Copper-Catalyzed Perfluoroalkylthiolation of Alkynes with Perfluoroalkanesulfenamides

State-of-the-Art in Electrophilic Trifluoromethylthiolation Reagents

(2016) Hélène Chachignon et al.   CHINESE JOURNAL OF CHEMISTRY

Trifluoromethylthiolation of Unsymmetrical λ3-Iodane Derivatives: Additive-Free, Selective and Scalable Introduction of the SCF3Group

(2016) Pavlo Nikolaienko et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Regioselective ortho-trifluoromethylthiolation of 2-arylbenzo[d]thiazole via tandem substrate-assisted C–H iodination and trifluoromethylthiolation

(2016) Puying Luo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Silver-Mediated Trifluoromethylthiolation–Iodination of Arynes

(2016) Yuwen Zeng et al.   ORGANIC LETTERS

BF3·OEt2-AgSCF3 Mediated Trifluoromethylthiolation/Cascade Cyclization of Propynols: Synthesis of 4-((Trifluoromethyl)thio)-2H-chromene and 4-((Trifluoromethyl)thio)-1,2-dihydroquinoline Derivatives

(2016) Yi-Feng Qiu et al.   ORGANIC LETTERS

Recent advances in trifluoromethylthiolation using nucleophilic trifluoromethylthiolating reagents

(2016) Huidong Zheng et al.   TETRAHEDRON LETTERS

Metal-Free Direct Nucleophilic Perfluoroalkylthiolation with Perfluoroalkanesulfenamides

(2016) Quentin Glenadel et al.   Asian Journal of Organic Chemistry

Shelf-Stable Electrophilic Reagents for Trifluoromethylthiolation

(2015) Xinxin Shao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Catalyzed Trifluoromethylthiolation of Di(hetero)aryl-λ3-iodanes: Mechanistic Insight and Application to Synthesis of (Hetero)Aryl Trifluoromethyl Sulfides

(2015) Perumal Saravanan et al.   ADVANCED SYNTHESIS & CATALYSIS

Trifluoromethylthiolation of Aryl Iodides and Bromides Enabled by a Bench-Stable and Easy-To-Recover Dinuclear Palladium(I) Catalyst

(2015) Guoyin Yin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diaryliodoniums by Rhodium(III)-Catalyzed CH Activation: Mild Synthesis and Diversified Functionalizations

(2015) Fang Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sandmeyer-Type Trifluoromethylthiolation and Trifluoromethylselenolation of (Hetero)Aromatic Amines Catalyzed by Copper

(2015) Christian Matheis et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mild and Soft Catalyzed Trifluoromethylthiolation of Boronic Acids: The Crucial Role of Water

(2015) Quentin Glenadel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Advances of Direct Trifluoromethylthiolation

(2015) Ke Zhang et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions

(2015) Jin-Hong Lin et al.   CURRENT ORGANIC CHEMISTRY

First and second generation of trifluoromethanesulfenamide reagent: A trifluoromethylthiolating comparison

(2015) Quentin Glenadel et al.   JOURNAL OF FLUORINE CHEMISTRY

Synthesis of Vinyl Trifluoromethyl Thioethers via Copper-Mediated Trifluoromethylthiolation of Vinyl Bromides

(2015) Yangjie Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Structure–Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent

(2015) Xinxin Shao et al.   JOURNAL OF ORGANIC CHEMISTRY

Fundamental Studies and Development of Nickel-Catalyzed Trifluoromethylthiolation of Aryl Chlorides: Active Catalytic Species and Key Roles of Ligand and Traceless MeCN Additive Revealed

(2015) Guoyin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An efficient and practical approach to trifluoromethylthiolation of α-haloketones/α-haloarylmethanes

(2015) Min Jiang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

SYNFORM ISSUE 2015/05

(2015) Matteo Zanda   SYNLETT

Synthesis of β-Trifluoromethylthio- and β-Trifluoromethylseleno-α,β-unsaturated Ketones through Copper-Mediated Trifluoromethylthio(seleno)lation

(2015) Zhirong Chen et al.   SYNTHESIS-STUTTGART

Highlyortho-Selective Trifluoromethylthiolation Reactions using a Ligand Exchange Strategy

(2014) Weiyu Yin et al.   ADVANCED SYNTHESIS & CATALYSIS

N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent

(2014) Chunfa Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Catalytic Trifluoromethylthiolation of Boronic Acids and Alkynes Employing Electrophilic Shelf-StableN-(trifluoromethylthio)phthalimide

(2014) Roman Pluta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrotrifluoromethylthiolation of α-diazo esters – synthesis of α-SCF3 substituted esters

(2014) Quentin Lefebvre et al.   CHEMICAL COMMUNICATIONS

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

(2014) Xiu-Hua Xu et al.   CHEMICAL REVIEWS

Direct Trifluoromethylthiolation of Alcohols under Mild Reaction Conditions: Conversion of ROH into RSCF3

(2014) Pavlo Nikolaienko et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion

(2014) Xi Wang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Oxidative Trifluoromethylthiolation of Terminal Alkynes with AgSCF3: A Convenient Approach to Alkynyl Trifluoromethyl Sulfides

(2014) Sheng-Qing Zhu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

An Improved Protocol for the Synthesis of α-Trifluoromethylthio-Substituted Ketones by Copper-Mediated Trifluoromethylthiolation of α-Bromo Ketones

(2014) Yangjie Huang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept

(2014) Fabien Toulgoat et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Efficient C(sp3alkyl)–SCF3 bond formations via copper-mediated trifluoromethylthiolation of alkyl halides

(2014) Quanfu Lin et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Mediated Trifluoromethylthiolation of α-Diazoesters

(2014) Mingyou Hu et al.   ORGANIC LETTERS

Copper-Catalyzed Trifluoromethylthiolation of Aryl Halides with Diverse Directing Groups

(2014) Jiabin Xu et al.   ORGANIC LETTERS

Diversity-Oriented Approach to CF3CHF-, CF3CFBr-, CF3CF2-, (CF3)2CH-, and CF3(SCF3)CH-Substituted Arenes from 1-(Diazo-2,2,2-trifluoroethyl)arenes

(2014) Enrico Emer et al.   ORGANIC LETTERS

Formation of CSCF3Bonds through Direct Trifluoromethylthiolation

(2013) Anis Tlili et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Catalyzed Electrophilic Trifluoromethylthiolation of Terminal Alkynes

(2013) Sébastien Alazet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation

(2013) Xinxin Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct electrophilicN-trifluoromethylthiolation of amines with trifluoromethanesulfenamide

(2013) Sébastien Alazet et al.   Beilstein Journal of Organic Chemistry

Copper-Catalyzed Trifluoromethyl Thiolation-Mild and Efficient Synthesis of Trifluoromethyl Thioethers

(2013) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nucleophilic Trifluoromethylthiolation of Allylic Bromides: A Facile Preparation of Allylic Trifluoromethyl Thioethers

(2013) Jianwei Tan et al.   CHINESE JOURNAL OF CHEMISTRY

Facile Assembly of 1-[(Trifluoromethyl)thio]isoquinolines through Reaction of 2-Alkynylbenzaldoxime with Silver (Trifluoromethyl)thiolate

(2013) Qing Xiao et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper(I) trifluoromethylthiolate complex bearing triphenylphosphine ligand for nucleophilic trifluoromethylthiolation of allylic bromides

(2013) Zhiyuan Wang et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Copper-Catalyzed Electrophilic Carbofunctionalization of Alkynes to Highly Functionalized Tetrasubstituted Alkenes

(2013) Marcos G. Suero et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Copper-Catalyzed Trifluoromethylthiolation of Enamines, Indoles, and β-Keto Esters

(2013) Yu-Dong Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-mediated synthesis of α-trifluoromethylthio- and seleno-α,β-unsaturated carbonyl compounds

(2013) Peitao Zhu et al.   TETRAHEDRON

Silver-mediated fluorination, trifluoromethylation, and trifluoromethylthiolation of arynes

(2013) Kung-Pern Wang et al.   Chemical Science

Electrophilic Trifluoromethanesulfanylation of Organometallic Species with Trifluoromethanesulfanamides

(2012) François Baert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides

(2012) Zhiqiang Weng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Trifluoromethylthiolations of Aryl Boronic Acids Using a Copper/O2-Based Protocol

(2012) Cheng-Pan Zhang et al.   Chemistry-An Asian Journal

Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur

(2012) Chao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Contribution to the Mechanism of Copper-Catalyzed C–N and C–O Bond Formation

(2012) Guillaume Lefèvre et al.   ORGANOMETALLICS

Pd-Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions

(2011) Georgiy Teverovskiy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Synthesis of Aryl Trifluoromethyl Sulfides at Room Temperature

(2011) Cheng-Pan Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Click-alkynylation of N- and P-nucleophiles by oxidative cross-coupling with alkynylcopper reagents: a general synthesis of ynamides and alkynylphosphonates

(2011) Kévin Jouvin et al.   Chemical Science

Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparation

(2010) Vladimir N Boiko   Beilstein Journal of Organic Chemistry

The mechanism of the modified Ullmann reaction

(2010) Elena Sperotto et al.   DALTON TRANSACTIONS

Catalytic CC, CN, and CO Ullmann-Type Coupling Reactions

(2009) Florian Monnier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis

(2008) Gwilherm Evano et al.   CHEMICAL REVIEWS

Studies on the 1,2-Migrations in Pd-Catalyzed Negishi Couplings with JosiPhos Ligands

(2008) Anders T. Lindhardt et al.   JOURNAL OF ORGANIC CHEMISTRY