Reactivity of an NHC-Stabilized Silylene towards Lewis Acids and Lewis Bases

Selective Silylation of Nitriles with an NHC-Stabilized Silylene to 1,2-Disilylimines and Subsequent Synthesis of Silaaziridines

(2016) Jianfeng Li et al.   ORGANOMETALLICS

Base-stabilized silaimine and its donor-free dimer derived from the reaction of NHC-supported silylene with SiCl4

(2015) Haiyan Cui et al.   DALTON TRANSACTIONS

Reactivity of an NHC-stabilized silylene towards ketones. Formation of silicon bis-enolates vs. bis-silylation of the CO bond

(2015) Yao Li et al.   DALTON TRANSACTIONS

Controlled Oxidation of an NHC-Stabilized Phosphinoaminosilylene with Dioxygen

(2015) Haiyan Cui et al.   INORGANIC CHEMISTRY

Frustrated Lewis Pairs

(2015) Douglas W. Stephan   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis Pairs: From Concept to Catalysis

(2014) Douglas W. Stephan   ACCOUNTS OF CHEMICAL RESEARCH

Bis[N,N′-diisopropylbenzamidinato(−)]silicon(II): Lewis Acid/Base Reactions with Triorganylboranes

(2014) Konstantin Junold et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactions of Diaryldibromodisilenes with N-Heterocyclic Carbenes: Formation of Formal Bis-NHC Adducts of Silyliumylidene Cations

(2014) Tomohiro Agou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides

(2014) Douglas W. Stephan et al.   Chemical Science

Silicon(II) Coordination Chemistry: N-Heterocyclic Carbene Complexes of Si2+and SiI+

(2013) Alexander C. Filippou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cyclic Silylone (“Siladicarbene”) with an Electron-Rich Silicon(0) Atom

(2013) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Dihydrodisilene Transition Metal Complex from an N-Heterocyclic Carbene-Stabilized Silylene Monohydride

(2013) Shigeyoshi Inoue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of an Isolable Base-Stabilized Silacycloprop-1-ylidene

(2012) Ricardo Rodriguez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Acyclic Imino-Substituted Silylene: Synthesis, Isolation, and its Facile Conversion into a Zwitterionic Silaimine

(2012) Shigeyoshi Inoue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conversion of a Singlet Silylene to a stable Biradical

(2012) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of Stable Low-Oxidation-State Group 14 Element Amidohydrides and Hydride-Mediated Ring-Expansion Chemistry of N-Heterocyclic Carbenes

(2012) S. M. Ibrahim Al-Rafia et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Isolable NHC-Stabilized Silylene Radical Cation: Synthesis and Structural Characterization

(2012) Hiroaki Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

2-Hydro-2-aminophosphasilene with N–Si–P π Conjugation

(2012) Haiyan Cui et al.   ORGANOMETALLICS

Lewis Base Stabilized Group 14 Metalylenes

(2012) Amit Pratap Singh et al.   ORGANOMETALLICS

Metal-Free, Stereospecific Bis-Silylation of Functionalized Alkynes with NHC-Supported Silylaminosilylene

(2012) Haiyan Cui et al.   ORGANOMETALLICS

Aromatic Ylide-Stabilized Carbocyclic Silylene

(2011) Matthew Asay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient generation of stable adducts of Si(ii) dihydride using a donor–acceptor approach

(2011) S. M. Ibrahim Al-Rafia et al.   CHEMICAL COMMUNICATIONS

Synthesis of a Base-Stabilized 1-Hydrosilanimine via NHC-Mediated Dehydrohalogenation of Hydrochlorosilane

(2011) Haiyan Cui et al.   Chemistry-An Asian Journal

A stable silicon(ii) monohydride

(2011) Anukul Jana et al.   DALTON TRANSACTIONS

Silylation of N-heterocyclic carbene with aminochlorosilane and -disilane: dehydrohalogenation vs. Si–Si bond cleavage

(2011) Haiyan Cui et al.   DALTON TRANSACTIONS

Reactions of Stable Amidinate Chlorosilylene and [1+4]-Oxidative Addition of N-Heterocyclic Silylene with N-Benzylideneaniline

(2011) Anukul Jana et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cleavage of Carbene-Stabilized Disilicon

(2011) Mariham Y. Abraham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds

(2010) Mitsuo Kira   CHEMICAL COMMUNICATIONS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Stable N-Heterocyclic Carbene Adducts of Arylchlorosilylenes and Their Germanium Homologues

(2010) Alexander C. Filippou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Facile Synthesis of a Rare Chlorosilylene-BH3 Adduct

(2010) Ramachandran Azhakar et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Base-Stabilized 1-Silacyclopenta-2,4-dienylidenes

(2010) Yihua Gao et al.   ORGANOMETALLICS

Frustrated Lewis Pairs and Ring-Opening of THF, Dioxane, and Thioxane†

(2010) Birgit Birkmann et al.   ORGANOMETALLICS

SiBr2(Idipp): A Stable N-Heterocyclic Carbene Adduct of Dibromosilylene

(2009) Alexander C. Filippou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[2,6-(Trip)2H3C6](Cp*)Si: A Stable Monomeric Arylsilicon(II) Compound

(2009) Peter Jutzi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

Ambiphilicity of Dichlorosilylene in a Single Molecule

(2009) Rajendra S. Ghadwal et al.   CHEMISTRY-A EUROPEAN JOURNAL

Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

(2009) Douglas W. Stephan   DALTON TRANSACTIONS

Dehydrochlorination to Silylenes by N-Heterocyclic Carbenes

(2009) Haiyan Cui et al.   ORGANOMETALLICS