Nickel-Catalyzed Allylic C(sp2)-H Activation: Stereoselective Allyl Isomerization and Regiospecific Allyl Arylation of Allylarenes

Ni-Catalyzed cross coupling of aryl grignard reagents with aryl halides in a nonpolar solvent and an efficient synthesis of biaryls under neat conditions

(2016) Qiang Wu et al.   CHEMICAL RESEARCH IN CHINESE UNIVERSITIES

Pd-Catalyzed α-Selective C–H Functionalization of Olefins: En Route to 4-Imino-β-Lactams

(2016) Wei-Jun Kong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Two-State Reactivity in Low-Valent Iron-Mediated C–H Activation and the Implications for Other First-Row Transition Metals

(2016) Yihua Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalyzed arylation of heteroaryl-containing diarylmethanes: exceptional reactivity of the Ni(NIXANTPHOS)-based catalyst

(2016) Xinyu Cao et al.   Chemical Science

Recent developments in low-cost TM-catalyzed Heck-type reactions (TM = transition metal, Ni, Co, Cu, and Fe)

(2016) Sa-Sa Wang et al.   Catalysis Science & Technology

Aqueous Titanium Trichloride Promoted Reductive Cyclization ofo-Nitrostyrenes to Indoles: Development and Application to the Synthesis of Rizatriptan and Aspidospermidine

(2015) Shuo Tong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective aerobic oxidative Heck reactions with electronically unbiased alkenes: efficient access to α-alkyl vinylarenes

(2015) Changwu Zheng et al.   CHEMICAL COMMUNICATIONS

Isomerization of Allylbenzenes

(2015) Mohammad Hassam et al.   CHEMICAL REVIEWS

Oxidative Olefination of Anilides with Unactivated Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Complex Under Ambient Conditions

(2015) Yuji Takahama et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Understanding of Transition-Metal-Catalyzed Olefin Isomerization: Metal-Hydride Insertion-Elimination vs. π-Allyl Pathways

(2015) Soumik Biswas   COMMENTS ON INORGANIC CHEMISTRY

Nickel-Catalyzed Alkynylation of a C(sp2)–H Bond Directed by an 8-Aminoquinoline Moiety

(2015) Jun Yi et al.   JOURNAL OF ORGANIC CHEMISTRY

Cp*Ir(III)-Catalyzed Mild and Broad C−H Arylation of Arenes and Alkenes with Aryldiazonium Salts Leading to the External Oxidant-Free Approach

(2015) Kwangmin Shin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Double-Bond Isomerization: Highly Reactive Nickel Catalyst Applied in the Synthesis of the Pheromone (9Z,12Z)-Tetradeca-9,12-dienyl Acetate

(2015) Felicia Weber et al.   ORGANIC LETTERS

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Palladium-Catalysed, Directed CH Coupling with Organometallics

(2014) Ramesh Giri et al.   ADVANCED SYNTHESIS & CATALYSIS

An Alternative Mechanism for the Cobalt-Catalyzed Isomerization of Terminal Alkenes to (Z)-2-Alkenes

(2014) Anastasia Schmidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Mizoroki-Heck Reaction of Aryl Sulfonates and Chlorides with Electronically Unbiased Terminal Olefins: High Selectivity for Branched Products

(2014) Sarah Z. Tasker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed C(sp2)H and C(sp3)H Arylation by Triazole Assistance

(2014) Qing Gu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Double Bond Isomerisation and Migration-New Playgrounds for Transition Metal-Catalysis

(2014) Gerhard Hilt   ChemCatChem

Alkylation of Pyridines at Their 4-Positions with Styrenes plus Yttrium Reagent or Benzyl Grignard Reagents

(2014) Tomoya Mizumori et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkene Isomerization-Hydroarylation Tandem Catalysis: Indole C2-Alkylation with Aryl-Substituted Alkenes Leading to 1,1-Diarylalkanes

(2014) Takeshi Yamakawa et al.   Chemistry-An Asian Journal

Ruthenium-Catalyzed One-Pot Synthesis of (E)-(2-Arylvinyl)boronates through an Isomerization/Cross-Metathesis Sequence from Allyl-Substituted Aromatics

(2014) Rémy Hemelaere et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Cross-Coupling of Vinylarenes with Arylaluminum Reagents in the Presence of Ketones

(2014) Shota Tanaka et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Diarylrhodates as Promising Active Catalysts for the Arylation of Vinyl Ethers with Grignard Reagents

(2014) Takanori Iwasaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Z-Selective Alkene Isomerization by High-Spin Cobalt(II) Complexes

(2014) Chi Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Directed Alkylation of Aromatic and Olefinic Carboxamides with Primary and Secondary Alkyl Tosylates, Mesylates, and Halides

(2014) Laurean Ilies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed C(sp2)–H Bond Functionalization with Organoboron Compounds

(2014) Rui Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope and Mechanism in Palladium-Catalyzed Isomerizations of Highly Substituted Allylic, Homoallylic, and Alkenyl Alcohols

(2014) Evgeny Larionov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Mechanistic Studies of Alkene Isomerization Catalyzed by CCC-Pincer Complexes of Iridium

(2014) Spring Melody M. Knapp et al.   ORGANOMETALLICS

Easy access to enamides: a mild nickel-catalysed alkene isomerization of allylamides

(2013) Lu Wang et al.   CHEMICAL COMMUNICATIONS

Nickel-Catalyzed Direct Alkylation of C–H Bonds in Benzamides and Acrylamides with Functionalized Alkyl Halides via Bidentate-Chelation Assistance

(2013) Yoshinori Aihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Allylic Arylation of Olefins via C(sp3)–H Activation under Mild Conditions

(2013) Masaki Sekine et al.   ORGANIC LETTERS

Tandem Isomerization and C–H Activation: Regioselective Hydroheteroarylation of Allylarenes

(2013) Wei-Chih Lee et al.   ORGANIC LETTERS

Modular Palladium Bipyrazoles for the Isomerization of Allylbenzenes - Mechanistic Considerations and Insights into Catalyst Design and Activity, Role of Solvent, and Additive Effects

(2012) Markus J. Spallek et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed, Highly Efficient, Regiocontrolled Arylation of Electron-Rich Allylamines with Aryl Halides

(2012) Yuheng Deng et al.   ADVANCED SYNTHESIS & CATALYSIS

Intermolecular Mizoroki-Heck Reaction of Aliphatic Olefins with High Selectivity for Substitution at the Internal Position

(2012) Liena Qin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Benign Catalysis with Iron: Unique Selectivity in Catalytic Isomerization Reactions of Olefins

(2012) Reiko Jennerjahn et al.   ChemSusChem

Direct Arylation/Alkylation/Magnesiation of Benzyl Alcohols in the Presence of Grignard Reagents via Ni-, Fe-, or Co-Catalyzed sp3 C–O Bond Activation

(2012) Da-Gang Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Titanium-Mediated Oxidative Arylation of Homoallylic Alcohols

(2011) Kathleen S. Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

“Ligand-Consuming” Formation of Rhodium-Hydride Species from [Rh(OH)(cod)]2 Without any Additional Hydride Sources for Catalytic Olefin Isomerizations and Cyclobutene Synthesis

(2011) Ken Motokura et al.   ChemCatChem

Iron-Catalyzed Isomerizations of Olefins

(2011) Matthias Mayer et al.   ChemCatChem

Iron-Catalyzed Stereospecific Activation of Olefinic C–H Bonds with Grignard Reagent for Synthesis of Substituted Olefins

(2011) Laurean Ilies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed C–H/C–O Coupling of Azoles with Phenol Derivatives

(2011) Kei Muto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Chelation-Assisted Transformations Involving Ortho C–H Bond Activation: Regioselective Oxidative Cycloaddition of Aromatic Amides to Alkynes

(2011) Hirotaka Shiota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-catalyzed estragole isomerization: high trans-selective formation of anethole

(2010) Beatriz Lastra-Barreira et al.   GREEN CHEMISTRY

In Situ Generated Bulky Palladium Hydride Complexes as Catalysts for the Efficient Isomerization of Olefins. Selective Transformation of Terminal Alkenes to 2-Alkenes

(2010) Delphine Gauthier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed, Directed Oxidative Arylation of Olefins with Organozinc and Grignard Reagents

(2010) Laurean Ilies et al.   ORGANIC LETTERS

Highly Active and Selective Platinum(II)-Catalyzed Isomerization of Allylbenzenes: Efficient Access to (E)-Anethole and Other Fragrances via Unusual Agostic Intermediates

(2010) Alessandro Scarso et al.   ORGANOMETALLICS

DFT Calculations of the Isomerization of 2-Methyl-3-butenenitrile by [Ni(bisphosphine)] in Relation to the DuPont Adiponitrile Process

(2010) Ting Li et al.   ORGANOMETALLICS

Transition-Metal-Catalyzed Oxidative Heck Reactions

(2010) Babak Karimi et al.   SYNTHESIS-STUTTGART

Cobalt-Catalyzed Isomerization of 1-Alkenes to (E)-2-Alkenes with Dimethylphenylsilylmethylmagnesium Chloride and Its Application to the Stereoselective Synthesis of (E)-Alkenylsilanes

(2009) Tsuneyuki Kobayashi et al.   Chemistry-An Asian Journal

Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination ofN-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides

(2009) Takuji Hatakeyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

One-Pot Desymmetrizing Hydroformylation/Carbonyl Ene Cyclization Process: Straightforward Access to Highly Functionalized Cyclohexanols

(2008) Aurélien Bigot et al.   ORGANIC LETTERS