Protic N-Heterocyclic Carbene Versus Pyrazole: Rigorous Comparison of Proton- and Electron-Donating Abilities in a Pincer-Type Framework

Homo- and Heterodinuclear Ir and Rh Imine-functionalized Protic NHC Complexes: Synthetic, Structural Studies, and Tautomerization/Metallotropism Insights

(2016) Fan He et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cationic rhenium complexes ligated with N-heterocyclic carbenes – an overview

(2016) Claudia Hille et al.   DALTON TRANSACTIONS

Preparation of Rhodium(III) Di-NHC Chelate Complexes Featuring Two Different NHC Donors via a Mild NaOAc-Assisted C–H Activation

(2016) Francisco Aznarez et al.   ORGANOMETALLICS

Exploiting Metal–Ligand Bifunctional Reactions in the Design of Iron Asymmetric Hydrogenation Catalysts

(2015) Robert H. Morris   ACCOUNTS OF CHEMICAL RESEARCH

Metal-Ligand Cooperation

(2015) Julia R. Khusnutdinova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen Production from a Methanol-Water Solution Catalyzed by an Anionic Iridium Complex Bearing a Functional Bipyridonate Ligand under Weakly Basic Conditions

(2015) Ken-ichi Fujita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploring Mn–O bonding in the context of an electronically flexible secondary coordination sphere: synthesis of a Mn(iii)–oxo

(2015) Yun Ji Park et al.   CHEMICAL COMMUNICATIONS

Imine-functionalised protic NHC complexes of Ir: direct formation by C–H activation

(2015) Fan He et al.   CHEMICAL COMMUNICATIONS

Complexes Bearing Protic N-Heterocyclic Carbenes: Synthesis and Applications

(2015) Mareike C. Jahnke et al.   CHEMISTRY LETTERS

Hydrogen-Bonding Pincer Complexes with Two Protic N-Heterocyclic Carbenes from Direct Metalation of a 1,8-Bis(imidazol-1-yl)carbazole by Platinum, Palladium, and Nickel

(2015) David C. Marelius et al.   CHEMISTRY-A EUROPEAN JOURNAL

Complexes with protic (NH,NH and NH,NR) N-heterocyclic carbene ligands

(2015) Mareike C. Jahnke et al.   COORDINATION CHEMISTRY REVIEWS

Beyond H2: exploiting 2-hydroxypyridine as a design element from [Fe]-hydrogenase for energy-relevant catalysis

(2015) Cameron M Moore et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Protic Ruthenium Tris(pyrazol-3-ylmethyl)amine Complexes Featuring a Hydrogen-Bonding Network in the Second Coordination Sphere

(2015) Hiroaki Yamagishi et al.   INORGANIC CHEMISTRY

A Proton-Switchable Bifunctional Ruthenium Complex That Catalyzes Nitrile Hydroboration

(2015) Jacob B. Geri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Activation by an Iridium(III) Complex Bearing a Bidentate Protic NH,NR-NHC∧Phosphine Ligand

(2015) Steffen Cepa et al.   ORGANOMETALLICS

Trifunctional pNHC, Imine, Pyridine Pincer-Type Iridium(III) Complexes: Synthetic, Structural, and Reactivity Studies

(2015) Fan He et al.   ORGANOMETALLICS

High-spin Mn–oxo complexes and their relevance to the oxygen-evolving complex within photosystem II

(2015) Rupal Gupta et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Synthesis and Structures of Ruthenium and Iron Complexes Bearing an Unsymmetrical Pincer-type Ligand with Protic Pyrazole and Tertiary Aminoalkyl Arms

(2015) Tatsuro Toda et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Nitrite reduction by copper through ligand-mediated proton and electron transfer

(2015) Cameron M. Moore et al.   Chemical Science

Highly Robust Hydrogen Generation by Bioinspired Ir Complexes for Dehydrogenation of Formic Acid in Water: Experimental and Theoretical Mechanistic Investigations at Different pH

(2015) Wan-Hui Wang et al.   ACS Catalysis

Metal–ligand bifunctional reactivity and catalysis of protic N-heterocyclic carbene and pyrazole complexes featuring β-NH units

(2014) Shigeki Kuwata et al.   CHEMICAL COMMUNICATIONS

Bond Activation and Catalysis by Ruthenium Pincer Complexes

(2014) Chidambaram Gunanathan et al.   CHEMICAL REVIEWS

Unsymmetrical Pincer-Type Ruthenium Complex Containing β-Protic Pyrazole and N-Heterocyclic Carbene Arms: Comparison of Brønsted Acidity of NH Groups in Second Coordination Sphere

(2014) Tatsuro Toda et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis, structures, and reactivities of iron, cobalt, and manganese complexes bearing a pincer ligand with two protic pyrazole arms

(2014) Kazuki Umehara et al.   INORGANICA CHIMICA ACTA

A Versatile Methodology for the Regioselective C8-Metalation of Purine Bases

(2014) Dirk Brackemeyer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(R)-3-METHYL-3-PHENYL-1-PENTENE VIA CATALYTIC ASYMMETRIC HYDROVINYLATION

(2014)   ORGANIC SYNTHESES

Synthesis of Complexes with Protic NH,NH-NHC Ligands via Oxidative Addition of 2-Halogenoazoles to Zero-Valent Transition Metals

(2014) Rajorshi Das et al.   ORGANOMETALLICS

Mono- and Dimetalation of a Tridentate Bisimidazole-Phosphine Ligand

(2014) Sarah E. Flowers et al.   ORGANOMETALLICS

Group 7 transition metal complexes with N-heterocyclic carbenes

(2013) Sebastian J. Hock et al.   CHEMICAL SOCIETY REVIEWS

Cobalt induced CH bond activation and C8-arylation of caffeine with aryl bromides

(2013) Tingting Zheng et al.   INORGANIC CHEMISTRY COMMUNICATIONS

N–N Bond Cleavage of Hydrazines with a Multiproton-Responsive Pincer-Type Iron Complex

(2013) Kazuki Umehara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Learning from the Neighbors: Improving Homogeneous Catalysts with Functional Ligands Motivated by Heterogeneous and Biocatalysis

(2012) Bjorn Askevold et al.   ChemCatChem

Substrate Recognition and Regioselective Catalysis with Complexes Bearing NR,NH-NHC Ligands

(2012) F. Ekkehardt Hahn   ChemCatChem

Synthesis of Complexes Containing an Anionic NHC Ligand with an Unsubstituted Ring-Nitrogen Atom

(2012) Tim Kösterke et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis, Structures, and Reactivities of Pincer-Type Ruthenium Complexes Bearing Two Proton-Responsive Pyrazole Arms

(2012) Akihiro Yoshinari et al.   Chemistry-An Asian Journal

Outer sphere hydrogenation catalysis

(2012) Odile Eisenstein et al.   NEW JOURNAL OF CHEMISTRY

Catalytic Intramolecular Hydroamination with a Bifunctional Iridium Pyrazolato Complex: Substrate Scope and Mechanistic Elucidation

(2012) Yohei Kashiwame et al.   ORGANOMETALLICS

Synthesis, Structure, and Proton-Transfer Reactions of Brønsted Acidic Pyridylpyrazole Complexes of Ruthenium

(2011) Yohei Kashiwame et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

β-Protic Pyrazole and N-Heterocyclic Carbene Complexes: Synthesis, Properties, and Metal-Ligand Cooperative Bifunctional Catalysis

(2011) Shigeki Kuwata et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Rhodium(I) Complexes Bearing Bidentate NH,NR-NHC/Phosphine Ligands

(2011) Abbas Raja Naziruddin et al.   ORGANOMETALLICS

From Bis(N-Alkylimidazole) to Bis(NH-NHC) in Rhenium Carbonyl Complexes

(2010) Miguel A. Huertos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Labile and Catalytically Active Imidazol-2-yl Fragment System

(2010) Valentín Miranda-Soto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemistry ofConcertoMolecular Catalysis Based on the Metal/NH Bifunctionality

(2010) Takao Ikariya   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Bifunctional Organometallic Catalysis and Reactivity Using Heterocyclic Phosphines and Metallated Heterocycles

(2010) Douglas B. Grotjahn   CHEMISTRY LETTERS

Ruthenium Complexes Bearing N-H Acidic Pyrazole Ligands

(2010) Thomas Jozak et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Role of the Secondary Coordination Sphere in Metal-Mediated Dioxygen Activation

(2010) Ryan L. Shook et al.   INORGANIC CHEMISTRY

Metal-Pyrazole Bifunction in Half-Sandwich CN Chelate Iridium Complexes: Pyrazole-Pyrazolato Interconversion and Application to Catalytic Intramolecular Hydroamination of Aminoalkene

(2009) Yohei Kashiwame et al.   CHEMISTRY-A EUROPEAN JOURNAL

Imidazol-2-yl Complexes of Cp*Ir as Bifunctional Ambident Reactants

(2008) Valentín Miranda-Soto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed C−C Coupling Reactions: Mechanistic Considerations

(2008) Kirsty J. Hawkes et al.   ORGANOMETALLICS

Isolation and Interconversion of ProticN-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation ofN-(2-Pyridyl)benzimidazole and Allyl Alcohol

(2008) Kenjirou Araki et al.   ORGANOMETALLICS

Ruthenium(II) Complexes Bearing a Pyridyl-Supported Pyrazolyl−N-Heterocyclic Carbene (NNC) Ligand and Their Catalytic Activity in the Transfer Hydrogenation of Ketones

(2008) Fanlong Zeng et al.   ORGANOMETALLICS