Scope and Limitations of TBA[Fe]‐catalyzed Carbene Transfer to X−H‐bonds – Indication of a Mechanistic Dichotomy

The Generation of Diazo Compounds in Continuous-Flow

(2018) Katharina J. Hock et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron Porphyrin Catalyzed Insertion Reaction of N-Tosylhydrazone-Derived Carbenes into X–H (X = Si, Sn, Ge) Bonds

(2018) En-Hui Wang et al.   ORGANIC LETTERS

Copper-Catalyzed Carbenoid Insertion Reactions of α-Diazoesters and α-Diazoketones into Si–H and S–H Bonds

(2017) Hoda Keipour et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium catalyzed acceptor/acceptor carbene insertion into N–H bonds in water

(2017) Kankanala Ramakrishna et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iron-Catalyzed Carbene Insertion Reactions of α-Diazoesters into Si–H Bonds

(2017) Hoda Keipour et al.   ORGANIC LETTERS

Reactivity Comparison of Primary Aromatic Amines and Thiols in E–H Insertion Reactions with Diazoacetates Catalyzed by Iridium(III) Tetratolylporphyrin

(2017) Bernie J. Anding et al.   ORGANOMETALLICS

Copper-Catalyzed Insertion into Heteroatom-Hydrogen Bonds with Trifluorodiazoalkanes

(2016) Stephen Hyde et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of α-Mercapto-β-amino Esters via Rh(II)/Chiral Phosphoric Acid-Cocatalyzed Three-Component Reaction of Diazo Compounds, Thiols, and Imines

(2016) Guolan Xiao et al.   ORGANIC LETTERS

Iron bis(oxazoline) complexes in asymmetric catalysis

(2016) Thierry Ollevier   Catalysis Science & Technology

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

Iron Catalysis in Organic Synthesis

(2015) Ingmar Bauer et al.   CHEMICAL REVIEWS

Elevated Catalytic Activity of Ruthenium(II)-Porphyrin-Catalyzed Carbene/Nitrene Transfer and Insertion Reactions with N-Heterocyclic Carbene Ligands

(2014) Ka-Ho Chan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-catalyzed transformations of diazo compounds

(2014) Shou-Fei Zhu et al.   National Science Review

Catalytic X–H insertion reactions based on carbenoids

(2013) Dennis Gillingham et al.   CHEMICAL SOCIETY REVIEWS

Combined C–H functionalization/O–H insertion reaction to form tertiary β-alkoxy substituted β-aminophosphonates catalyzed by [Cu(MeCN)4]PF6

(2013) Yan Cai et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iron Porphyrin-Catalyzed Three-Component Reaction of Ethyl Diazoacetate with Aliphatic Amines and β,γ-Unsaturated α-Keto Esters

(2013) Chaoqun Ma et al.   ORGANIC LETTERS

Highly enantioselective S–H bond insertion cooperatively catalyzed by dirhodium complexes and chiral spiro phosphoric acids

(2013) Bin Xu et al.   Chemical Science

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

(2012) Shou-Fei Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Activation of Diazo Compounds Using Electron-Rich, Defined Iron Complexes for Carbene-Transfer Reactions

(2012) Michael S. Holzwarth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand

(2012) Jing-Cui Wang et al.   CHEMICAL COMMUNICATIONS

Preparation of Trifluoromethyl-Substituted Aziridines with in Situ Generated CF3CHN2

(2012) Stefan A. Künzi et al.   ORGANIC LETTERS

Iron-Catalyzed Cyclopropanation in 6 M KOH with in Situ Generation of Diazomethane

(2012) B. Morandi et al.   SCIENCE

The arene–alkene photocycloaddition

(2011) Ursula Streit et al.   Beilstein Journal of Organic Chemistry

Selective functionalisation of saturated C–H bonds with metalloporphyrin catalysts

(2011) Chi-Ming Che et al.   CHEMICAL SOCIETY REVIEWS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Iron-Catalyzed Preparation of Trifluoromethyl Substituted Vinyl- and Alkynylcyclopropanes

(2011) Bill Morandi et al.   ORGANIC LETTERS

Enantioselective Cobalt-Catalyzed Preparation of Trifluoromethyl-Substituted Cyclopropanes

(2010) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Cyclopropenation of Alkynes: Synthesis of Trifluoromethyl-Substituted Cyclopropenes

(2010) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

O-H insertion and tandem N-H insertion/cyclization reactions using an iron porphyrin as catalyst with diazo compounds as carbene sources

(2010) Harun M. Mbuvi et al.   JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

Enantioselective iron-catalysed O–H bond insertions

(2010) Shou-Fei Zhu et al.   Nature Chemistry

Chemical reactivity of 6-diazo-5-oxo-l-norleucine (DON) catalyzed by metalloporphyrins (Fe,Ru)

(2010) Paul Le Maux et al.   TETRAHEDRON

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Application of donor/acceptor-carbenoids to the synthesis of natural products

(2009) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Iron(III) Corroles and Porphyrins as Superior Catalysts for the Reactions of Diazoacetates with Nitrogen- or Sulfur-Containing Nucleophilic Substrates: Synthetic Uses and Mechanistic Insights

(2008) Iris Aviv et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE