A new face of phenalenyl-based radicals in the transition metal-free C–H arylation of heteroarenes at room temperature: trapping the radical initiator via C–C σ-bond formation

Blue light mediated C–H arylation of heteroarenes using TiO2 as an immobilized photocatalyst in a continuous-flow microreactor

(2017) David C. Fabry et al.   GREEN CHEMISTRY

Dual gold and photoredox catalysed C–H activation of arenes for aryl–aryl cross couplings

(2017) V. Gauchot et al.   Chemical Science

Photoinduced Copper-Catalyzed C−H Arylation at Room Temperature

(2016) Fanzhi Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Open-Shell Phenalenyl in Transition Metal-Free Catalytic C–H Functionalization

(2016) Rupankar Paira et al.   JOURNAL OF ORGANIC CHEMISTRY

KOtBu-Initiated Aryl C–H Iodination: A Powerful Tool for the Synthesis of High Electron Affinity Compounds

(2016) Qinqin Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

KOtBu: A Privileged Reagent for Electron Transfer Reactions?

(2016) Joshua P. Barham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluxional σ-Bonds of the 2,5,8-Trimethylphenalenyl Dimer: Direct Observation of the Sixfold σ-Bond Shift via a π-Dimer

(2016) Kazuyuki Uchida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Decarbonylative Cross-Coupling of Azinecarboxylates with Arylboronic Acids

(2016) Kei Muto et al.   ORGANIC LETTERS

Evidence for the interaction between tBuOK and 1,10-phenanthroline to form the 1,10-phenanthroline radical anion: a key step for the activation of aryl bromides by electron transfer

(2015) Hong Yi et al.   CHEMICAL COMMUNICATIONS

Switching Closed-Shell to Open-Shell Phenalenyl: Toward Designing Electroactive Materials

(2015) Anand Pariyar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Access to 2-(Het)aryl and 2-Styryl Benzoxazoles via Palladium-Catalyzed Aminocarbonylation of Aryl and Vinyl Bromides

(2015) Karoline T. Neumann et al.   ORGANIC LETTERS

Ascorbic Acid as an Initiator for the Direct CH Arylation of (Hetero)arenes with Anilines Nitrosated In Situ

(2014) Fernando Pinacho Crisóstomo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Observations on transition metal free biaryl coupling: potassium tert-butoxide alone promotes the reaction without diamine or phenanthroline catalysts

(2014) J. Cuthbertson et al.   CHEMICAL COMMUNICATIONS

Identifying the Roles of Amino Acids, Alcohols and 1,2-Diamines as Mediators in Coupling of Haloarenes to Arenes

(2014) Shengze Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The electron is a catalyst

(2014) Armido Studer et al.   Nature Chemistry

Hexamethoxyphenalenyl as a Possible Quantum Spin Simulator: An Electronically Stabilized Neutral π Radical with Novel Quantum Coherence Owing to Extremely High Nuclear Spin Degeneracy

(2013) Akira Ueda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Radical Process towards the Development of Transition-Metal-Free Aromatic CarbonCarbon Bond-Forming Reactions

(2013) Tek Long Chan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Interface-engineered templates for molecular spin memory devices

(2013) Karthik V. Raman et al.   NATURE

Programmed synthesis of arylthiazoles through sequential C–H couplings

(2013) Satoshi Tani et al.   Chemical Science

Metal-Free, Visible-Light-Mediated Direct C–H Arylation of Heteroarenes with Aryl Diazonium Salts

(2012) Durga Prasad Hari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phenalenyl-Based Molecules: Tuning the Lowest Unoccupied Molecular Orbital to Design a Catalyst

(2011) Tamal K. Sen et al.   CHEMISTRY-A EUROPEAN JOURNAL

A new spin on bistability

(2011) Robin G. Hicks   Nature Chemistry

Synthetic organic spin chemistry for structurally well-defined open-shell graphene fragments

(2011) Yasushi Morita et al.   Nature Chemistry

Organic tailored batteries materials using stable open-shell molecules with degenerate frontier orbitals

(2011) Yasushi Morita et al.   NATURE MATERIALS

tert-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic 1,10-Phenanthroline Derivative

(2010) Eiji Shirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C−H Arylation of Unactivated Benzene

(2010) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An efficient organocatalytic method for constructing biaryls through aromatic C–H activation

(2010) Chang-Liang Sun et al.   Nature Chemistry

Silver-Mediated Direct Amination of Benzoxazoles: Tuning the Amino Group Source from Formamides to Parent Amines

(2009) Seung���Hwan Cho et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

OLEX2: a complete structure solution, refinement and analysis program

(2009) Oleg V. Dolomanov et al.   JOURNAL OF APPLIED CRYSTALLOGRAPHY

Potassiumt-Butoxide Alone Can Promote the Biaryl Coupling of Electron-Deficient Nitrogen Heterocycles and Haloarenes

(2008) Shuichi Yanagisawa et al.   ORGANIC LETTERS