Silver-mediated fluorination, trifluoromethylation, and trifluoromethylthiolation of arynes

A “Hot, Energized” Benzyne

(2013) Reinhard W. Hoffmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Mediated Trifluoromethylation–Iodination of Arynes

(2013) Yuwen Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkane C–H Insertion by Aryne Intermediates with a Silver Catalyst

(2013) Sang Young Yun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Computational Model to Predict the Synthetic Utility of Heterocyclic Arynes

(2012) Adam E. Goetz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ortho-Trifluoromethylation of Functionalized Aromatic Triazenes

(2012) Andreas Hafner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A “Renaissance” in Radical Trifluoromethylation

(2012) Armido Studer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides

(2012) Zhiqiang Weng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Comprehensive History of Arynes in Natural Product Total Synthesis

(2012) Pamela M. Tadross et al.   CHEMICAL REVIEWS

Nonmetathetic Activity of Ruthenium Alkylidene Complexes: 1,4-Hydrovinylative Cyclization of Multiynes with Ethylene

(2012) Sang Young Yun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Steric Effects Compete with Aryne Distortion To Control Regioselectivities of Nucleophilic Additions to 3-Silylarynes

(2012) Sarah M. Bronner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Fluorination of Aryl Iodides

(2012) Patrick S. Fier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The hexadehydro-Diels–Alder reaction

(2012) Thomas R. Hoye et al.   NATURE

Trifluoromethylation of heterocycles via visible light photoredox catalysis

(2012) Naeem Iqbal et al.   TETRAHEDRON LETTERS

Highly Selective Trifluoromethylation of 1,3-Disubstituted Arenes through Iridium-Catalyzed Arene Borylation

(2011) Tianfei Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ortho-Selective Nucleophilic Addition of Primary Amines to Silylbenzynes: Synthesis of 2-Silylanilines

(2011) Takashi Ikawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuRF]

(2011) Nichole D. Litvinas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Broadly Applicable Copper Reagent for Trifluoromethylations and Perfluoroalkylations of Aryl Iodides and Bromides

(2011) Hiroyuki Morimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions

(2011) Georgiy Teverovskiy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Regio- and Enantioselective Fluorination of Acyclic Allylic Halides

(2011) Matthew H. Katcher et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Synthesis of Aryl Trifluoromethyl Sulfides at Room Temperature

(2011) Cheng-Pan Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nucleophilic Aryl Fluorination and Aryl Halide Exchange Mediated by a CuI/CuIIICatalytic Cycle

(2011) Alicia Casitas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis

(2011) David A. Nagib et al.   NATURE

Synthesis of α-CN and α-CF3N-Heterocycles through Tandem Nucleophilic Additions

(2011) Junbin Han et al.   ORGANIC LETTERS

Silver-Mediated Trifluoromethylation of Arenes Using TMSCF3

(2011) Yingda Ye et al.   ORGANIC LETTERS

Innate C-H trifluoromethylation of heterocycles

(2011) Y. Ji et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Fluoride-Derived Electrophilic Late-Stage Fluorination Reagent for PET Imaging

(2011) E. Lee et al.   SCIENCE

Ynamides: A Modern Functional Group for the New Millennium

(2010) Kyle A. DeKorver et al.   CHEMICAL REVIEWS

Initiation and Termination Mode of Enyne Cross-Metathesis and Metallotropic [1,3]-Shift Controlled by Remote Substituents

(2010) Sang Young Yun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Activation of Benzene by Unsaturated η2-Cyclopropene and η2-Benzyne Complexes of Niobium

(2010) Cédric Boulho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Asymmetric Synthesis of Allylic Fluorides

(2010) Matthew H. Katcher et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indolyne and Aryne Distortions and Nucleophilic Regioselectivites

(2010) Paul H.-Y. Cheong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

(2010) E. J. Cho et al.   SCIENCE

Catalytic CC, CN, and CO Ullmann-Type Coupling Reactions

(2009) Florian Monnier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New trends in the chemistry of α-fluorinated ethers, thioethers, amines and phosphines

(2009) Baptiste Manteau et al.   JOURNAL OF FLUORINE CHEMISTRY

Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex

(2009) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Versatile Pd(OTf)2·2H2O-Catalyzedortho-Fluorination Using NMP as a Promoter

(2009) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The unique role of halogen substituents in the design of modern agrochemicals

(2009) Peter Jeschke   PEST MANAGEMENT SCIENCE

Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides

(2009) D. A. Watson et al.   SCIENCE

Palladium-Mediated Fluorination of Arylboronic Acids

(2008) Takeru Furuya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of11C,18F,15O, and13N Radiolabels for Positron Emission Tomography

(2008) Philip W. Miller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-catalyzed efficient tandem assembly of terminal alkynes and arynes: synthesis of alkynylated biphenyl derivatives

(2008) Chunsong Xie et al.   CHEMICAL COMMUNICATIONS

Molecular Imaging with PET

(2008) Simon M. Ametamey et al.   CHEMICAL REVIEWS

Fluorination of Nonactivated Haloarenes via Arynes under Mild Conditions, Resulting from Further Studies toward Ar−F Reductive Elimination from Palladium(II)

(2008) Vladimir V. Grushin et al.   ORGANOMETALLICS