Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site

Synthesis and Catalytic Activity of Molybdenum-Nitride Complexes Bearing Pincer Ligands

(2015) Eriko Kinoshita et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers

(2015) Nitesh Khoenkhoen et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Catalytic Reduction of Dinitrogen to Ammonia by Use of Molybdenum–Nitride Complexes Bearing a Tridentate Triphosphine as Catalysts

(2015) Kazuya Arashiba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cleavage and Formation of Molecular Dinitrogen in a Single System Assisted by Molybdenum Complexes Bearing Ferrocenyldiphosphine

(2014) Takamasa Miyazaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Ligand Modification Chemistry of a Molybdenum Dinitrogen Complex: Redox and Chemical Activity of a Bis(imino)pyridine Ligand

(2014) Grant W. Margulieux et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox Control of a Dendritic Ferrocenyl-Based Homogeneous Catalyst

(2014) Paul Neumann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photolytic N2Splitting: A Road to Sustainable NH3Production?

(2014) Christophe Rebreyend et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dinitrogen Activation Upon Reduction of a Triiron(II) Complex

(2014) Yousoon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Dinitrogen Reduction at the Molybdenum Center Promoted by a Bulky Tetradentate Phosphine Ligand

(2014) Qian Liao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular electron transfer between molybdenum and iron mimicking bacterial sulphite dehydrogenase

(2014) Kristina Hüttinger et al.   CHEMICAL COMMUNICATIONS

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Challenges in reduction of dinitrogen by proton and electron transfer

(2014) Cornelis J. M. van der Ham et al.   CHEMICAL SOCIETY REVIEWS

Molybdenum Complexes Supported by Mixed NHC/Phosphine Ligands: Activation of N2and Reaction With P(OMe)3to the FirstMeta-Phosphite Complex

(2014) Christian Gradert et al.   CHEMISTRY-A EUROPEAN JOURNAL

How Does Nishibayashi’s Molybdenum Complex Catalyze Dinitrogen Reduction to Ammonia?

(2014) Yong-Hui Tian et al.   INORGANIC CHEMISTRY

Catalytic Hydrogen Evolution by Fe(II) Carbonyls Featuring a Dithiolate and a Chelating Phosphine

(2014) Souvik Roy et al.   INORGANIC CHEMISTRY

Fine-Tuning the Energy Barrier for Metal-Mediated Dinitrogen N≡N Bond Cleavage

(2014) Andrew J. Keane et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum–Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand

(2014) Shogo Kuriyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Multi-iron System Capable of Rapid N2 Formation and N2 Cleavage

(2014) K. Cory MacLeod et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrogen Atom Transfer from a Dinitrogen-Derived Vanadium Nitride Complex to Carbon Monoxide and Isocyanide

(2014) Yutaka Ishida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A 106-Fold Enhancement in N2-Binding Affinity of an Fe2(μ-H)2 Core upon Reduction to a Mixed-Valence FeIIFeI State

(2014) Jonathan Rittle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox Control of Group 4 Metal Ring-Opening Polymerization Activity toward l-Lactide and ε-Caprolactone

(2014) Xinke Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium

(2014) Isabel Klopsch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of Molybdenum-Dinitrogen Complexes Bearing PNN-Type Pincer Ligand

(2014) Kazuya Arashiba et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Late Metal Scaffolds that Activate Both, Dinitrogen and Reduced Dinitrogen Species NxHy

(2014) Claudia Köthe et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Preparation and reactivity of molybdenum–dinitrogen complexes bearing an arsenic-containing ANA-type pincer ligand

(2013) Yoshiaki Tanabe et al.   CHEMICAL COMMUNICATIONS

N2 coordination

(2013) Michael D. Fryzuk   CHEMICAL COMMUNICATIONS

Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1′-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

(2013) Shishir Ghosh et al.   CHEMICAL COMMUNICATIONS

Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen

(2013) Hong-Peng Jia et al.   CHEMICAL SOCIETY REVIEWS

Design and Preparation of Molybdenum-Dinitrogen Complexes with Ferrocenyldiphosphine and Pentamethylcyclopentadienyl Moieties as Auxiliary Ligands

(2013) Takamasa Miyazaki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Developing more sustainable processes for ammonia synthesis

(2013) Yoshiaki Tanabe et al.   COORDINATION CHEMISTRY REVIEWS

Synthesis and study of olefin metathesis catalysts supported by redox-switchable diaminocarbene[3]ferrocenophanes

(2013) C. Daniel Varnado et al.   DALTON TRANSACTIONS

Second Sphere Control of Redox Catalysis: Selective Reduction of O2 to O2– or H2O by an Iron Porphyrin Catalyst

(2013) Subhra Samanta et al.   INORGANIC CHEMISTRY

Dinitrogen Reduction by a Chromium(0) Complex Supported by a 16-Membered Phosphorus Macrocycle

(2013) Michael T. Mock et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of a Base-Free Hafnium Nitride from N2 Cleavage: A Versatile Platform for Dinitrogen Functionalization

(2013) Scott P. Semproni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

X-ray Spectroscopic Observation of an Interstitial Carbide in NifEN-Bound FeMoco Precursor

(2013) Kyle M. Lancaster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of N2 to NH3 by an Fe–N2 Complex Featuring a C-Atom Anchor

(2013) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron

(2013) K. Cory MacLeod et al.   Nature Chemistry

Fe-N2/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco)

(2013) J. Rittle et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Dinitrogen Cleavage and Hydrogenation by a Trinuclear Titanium Polyhydride Complex

(2013) T. Shima et al.   SCIENCE

Redox-Active Ligands in Catalysis

(2012) Vijayendran K. K. Praneeth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-active ligands in catalysis

(2012) Oana R. Luca et al.   CHEMICAL SOCIETY REVIEWS

Asymmetric Mixed-Valence Complexes that Consist of Cyclometalated Ruthenium and Ferrocene: Synthesis, Characterization, and Electronic-Coupling Studies

(2012) Si-Hai Wu et al.   Chemistry-An Asian Journal

Molybdenum(0) dinitrogen complexes with polydentate phosphine ligands for synthetic nitrogen fixation: Geometric and electronic structure contributions to reactivity

(2012) Henning Broda et al.   COORDINATION CHEMISTRY REVIEWS

Synthesis and Catalytic Activity of Molybdenum–Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands

(2012) Eriko Kinoshita et al.   ORGANOMETALLICS

Radical SAM-Dependent Carbon Insertion into the Nitrogenase M-Cluster

(2012) J. A. Wiig et al.   SCIENCE

Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions

(2012) Masahiro Yuki et al.   Nature Communications

Redox control of a polymerization catalyst by changing the oxidation state of the metal center

(2011) Erin M. Broderick et al.   CHEMICAL COMMUNICATIONS

Redox Control of a Ring-Opening Polymerization Catalyst

(2011) Erin M. Broderick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands

(2011) Hiromasa Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combining acid–base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase

(2011) James M. Camara et al.   Nature Chemistry

Alkynyl-Bridged Ruthenium(II) 4′-Diferrocenyl-2,2′:6′,2′′-terpyridine Electron Transfer Complexes: Synthesis, Structures, and Electrochemical and Spectroscopic Studies

(2011) Kai-Qiang Wu et al.   ORGANOMETALLICS

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

(2011) T. Spatzal et al.   SCIENCE

X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

(2011) K. M. Lancaster et al.   SCIENCE

Arrested Catalysis: Controlling Kumada Coupling Activity via a Redox-Active N-Heterocyclic Carbene

(2010) Andrew G. Tennyson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

(2010) Kazuya Arashiba et al.   Nature Chemistry

Ferrocene Redox Controlled Reversible Immobilization of Ruthenium Carbene in Ionic Liquid: A Versatile Catalyst for Ring-Closing Metathesis

(2009) Guiyan Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

One-Electron Oxidation of Ruthenocene: Reactions of the Ruthenocenium Ion in Gentle Electrolyte Media

(2009) Jannie C. Swarts et al.   INORGANIC CHEMISTRY

Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum: Theory versus Experiment

(2008) Richard R. Schrock   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION