Pd/Cu-Catalyzed C–H/C–H Cross Coupling of (Hetero)Arenes with Azoles through Arylsulfonium Intermediates

Catalytic Transformations of Sulfonium Salts via C‐S Bond Activation

(2021) Hideki Yorimitsu   CHEMICAL RECORD

Radical C–C bond formation using sulfonium salts and light

(2020) Aron Peter et al.   ADVANCED SYNTHESIS & CATALYSIS

Ni-Catalyzed Carboxylation of C(sp2)–S Bonds with CO2: Evidence for the Multifaceted Role of Zn

(2020) Tomoyuki Yanagi et al.   ACS Catalysis

Metal-free photoredox-catalysed formal C–H/C–H coupling of arenes enabled by interrupted Pummerer activation

(2020) Miles H. Aukland et al.   Nature Catalysis

Synthetic Applications of Sulfonium Salts

(2020) Manuel Alcarazo et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Site-Selective C–H Functionalization–Sulfination Sequence to Access Aryl Sulfonamides

(2020) Eva Maria Alvarez et al.   ORGANIC LETTERS

A leap forward in sulfonium salt and sulfur ylide chemistry

(2020) Rong Fan et al.   CHINESE CHEMICAL LETTERS

Germylation of Arenes via Pd(I) Dimer Enabled Sulfonium Salt Functionalization

(2020) Aymane Selmani et al.   ORGANIC LETTERS

Site-Selective Silylation of Arenes Mediated by Thianthrene S-Oxide

(2020) Yichen Wu et al.   ORGANIC LETTERS

Thianthrenation-Enabled α-Arylation of Carbonyl Compounds with Arenes

(2020) Xiao-Xue Nie et al.   ORGANIC LETTERS

Construction of 2-(2-Arylphenyl)azoles via Cobalt-Catalyzed C–H/C–H Cross-Coupling Reactions and Evaluation of Their Antifungal Activity

(2020) Xinmou Wang et al.   ORGANIC LETTERS

Site-selective and versatile aromatic C−H functionalization by thianthrenation

(2019) Florian Berger et al.   NATURE

Base‐Mediated O‐Arylation of Alcohols and Phenols by Triarylsulfonium Triflates

(2019) Xiao‐Xia Ming et al.   Chemistry-An Asian Journal

Transition-Metal-Free Aryl–Heteroatom Bond Formation via C–S Bond Cleavage

(2019) Jian-Nan Zhao et al.   ORGANIC LETTERS

Aryl Sulfonium Salts for Site-Selective Late-Stage Trifluoromethylation

(2019) Fei Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective C−H Oxygenation via Aryl Sulfonium Salts

(2019) Ruocheng Sang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Structure, and Reactivity of 5-(Aryl)dibenzothiophenium Triflates

(2019) Kevin Kafuta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox catalysis with aryl sulfonium salts enables site-selective late-stage fluorination

(2019) Jiakun Li et al.   Nature Chemistry

Para-selective borylation of monosubstituted benzenes using a transient mediator

(2019) Jie Wu et al.   Science China-Chemistry

Pd/Cu bimetallic co-catalyzed direct 2-arylation of benzoxazole with aryl chloride

(2019) Ling-Li Zheng et al.   TETRAHEDRON LETTERS

Transition Metal-Free N-Arylation of Amines by Triarylsulfonium Triflates

(2018) Ze-Yu Tian et al.   CHEMISTRY-A EUROPEAN JOURNAL

Application of arylsulfonium salts as arylation reagents

(2018) Ze-Yu Tian et al.   TETRAHEDRON LETTERS

Recent developments in palladium-catalysed non-directed coupling of (hetero)arene C–H bonds with C–Z (Z = B, Si, Sn, S, N, C, H) bonds in bi(hetero)aryl synthesis

(2018) Pui Ying Choy et al.   Organic Chemistry Frontiers

C–S Bond Activation

(2018) Shinya Otsuka et al.   Topics in Current Chemistry

Ring-Closing Synthesis of Dibenzothiophene Sulfonium Salts and Their Use as Leaving Groups for Aromatic 18F-Fluorination

(2018) Thibault Gendron et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Process Development of Febuxostat Using Palladium- and Copper-Catalyzed C–H Arylation

(2018) Masato Komiyama et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Sonogashira Reaction Using Arylsulfonium Salts as Cross-Coupling Partners

(2017) Ze-Yu Tian et al.   ORGANIC LETTERS

A new face of phenalenyl-based radicals in the transition metal-free C–H arylation of heteroarenes at room temperature: trapping the radical initiator via C–C σ-bond formation

(2017) Jasimuddin Ahmed et al.   Chemical Science

Palladium-Catalyzed Borylation of Aryl Sulfoniums with Diborons

(2017) Hiroko Minami et al.   ACS Catalysis

Palladium-catalyzed Mizoroki–Heck-type reactions of [Ph2SRfn][OTf] with alkenes at room temperature

(2016) Shi-Meng Wang et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Arylation of Arylboronic Acids with Yagupolskii-Umemoto Reagents

(2016) Shi-Meng Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Synthesis of a PDE4 Inhibitor by Using Pd–Cu-Catalyzed C–H/C–Br Coupling of Benzoxazole with a Heteroaryl Bromide

(2016) Kiichi Kuroda et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Palladium-Assisted “Aromatic Metamorphosis” of Dibenzothiophenes into Triphenylenes

(2015) Dhananjayan Vasu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Room-temperature palladium-catalyzed direct 2-arylation of benzoxazoles with aryl and heteroaryl bromides

(2014) Feng Gao et al.   CHEMICAL COMMUNICATIONS

2-(2-Arylphenyl)benzoxazole As a Novel Anti-Inflammatory Scaffold: Synthesis and Biological Evaluation

(2014) Kapileswar Seth et al.   ACS Medicinal Chemistry Letters

Visible-Light Photocatalytic Reduction of Sulfonium Salts as a Source of Aryl Radicals

(2013) Simon Donck et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Mediated and Copper-Catalyzed Cross-Coupling of Indoles and 1,3-Azoles: Double CH Activation

(2012) Mayuko Nishino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed Oxidative CH/CH Cross-Coupling between Two Structurally Similar Azoles

(2012) Jiaxing Dong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Decarbonylative C–H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A

(2012) Kazuma Amaike et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalyzed desulfitative arylation of azoles with arylsulfonyl hydrazides

(2012) Xinzhang Yu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed Dehydrogenative Cross-Couplings of Benzazoles with Azoles

(2011) Wei Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct Arylations of Azoles with Aryl Silicon and Tin Reagents

(2011) Wei Han et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Efficient Arylation of Benzoazoles with Aryl Bromides by a Practical Palladium-Copper Cocatalytic System

(2011) Zhi-Zhen Huang et al.   HETEROCYCLES

Palladium-Catalyzed Direct Arylations of Heteroarenes with Tosylates and Mesylates

(2008) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct arylations on water: synthesis of 2,5-disubstituted oxazoles balsoxin and texaline

(2008) Stephan A. Ohnmacht et al.   CHEMICAL COMMUNICATIONS