Expanding the Chemistry of CationicN-Heterocyclic Carbenes: Alternative Synthesis, Reactivity, and Coordination Chemistry

Silver and Gold Complexes with Benzimidazolin-2-ylidene Ligands

(2015) Mareike C. Jahnke et al.   ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES

Yes They Can: Small-molecule Activation with Stable Diaminocarbenes

(2011) Ulrich Siemeling   AUSTRALIAN JOURNAL OF CHEMISTRY

Synthetic Routes to N-Heterocyclic Carbene Precursors

(2011) Laure Benhamou et al.   CHEMICAL REVIEWS

How Important Is Backbonding in Metal Complexes Containing N-Heterocyclic Carbenes? Structural and NBO Analysis

(2011) Aleix Comas-Vives et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

When Does Carbonylation of Carbenes Yield Ketenes? A Theoretical Study with Implications for Synthesis

(2011) Catharina Goedecke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Olefin Metathesis Catalysts ContainingN,N′-Diamidocarbenes

(2011) Jonathan P. Moerdyk et al.   ORGANOMETALLICS

A Cationic N-Heterocyclic Carbene with an Organometallic Backbone: Synthesis and Reactivity

(2011) Björn Hildebrandt et al.   ORGANOMETALLICS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Steering the Surprisingly Modular π-Acceptor Properties of N-Heterocyclic Carbenes: Implications for Gold Catalysis

(2010) Manuel Alcarazo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs)

(2010) Gregorio Guisado-Barrios et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ammonia N–H activation by a N,N′-diamidocarbene

(2010) Todd W. Hudnall et al.   CHEMICAL COMMUNICATIONS

Anionic N-Heterocyclic Carbenes with N,N′-Bis(fluoroaryl) and N,N′-Bis(perfluoroaryl) Substituents

(2010) Matthew G. Hobbs et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electronic Tuning of a Carbene Center via Remote Chemical Induction, and Relevant Effects in Catalysis

(2010) Vincent César et al.   CHEMISTRY-A EUROPEAN JOURNAL

N,N′-Diamidoketenimines via Coupling of Isocyanides to an N-Heterocyclic Carbene

(2010) Todd W. Hudnall et al.   JOURNAL OF ORGANIC CHEMISTRY

Kinetic and Thermodynamic Evaluation of the Reversible N-Heterocyclic Carbene−Isothiocyanate Coupling Reaction: Applications in Latent Catalysis

(2010) Brent C. Norris et al.   JOURNAL OF ORGANIC CHEMISTRY

Facile synthesis of [(NHC)(NHCewg)RuCl2(CHPh)] complexes

(2010) Stefanie Wolf et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Hydrolysis of Imidazole-2-ylidenes

(2010) Oldamur Hollóczki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The influence of electron delocalization upon the stability and structure of potential N-heterocyclic carbene precursors with 1,3-diaryl-imidazolidine-4,5-dione skeletons

(2010) Matthew G. Hobbs et al.   NEW JOURNAL OF CHEMISTRY

Differentially Substituted Acyclic Diaminocarbene Ligands Display Conformation-Dependent Donicities

(2010) Mary S. Collins et al.   ORGANOMETALLICS

Facile Derivatization of a “Chemo-active” NHC Incorporating an Enolate Backbone and Relevant Tuning of Its Electronic Properties

(2010) Laure Benhamou et al.   ORGANOMETALLICS

An N-Heterocyclic Carbene Ligand with an Oxalamide Backbone

(2010) Markus Braun et al.   ORGANOMETALLICS

A Seven-MemberedN,N′-Diamidocarbene

(2010) Todd W. Hudnall et al.   ORGANOMETALLICS

N-heterocyclic carbenes which readily add ammonia, carbon monoxide and other small molecules,

(2010) Ulrich Siemeling et al.   Chemical Science

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

An [(NHC)(NHCEWG)RuCl2(CHPh)] Complex for the Efficient Formation of Sterically Hindered Olefins by Ring-Closing Metathesis

(2009) Tim Vorfalt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Imidazol-2-ylidene-4-olate: an anionic N-heterocyclic carbene pre-programmed for further derivatization

(2009) Laure Benhamou et al.   CHEMICAL COMMUNICATIONS

Electronically tunable N-heterocyclic carbene ligands: 1,3-diaryl vs. 4,5-diaryl substitution

(2009) James W. Ogle et al.   CHEMICAL COMMUNICATIONS

Grubbs’ Ruthenium-Carbenes Beyond the Metathesis Reaction: Less Conventional Non-Metathetic Utility

(2009) Benito Alcaide et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

1,1′-Bis(N-benzimidazolylidene)ferrocene: synthesis and study of a novel ditopic ligand and its transition metal complexes

(2009) C. Daniel Varnado Jr et al.   DALTON TRANSACTIONS

Main-chain organometallic polymers comprising redox-active iron(ii) centers connected by ditopic N-heterocyclic carbenes

(2009) Laszlo Mercs et al.   DALTON TRANSACTIONS

Six-Membered N-Heterocyclic Carbenes with a 1,1′-Ferrocenediyl Backbone: Bulky Ligands with Strong Electron-Donor Capacity and Unusual Non-Innocent Character

(2009) Ulrich Siemeling et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Ru-Based Olefin Metathesis Catalysts Bearing pH-Responsive N-Heterocyclic Carbene (NHC) Ligands: Activity Control via Degree of Protonation

(2009) Shawna L. Balof et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Theoretical Analysis of Bonding in N-Heterocyclic Carbene−Rhodium Complexes

(2009) Monika Srebro et al.   INORGANIC CHEMISTRY

AnN,N′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry

(2009) Todd W. Hudnall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quantifying the Donor−Acceptor Properties of Phosphine and N-Heterocyclic Carbene Ligands in Grubbs’ Catalysts Using a Modified EDA Procedure Based on Orbital Deletion

(2009) Nadya S. Antonova et al.   ORGANOMETALLICS

Redox-Active N-Heterocyclic Carbenes: Design, Synthesis, and Evaluation of Their Electronic Properties

(2009) Evelyn L. Rosen et al.   ORGANOMETALLICS

Diaminocarbene[3]ferrocenophanes and Their Transition-Metal Complexes

(2008) Dimitri M. Khramov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A stable crystalline N-heterocyclic carbene with a 1,1′-ferrocenediyl backbone

(2008) Ulrich Siemeling et al.   CHEMICAL COMMUNICATIONS

Recent advances in carbon–carbon bond-forming reactions involving homoenolates generated by NHC catalysis

(2008) Vijay Nair et al.   CHEMICAL SOCIETY REVIEWS

Carbenes: Synthesis, properties, and organometallic chemistry

(2008) Pierre de Frémont et al.   COORDINATION CHEMISTRY REVIEWS

Understanding the M(NHC) (NHC=N-heterocyclic carbene) bond

(2008) Heiko Jacobsen et al.   COORDINATION CHEMISTRY REVIEWS

Efficient Transfer Hydrogenation Using Iridium and Rhodium Complexes of Benzannulated N-Heterocyclic Carbenes

(2008) Hayati Türkmen et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

N-Heterocyclic Carbenes with Inorganic Backbones:  Electronic Structures and Ligand Properties

(2008) Anna Kausamo et al.   INORGANIC CHEMISTRY

Acceptor substituted N-heterocyclic carbenes and their Rh(I)complexes: Synthesis, structure and properties

(2008) Agnes Bittermann et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis of (NHC)Rh(cod)Cl and (NHC)RhCl(CO)2 complexes – Translation of the Rh- into the Ir-scale for the electronic properties of NHC ligands

(2008) Stefanie Wolf et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

A Stable Anionic N-Heterocyclic Carbene and Its Zwitterionic Complexes

(2008) Vincent César et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homo- and Heterodinuclear Complexes with Triazolyl-diylidene. An Easy Approach to Tandem Catalysts

(2008) Alessandro Zanardi et al.   ORGANOMETALLICS

Flexible, Bowl-Shaped N-Heterocyclic Carbene Ligands: Substrate Specificity in Iridium-Catalyzed Ketone Hydrosilylation

(2008) Anthony R. Chianese et al.   ORGANOMETALLICS

N-Heterocyclic carbenes: deducing σ- and π-contributions in Rh-catalyzed hydroboration and Pd-catalyzed coupling reactions

(2008) Dimitri M. Khramov et al.   TETRAHEDRON

Synthesis, structure and catalytic activity of the first iridium(I) siloxide versus chloride complexes with 1,3-mesitylimidazolin-2-ylidene ligand

(2007) Ireneusz Kownacki et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System

(2007) Roy A. Kelly III et al.   ORGANOMETALLICS