Acylsilanes: valuable organosilicon reagents in organic synthesis

Brook silenes: inspiration for a generation

(2013) Kim M. Baines   CHEMICAL COMMUNICATIONS

Synthesis of 2-hydroxymalonamides from Carbamoylsilane and A-keto Carboxamides

(2013) Xiao Juan Chen et al.   MENDELEEV COMMUNICATIONS

Synthesis of Acylsilanes via Nickel-Catalyzed Reactions of α-Hydroxyallylsilanes

(2013) Gangireddy PavanKumar Reddy et al.   ORGANIC LETTERS

Regio- and stereoselective preparation of (Z)-silyl enol ethers by three-component coupling using α,β-unsaturated acylsilanes as core building blocks

(2013) Akira Tsubouchi et al.   TETRAHEDRON LETTERS

Photochemically Induced Silylacylations of Alkynes with Acylsilanes

(2012) Hui-Jun Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Silyl Glyoxylates. Conception and Realization of Flexible Conjunctive Reagents for Multicomponent Coupling

(2012) Gregory R. Boyce et al.   JOURNAL OF ORGANIC CHEMISTRY

Intramolecular σ-Bond Metathesis Between Carbon–Carbon and Silicon–Silicon Bonds

(2012) Naoki Ishida et al.   ORGANIC LETTERS

Serine Protease Inhibition by a Silanediol Peptidomimetic

(2012) Swapnil Singh et al.   ORGANIC LETTERS

Computational Investigation of Brook-Type Silabenzenes and Their Possible Formation through [1,3]-Si→O Silyl Shifts

(2012) Alvi Muhammad Rouf et al.   ORGANOMETALLICS

[1,2]- and [1,4]-Wittig rearrangements of α-alkoxysilanes: effect of substitutions at both the migrating benzylic carbon and the terminal sp2 carbon of the allyl moiety

(2012) Edith N. Onyeozili et al.   TETRAHEDRON

A Lewis acid-promoted reduction of acylsilanes to α-hydroxysilanes by diethylzinc

(2012) Guang Gao et al.   TETRAHEDRON LETTERS

Enantioselective Synthesis of Siloxyallenes from Alkynoylsilanes by Reduction and a Brook Rearrangement and Their Subsequent Trapping in a [4+2] Cycloaddition

(2011) Michiko Sasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Acylsilanes by Palladium-catalyzed Cross-coupling Reaction of Thiol Esters and Silylzinc Chlorides

(2011) Hiroki Azuma et al.   CHEMISTRY LETTERS

A facile tandem reaction to access β-hydroxy-α,α-difluoroketone derivatives catalyzed by titanocene dichloride/magnesium

(2011) Lei Wu   JOURNAL OF FLUORINE CHEMISTRY

Asymmetric Synthesis ofcis-2-Aminocyclopropanols by Intramolecular Mannich Addition of Silyloxy Benzyl Carbanions

(2011) Bo Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Quantum chemical study on the mechanism of intramolecular cyclization of 2-benzyloxyphenyl trimethylsilyl ketone to give the benzofuran derivatives

(2011) Dinglong Cai et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Photochemically Promoted Transition Metal-Free Cross-Coupling of Acylsilanes with Organoboronic Esters

(2011) Kazuta Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversed-Polarity Synthesis of Diaryl Ketones via Palladium-Catalyzed Cross-Coupling of Acylsilanes

(2011) Jason R. Schmink et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of acylsilanes with α-sulfinyl carbanions: regioselective synthesis of silyl enol ethers

(2011) Mitsunori Honda et al.   TETRAHEDRON LETTERS

A highly stereoselective approach to tetrasubstituted (E)-β-hydroxy silyl enol ethers by addition of aryl-substituted oxiranyl anions to acylsilanes

(2011) Cheng Wang et al.   TETRAHEDRON LETTERS

Palladium-catalyzed carbonylative coupling reactions of aryl iodides with hexamethyldisilane (HMDS) to benzoyl silanes

(2011) Xiao-Feng Wu et al.   TETRAHEDRON LETTERS

Applications of CeCl3as an Environmental Friendly Promoter in Organic Chemistry

(2010) Giuseppe Bartoli et al.   CHEMICAL REVIEWS

Formal Total Syntheses of (+)-Prelaureatin and (+)-Laurallene by Diastereoselective Brook Rearrangement-Mediated [3 + 4] Annulation

(2010) Michiko Sasaki et al.   JOURNAL OF ORGANIC CHEMISTRY

Lanthanum Tricyanide-Catalyzed Acyl Silane−Ketone Benzoin Additions and Kinetic Resolution of Resultant α-Silyloxyketones

(2010) James C. Tarr et al.   JOURNAL OF ORGANIC CHEMISTRY

A Novel Utilization of Acylsilanes in Organic Synthesis

(2010) Mitsunori Honda et al.   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates

(2010) Jian-Ping Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of trifluoromethyl cyclohexyl, cyclohexenyl and aryl compounds via stepwise Robinson annulation

(2010) Fabien Massicot et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Brønsted Acid Catalyzed Asymmetric Reduction of Ketones and Acyl Silanes Using Chiralanti-Pentane-2,4-diol

(2010) Jun-ichi Matsuo et al.   ORGANIC LETTERS

(Selenocarbamoyl)silanes and -germanes: Their Synthesis Using (Selenocarbamoyl)lithium and Characterization

(2010) Toshiaki Murai et al.   ORGANOMETALLICS

Asymmetric reduction of aliphatic ketones and acyl silanes using chiral anti-pentane-2,4-diol and a catalytic amount of 2,4-dinitrobenzenesulfonic acid

(2010) Jun-ichi Matsuo et al.   TETRAHEDRON

Diastero- and enantioselective intramolecular carbometalation reaction

(2010) Rozalia Unger et al.   TETRAHEDRON

Radical cyclizations of acylsilanes in the synthesis of (+)-swainsonine and formal synthesis of (−)-epiquinamide

(2010) Ming-Jen Chen et al.   TETRAHEDRON

Zinc-Salen-Catalyzed Asymmetric Alkynylation of Alkyl Acylsilanes

(2009) Feng-Quan Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Natural Product Synthesis Using Multicomponent Reaction Strategies

(2009) Barry B. Touré et al.   CHEMICAL REVIEWS

Tandem Zn-Brook Rearrangement/Ene-Allene Carbocyclization

(2009) Rozalia Unger et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Amide Enolate Additions to Acylsilanes: In Situ Generation of Unusual and Stereoselective Homoenolate Equivalents

(2009) Robert B. Lettan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lanthanum Tricyanide-Catalyzed Acyl Silane−Ketone Benzoin Additions

(2009) James C. Tarr et al.   ORGANIC LETTERS

Enantio- and Diastereoselective Tandem Zn-Promoted Brook Rearrangement/Ene−Allene Carbocyclization Reaction

(2009) Rozalia Unger et al.   ORGANIC LETTERS

CuBr-Catalyzed Oxidative Difluoromethylation of Tertiary Amines with Difluoroenol Silyl Ethers

(2009) Lingling Chu et al.   ORGANIC LETTERS

The synthesis of carbohydrate-derived acylsilanes and their intramolecular free radical cyclizations with the formation of polyoxygenated cyclopentanes

(2009) Che-Chien Chang et al.   TETRAHEDRON LETTERS

Asymmetric Hydrogenation of Aromatic, Aliphatic, and α,β-Unsaturated Acyl Silanes Catalyzed by Tol-binap/Pica Ruthenium(II) Complexes: Practical Synthesis of Optically Active α-Hydroxysilanes

(2008) Noriyoshi Arai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Benzofurans Prepared by CH Bond Functionalization with Acylsilanes

(2008) Zengming Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New 6-oxa-2-silabicyclo[2.2.0]hexanes by photochemical conversion of acyl(allyl)(dimethyl)silanes

(2008) Catherine Hammaecher et al.   CHEMICAL COMMUNICATIONS

Umpolung Reactivity of Difluoroenol Silyl Ethers with Amines and Amino Alcohols. Application to the Synthesis of Enantiopure α-Difluoromethyl Amines and Amino Acids

(2008) Florent Huguenot et al.   JOURNAL OF ORGANIC CHEMISTRY

Simple Enantioselective Approach to Synthetic Limonoids

(2008) Douglas C. Behenna et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereoselective Brook Rearrangement-Mediated [3 + 4] Annulation: Application to a Formal Synthesis of (+)-Laurallene

(2008) Michiko Sasaki et al.   ORGANIC LETTERS

Silenes: Connectors between classical alkenes and nonclassical heavy alkenes

(2007) Henrik Ottosson et al.   COORDINATION CHEMISTRY REVIEWS