Recent Advances in the Synthesis of SCF2H- and SCF2FG-Containing Molecules

Direct Electrophilic (Benzenesulfonyl)Difluoromethylthiolation with a Shelf-Stable Reagent

(2016) Ermal Ismalaj et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic approaches to the 2010–2014 new agrochemicals

(2016) Stephane Jeanmart et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Preparation of difluoromethylthioethers through difluoromethylation of disulfides using TMS-CF2H

(2016) Joseph L. Howard et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Perfluoroalkylthiolation of Alkynes with Perfluoroalkanesulfenamides

(2016) Anis Tlili et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible Light-Promoted Decarboxylative Di- and Trifluoromethylthiolation of Alkyl Carboxylic Acids

(2016) Lisa Candish et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Perfluoroalkylthiolation of Few Chalcogenols

(2016) Quentin Glenadel et al.   CHINESE JOURNAL OF CHEMISTRY

A Metal-Free Diverse Synthesis of Difluoromethylthioethers and Difluorobis(arylthio)methanes from RSX (X = SR, Cl, SO2Ph) and TMSCF2H

(2016) Jia-Bin Han et al.   JOURNAL OF ORGANIC CHEMISTRY

Late stage trifluoromethylthiolation strategies for organic compounds

(2016) Sebastian Barata-Vallejo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Route to α-Fluoroalkyl Sulfides from α-Fluorodiaroylmethanes

(2016) Ya-mei Lin et al.   ORGANIC LETTERS

Palladium-catalyzed difluoromethylthiolation of heteroaryl bromides, iodides, triflates and aryl iodides

(2016) Jiang Wu et al.   Chemical Science

Metal-Free Direct Nucleophilic Perfluoroalkylthiolation with Perfluoroalkanesulfenamides

(2016) Quentin Glenadel et al.   Asian Journal of Organic Chemistry

New entries toward the synthesis of OCF3-containing molecules

(2016) Tatiana Besset et al.   Organic Chemistry Frontiers

Convenient synthesis of pentafluoroethyl thioethers via catalytic Sandmeyer reaction with a stable fluoroalkylthiolation reagent

(2016) C. Matheis et al.   Organic Chemistry Frontiers

Difluoromethanesulfonyl hypervalent iodonium ylides for electrophilic difluoromethylthiolation reactions under copper catalysis

(2016) Sadayuki Arimori et al.   Royal Society Open Science

Advances in Transition-Metal-Mediated Di-and Monofluoroalkylations

(2015) Chuanfa Ni et al.   ACTA CHIMICA SINICA

Copper-Promoted Sandmeyer Difluoromethylthiolation of Aryl and Heteroaryl Diazonium Salts

(2015) Jiang Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Difluoromethyl Thioethers from Difluoromethyl Trimethylsilane and Organothiocyanates Generated In Situ

(2015) Bilguun Bayarmagnai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Difluoromethylation and gem-difluorocyclopropenation with difluorocarbene generated by decarboxylation

(2015) Xiao-Yun Deng et al.   CHEMICAL COMMUNICATIONS

Synthesis of Aryl Tri- and Difluoromethyl Thioethers via a CH-Thiocyanation/Fluoroalkylation Cascade

(2015) Kévin Jouvin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Progress toward the Introduction of Functionalized Difluoromethylated Building Blocks onto C(sp2) and C(sp) Centers

(2015) Marie-Charlotte Belhomme et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Vicinal Difunctionalization of Alkynes: An Efficient Approach Towards the Synthesis of Highly Functionalized Fluorinated Alkenes

(2015) Tatiana Besset et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct S-difluoromethylation of thiols using the Ruppert–Prakash reagent

(2015) G.K. Surya Prakash et al.   JOURNAL OF FLUORINE CHEMISTRY

Organocatalytic, difluorocarbene-based S-difluoromethylation of thiocarbonyl compounds

(2015) Kohei Fuchibe et al.   JOURNAL OF FLUORINE CHEMISTRY

Applications of Fluorine in Medicinal Chemistry

(2015) Eric P. Gillis et al.   JOURNAL OF MEDICINAL CHEMISTRY

N-Difluoromethylthiophthalimide: A Shelf-Stable, Electrophilic Reagent for Difluoromethylthiolation

(2015) Dianhu Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation

(2015) Yang Gu et al.   ORGANOMETALLICS

Trifluoromethylation of Alkenes with Concomitant Introduction of Additional Functional Groups

(2014) Hiromichi Egami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deoxygenativegem-difluoroolefination of carbonyl compounds with (chlorodifluoromethyl)trimethylsilane and triphenylphosphine

(2014) Fei Wang et al.   Beilstein Journal of Organic Chemistry

Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis

(2014) Chuanfa Ni et al.   CHEMICAL REVIEWS

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

(2014) Xiu-Hua Xu et al.   CHEMICAL REVIEWS

Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of CH Bond Functionalization

(2014) Tatiana Besset et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fluorinated Sulfoximines: Preparation, Reactions and Applications

(2014) Xiao Shen et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept

(2014) Fabien Toulgoat et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Recent Advances in the Synthetic Application of Difluorocarbene

(2014) Jinbo Hu et al.   SYNTHESIS-STUTTGART

Formation of CSCF3Bonds through Direct Trifluoromethylthiolation

(2013) Anis Tlili et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Catalyzed Electrophilic Trifluoromethylthiolation of Terminal Alkynes

(2013) Sébastien Alazet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis ofgem-Difluorocyclopropa(e)nes and O-, S-, N-, and P-Difluoromethylated Compounds with TMSCF2Br

(2013) Lingchun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Difluoromethyl Ethers with Difluoromethyltriflate

(2013) Patrick S. Fier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct electrophilicN-trifluoromethylthiolation of amines with trifluoromethanesulfenamide

(2013) Sébastien Alazet et al.   Beilstein Journal of Organic Chemistry

Recent advances in transition metal-catalyzed Csp2-monofluoro-, difluoro-, perfluoromethylation and trifluoromethylthiolation

(2013) Grégory Landelle et al.   Beilstein Journal of Organic Chemistry

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Data-Mining for Sulfur and Fluorine: An Evaluation of Pharmaceuticals To Reveal Opportunities for Drug Design and Discovery

(2013) Elizabeth A. Ilardi et al.   JOURNAL OF MEDICINAL CHEMISTRY

Use of Fluoroform as a Source of Difluorocarbene in the Synthesis of Difluoromethoxy- and Difluorothiomethoxyarenes

(2013) Charles S. Thomoson et al.   JOURNAL OF ORGANIC CHEMISTRY

Research and development of a novel rice herbicide, pyrimisulfan#

(2013) Takumi Yoshimura et al.   JOURNAL OF PESTICIDE SCIENCE

S-, N-, and Se-Difluoromethylation Using Sodium Chlorodifluoroacetate

(2013) Vaibhav P. Mehta et al.   ORGANIC LETTERS

Electrophilic Trifluoromethanesulfanylation of Organometallic Species with Trifluoromethanesulfanamides

(2012) François Baert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New Reagent for Direct Difluoromethylation

(2012) Yuta Fujiwara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Difluoromethylation of O-, S-, N-, C-Nucleophiles Using Difluoromethyltri(n-butyl)ammonium Chloride as a New Difluorocarbene Source

(2011) Fei Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Chlorodifluoromethyl aryl ketones and sulfones as difluorocarbene reagents: The substituent effect

(2011) Fei Wang et al.   JOURNAL OF FLUORINE CHEMISTRY

N,N-Dimethyl-S-difluoromethyl-S-phenylsulfoximinium tetrafluoroborate: A versatile electrophilic difluoromethylating reagent

(2011) G.K. Surya Prakash et al.   JOURNAL OF FLUORINE CHEMISTRY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Efficacy of a spot-on formulation of pyriprole on dogs infested with Sarcoptes scabiei

(2010) J. J. Fourie et al.   VETERINARY RECORD

Selective difluoromethylation and monofluoromethylation reactions

(2009) Jinbo Hu et al.   CHEMICAL COMMUNICATIONS

New trends in the chemistry of α-fluorinated ethers, thioethers, amines and phosphines

(2009) Baptiste Manteau et al.   JOURNAL OF FLUORINE CHEMISTRY

N-Tosyl-S-difluoromethyl-S-phenylsulfoximine: A New Difluoromethylation Reagent for S-, N-, and C-Nucleophiles

(2009) Wei Zhang et al.   ORGANIC LETTERS

Diethyl bromodifluoromethylphosphonate: a highly efficient and environmentally benign difluorocarbene precursor

(2009) Yossi Zafrani et al.   TETRAHEDRON

Synthesis of Trifluoromethanesulfinamidines and -sulfanylamides

(2008) Aurélien Ferry et al.   JOURNAL OF ORGANIC CHEMISTRY

Electrophilic (phenylsulfonyl)difluoromethylation of thiols with a hypervalent iodine(III)–CF2SO2Ph reagent

(2008) Wei Zhang et al.   TETRAHEDRON LETTERS

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS