Fluorinated Ketones as Trapping Reagents for Visible-Light-Induced Singlet Nucleophilic Carbenes

Cooperative Catalysis for the Highly Diastereo- and Enantioselective [4+3]-Cycloannulation of ortho -Quinone Methides and Carbonyl Ylides

(2020) Arun Suneja et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Direct Aldol Addition of Aryl Ketones to α-Fluorinated Ketones

(2020) Connor J. Thomson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silicon‐Derived Singlet Nucleophilic Carbene Reagents in Organic Synthesis

(2020) Daniel L. Priebbenow   ADVANCED SYNTHESIS & CATALYSIS

Tandem Photoredox Catalysis: Enabling Carbonylative Amidation of Aryl and Alkylhalides

(2020) Anastasios Polyzos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Diastereoselective [3 + 2] Cycloaddition of Carbonyl Ylide: An Access to the Core Ring System of Cordigol and Lophirone H

(2020) Manickam Bakthadoss et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Catalytic Asymmetric Aldol Reaction of α-Alkoxyamides to α-Fluorinated Ketones

(2019) Roman Pluta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Scope and Limitations of TBA[Fe]‐catalyzed Carbene Transfer to X−H‐bonds – Indication of a Mechanistic Dichotomy

(2019) Annika Röske et al.   ChemCatChem

Insights into the Stability of Siloxy Carbene Intermediates and Their Corresponding Oxocarbenium Ions

(2019) Daniel L. Priebbenow   JOURNAL OF ORGANIC CHEMISTRY

Efficient Generation and Synthetic Applications of Alkyl‐Substituted Siloxycarbenes: Suppression of Norrish‐type Fragmentations of Alkanoylsilanes by Triplet Energy Transfer

(2019) Kento Ishida et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-Light-Induced, Metal-Free Carbene Insertion into B–H Bonds between Acylsilanes and Pinacolborane

(2019) Jian-Heng Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Continuous-flow photochemical carbene transfer reactions

(2019) Claire Empel et al.   Journal of Flow Chemistry

N-Heterocyclic Carbene Catalysis via Azolium Dienolates: An Efficient Strategy for Remote Enantioselective Functionalizations

(2018) Xiang-Yu Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photocatalytic and Chemoselective Transfer Hydrogenation of Diarylimines in Batch and Continuous Flow

(2018) Dean J. van As et al.   ORGANIC LETTERS

Recent Advances in Catalytic Asymmetric Synthesis of Tertiary Alcohols via Nucleophilic Addition to Ketones

(2018) Yun-Lin Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

A Catalytic Strategy for α,ω-Functionalization: NHC-Mediated Fragmentation/Umpolung Cascades to Access Hydroxytrifluoromethyl Ynones and Allenones

(2018) Christoph Selg et al.   ChemCatChem

Organocatalytic Enantioselective Cross-Aldol Reaction of o-Hydroxyarylketones and Trifluoromethyl Ketones

(2017) Pei Wang et al.   ORGANIC LETTERS

Applications of Continuous-Flow Photochemistry in Organic Synthesis, Material Science, and Water Treatment

(2016) Dario Cambié et al.   CHEMICAL REVIEWS

Transition-Metal-Free Diastereoselective Epoxidation of Trifluoromethylketones with N-Tosylhydrazones: Access to Tetrasubstituted Trifluoromethylated Oxiranes

(2016) Chuanle Zhu et al.   ORGANIC LETTERS

Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals

(2015) Bin Rao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acylsilanes in Iridium-Catalyzed Directed Amidation Reactions and Formation of Heterocycles via Siloxycarbenes

(2015) Peter Becker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Tertiary Propargylic Alcohols under N-Heterocyclic Carbene Catalysis

(2015) Eduardo Sánchez-Díez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nucleophilic Intermolecular Chemistry and Reactivity of Dimethylcarbene

(2015) Hui Cang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon–carbon bond activation of cyclobutenones enabled by the addition of chiral organocatalyst to ketone

(2015) Bao-Sheng Li et al.   Nature Communications

Synthesis ofα-Siloxyamides by the Reaction of a Carbamoylsilane with Ketones

(2015) Yuan Yao et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Acylsilanes in Rhodium(III)-Catalyzed Directed Aromatic C-H Alkenylations and Siloxycarbene Reactions with CC Double Bonds

(2013) Peter Becker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acylsilanes: valuable organosilicon reagents in organic synthesis

(2013) Hui-Jun Zhang et al.   CHEMICAL SOCIETY REVIEWS

Acyl anion free N-heterocyclic carbene organocatalysis

(2013) Sarah J. Ryan et al.   CHEMICAL SOCIETY REVIEWS

Photochemical Intermolecular Silylacylations of Electron-Deficient Internal Alkynes

(2013) Peter Becker et al.   JOURNAL OF ORGANIC CHEMISTRY

Photochemically Induced Silylacylations of Alkynes with Acylsilanes

(2012) Hui-Jun Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Flow photochemistry: Old light through new windows

(2012) Jonathan P Knowles et al.   Beilstein Journal of Organic Chemistry

Organocatalytic umpolung: N-heterocyclic carbenes and beyond

(2012) Xavier Bugaut et al.   CHEMICAL SOCIETY REVIEWS

Highly Enantioselective Organocatalytic Trifluoromethyl Carbinol Synthesis—A Caveat on Reaction Times and Product Isolation

(2012) Nongnaphat Duangdee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Kinetic Resolution of Cyclic Secondary Amines

(2011) Michael Binanzer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemically Promoted Transition Metal-Free Cross-Coupling of Acylsilanes with Organoboronic Esters

(2011) Kazuta Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-(Heteroarenesulfonyl)prolinamides-Catalyzed Aldol Reaction between Acetone and Aryl Trihalomethyl Ketones

(2011) Noriyuki Hara et al.   ORGANIC LETTERS

N-heterocyclic carbene catalysed asymmetric cross-benzoin reactions of heteroaromatic aldehydes with trifluoromethyl ketones

(2010) Dieter Enders et al.   CHEMICAL COMMUNICATIONS

Photochemical Synthesis of Nucleoside Analogues from Cyclobutanones: Bicyclic and Isonucleosides

(2010) Mileina Jaffer et al.   MOLECULES

A Direct Intermolecular Cross-Benzoin Type Reaction: N-Heterocyclic Carbene-Catalyzed Coupling of Aromatic Aldehydes with Trifluoromethyl Ketones

(2009) Dieter Enders et al.   ADVANCED SYNTHESIS & CATALYSIS

Persistent Triplet Carbenes

(2009) Katsuyuki Hirai et al.   CHEMICAL REVIEWS

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Catalytic Intermolecular Aldehyde−Ketone Coupling via Acyl Phosphonates

(2009) Ayhan S. Demir et al.   JOURNAL OF ORGANIC CHEMISTRY

α′-Hydroxyenones as Mechanistic Probes and Scope-Expanding Surrogates for α,β-Unsaturated Aldehydes in N-Heterocyclic Carbene-Catalyzed Reactions

(2009) Pei-Chen Chiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Most Powerful Chemical Traps for Bis(methoxycarbonyl)carbene (=2-Methoxy-1-(methoxycarbonyl)-2-oxoethylidene)

(2008) Vladimir V. Shevchenko et al.   HELVETICA CHIMICA ACTA

Rearrangement of Biaryl Monoaminocarbenes via Concerted Asynchronous Insertion into Aromatic C−H Bonds

(2008) Joan Vignolle et al.   ORGANIC LETTERS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS