2 Complex That Generates Hydrazine and Ammonia via Fe═NNH2: Demonstrating a Hybrid Distal-to-Alternating Pathway for N2 Reduction

(2016) Jonathan Rittle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Three- and Four-Coordinate Homoleptic Iron(I)–NHC Complexes: Synthesis and Characterization

(2016) Zhenwu Ouyang et al.   ORGANOMETALLICS

N-Heterocyclic Carbene Complexes of Three- and Four-Coordinate Fe(I)

(2016) Yasuhiro Ohki et al.   ORGANOMETALLICS

Remote Multiproton Storage within a Pyrrolide-Pincer-Type Ligand

(2015) Soufiane S. Nadif et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Mediated Production of Isocyanates, R3ENCO from Dinitrogen, Carbon Dioxide, and R3ECl

(2015) Andrew J. Keane et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Homolytic H2 cleavage by a mercury-bridged Ni(i) pincer complex [{(PNP)Ni}2{μ-Hg}]

(2015) Markus Kreye et al.   CHEMICAL COMMUNICATIONS

Four-Coordinate Iron(II) Diaryl Compounds with Monodentate N-Heterocyclic Carbene Ligation: Synthesis, Characterization, and Their Tetrahedral-Square Planar Isomerization in Solution

(2015) Yuesheng Liu et al.   INORGANIC CHEMISTRY

Evaluating Molecular Cobalt Complexes for the Conversion of N2 to NH3

(2015) Trevor J. Del Castillo et al.   INORGANIC CHEMISTRY

Recent Progress in Transition-Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions

(2015) Yoshiaki Nishibayashi   INORGANIC CHEMISTRY

A Terminal N2 Complex of High-Spin Iron(I) in a Weak, Trigonal Ligand Field

(2015) Alex McSkimming et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diiron Bridged-Thiolate Complexes That Bind N2 at the FeIIFeII, FeIIFeI, and FeIFeI Redox States

(2015) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterization of an Fe≡N–NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3

(2015) John S. Anderson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of Dinitrogen to Ammonia by Use of Molybdenum–Nitride Complexes Bearing a Tridentate Triphosphine as Catalysts

(2015) Kazuya Arashiba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Binding of dinitrogen to an iron–sulfur–carbon site

(2015) Ilija Čorić et al.   NATURE

C–H Bond Activations by Monoanionic, PNP-Supported Scandium Dialkyl Complexes

(2015) Daniel S. Levine et al.   ORGANOMETALLICS

Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site

(2015) Shogo Kuriyama et al.   Chemical Science

Dinitrogen Activation Upon Reduction of a Triiron(II) Complex

(2014) Yousoon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum–Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand

(2014) Shogo Kuriyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A 106-Fold Enhancement in N2-Binding Affinity of an Fe2(μ-H)2 Core upon Reduction to a Mixed-Valence FeIIFeI State

(2014) Jonathan Rittle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Late Metal Scaffolds that Activate Both, Dinitrogen and Reduced Dinitrogen Species NxHy

(2014) Claudia Köthe et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Catalytic C–S Cross-Coupling Reactions Employing Ni Complexes of Pyrrole-Based Pincer Ligands

(2014) Gopaladasu T. Venkanna et al.   ACS Catalysis

Catalytic Reduction of Hydrazine to Ammonia by a Mononuclear Iron(II) Complex on a Tris(thiolato)phosphine Platform

(2013) Ya-Ho Chang et al.   INORGANIC CHEMISTRY

N–N Bond Cleavage of Hydrazines with a Multiproton-Responsive Pincer-Type Iron Complex

(2013) Kazuki Umehara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of N2 to NH3 by an Fe–N2 Complex Featuring a C-Atom Anchor

(2013) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Oxidation and Reduction of Bis(imino)pyridine Iron Dinitrogen Complexes: Evidence for Formation of a Chelate Trianion.

(2012) Aaron M. Tondreau et al.   INORGANIC CHEMISTRY

Bis(imino)pyridine Iron Dinitrogen Compounds Revisited: Differences in Electronic Structure Between Four- and Five-Coordinate Derivatives.

(2012) S. Chantal E. Stieber et al.   INORGANIC CHEMISTRY

Synthesis of Sulfur- and Nitrogen-Bridged Diiron Complexes and Catalytic Behavior toward Hydrazines

(2012) Masahiro Yuki et al.   ORGANOMETALLICS

Synthesis of Bis(N-heterocyclic carbene) Complexes of Iron(II) and Their Application in Hydrosilylation and Transfer Hydrogenation

(2012) Takayoshi Hashimoto et al.   ORGANOMETALLICS

Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions

(2012) Masahiro Yuki et al.   Nature Communications

Homogeneous iron complexes for the conversion of dinitrogen into ammonia and hydrazine

(2010) Nilay Hazari   CHEMICAL SOCIETY REVIEWS

Iron–dinitrogen coordination chemistry: Dinitrogen activation and reactivity

(2010) Justin L. Crossland et al.   COORDINATION CHEMISTRY REVIEWS

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

(2010) Kazuya Arashiba et al.   Nature Chemistry

Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum: Theory versus Experiment

(2008) Richard R. Schrock   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multiple Pathways for Dinitrogen Activation during the Reduction of an Fe Bis(iminepyridine) Complex

(2008) Jennifer Scott et al.   INORGANIC CHEMISTRY

Nitrogenase Model Complexes [Cp*Fe(μ-SR1)2(μ-η2-R2NNH)FeCp*] (R1= Me, Et; R2= Me, Ph; Cp* = η5-C5Me5): Synthesis, Structure, and Catalytic N−N Bond Cleavage of Hydrazines on Diiron Centers

(2008) Yanhui Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY