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Title
Photocatalysis in organic and polymer synthesis
Authors
Keywords
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Journal
CHEMICAL SOCIETY REVIEWS
Volume 45, Issue 22, Pages 6165-6212
Publisher
Royal Society of Chemistry (RSC)
Online
2016-05-12
DOI
10.1039/c6cs00185h
References
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- Synthesis of aziridines by visible-light induced decarboxylative cyclization of N-aryl glycines and diazo compounds
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- Eosin Y catalyzed visible light mediated aerobic photo-oxidative cleavage of the C–C double bond of styrenes
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- Synthesis of sequence-defined acrylate oligomers via photo-induced copper-mediated radical monomer insertions
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- A well-defined, versatile photoinitiator (salen)Co–CO2CH3 for visible light-initiated living/controlled radical polymerization
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- Utilizing the electron transfer mechanism of chlorophyll a under light for controlled radical polymerization
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- A dual catalytic strategy for carbon–phosphorus cross-coupling via gold and photoredox catalysis
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- Versatile Synthetic Strategy for Coating Upconverting Nanoparticles with Polymer Shells through Localized Photopolymerization by Using the Particles as Internal Light Sources
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- Metal-Free Carbonylations by Photoredox Catalysis
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- Visible-Light-Induced Formal [3+2] Cycloaddition for Pyrrole Synthesis under Metal-Free Conditions
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- Turning lipophilic phthalocyanines/TiO2 composites into efficient photocatalysts for the conversion of CO2 into formic acid under UV–vis light irradiation
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- Visible light photoredox-catalysed intermolecular radical addition of α-halo amides to olefins
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- Visible-Light-Induced CS Bond Activation: Facile Access to 1,4-Diketones from β-Ketosulfones
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- Phototandem Catalysis: Efficient Synthesis of 3-Ester-3-hydroxy-2-oxindoles by a Visible Light-Induced Cyclization of Diazoamides through an Aerobic Oxidation Sequence
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- De Novo Synthesis of Imidazoles by Visible-Light-Induced Photocatalytic Aerobic Oxidation/[3+2] Cycloaddition/Aromatization Cascade
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- Visible-light photoredox-mediated oxidation of N-methyl tertiaryamines under catalyst free conditions: Direct synthesis of methylene-bridged bis-1,3-dicarbonyl compounds
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- A Practical and Stereoselective Organocatalytic Alkylation of Aldehydes with Benzodithiolylium Tetrafluoroborate
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- Visible-light-induced photocatalytic formyloxylation reactions of 3-bromooxindoles with water and DMF: the scope and mechanism
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- Synthesis of 2-substituted pyrimidines and benzoxazoles via a visible-light-driven organocatalytic aerobic oxidation: enhancement of the reaction rate and selectivity by a base
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- Synthesis of 6-substituted phenanthridines by metal-free, visible-light induced aerobic oxidative cyclization of 2-isocyanobiphenyls with hydrazines
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- The Development of Visible-Light Photoredox Catalysis in Flow
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- Photoirradiated Fe-Mediated AGET ATRP of Methyl Methacrylate in the Presence of Alcohol
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- A novel controlled grafting chemistry fully regulated by light for membrane surface hydrophilization and functionalization
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- A Visible-Light-Promoted Aerobic Metal-Free C-3 Thiocyanation of Indoles
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- Visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide as the initiator in conjugation with a photoredox catalystfac-[Ir(ppy)]3
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- Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis
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- Direct C–F Bond Formation Using Photoredox Catalysis
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- Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore
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- Synthesis of (−)-Pseudotabersonine, (−)-Pseudovincadifformine, and (+)-Coronaridine Enabled by Photoredox Catalysis in Flow
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- Metal-Free Atom Transfer Radical Polymerization
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- Dual Visible Light Photoredox and Gold-Catalyzed Arylative Ring Expansion
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- A Facile Visible-Light-Induced Route to Functionalize Polymeric Substrates by Combining Controlled Radical Grafting Polymerization and Thiol−Yne Click Chemistry with Photoredox Catalyst Ir(ppy)3
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- Spatial Control over Brush Growth through Sunlight-Induced Atom Transfer Radical Polymerization Using Dye-Sensitized TiO2as a Photocatalyst
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- UV Light as External Switch and Boost of Molar-Mass Control in Iodine-Mediated Polymerization
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- Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light
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- Photoinduced Electron Transfer–Reversible Addition–Fragmentation Chain Transfer (PET-RAFT) Polymerization of Vinyl Acetate and N-Vinylpyrrolidinone: Kinetic and Oxygen Tolerance Study
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- Oxygen Tolerance Study of Photoinduced Electron Transfer–Reversible Addition–Fragmentation Chain Transfer (PET-RAFT) Polymerization Mediated by Ru(bpy)3Cl2
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- Design of Novel Photoinitiators for Radical and Cationic Photopolymerizations under Near UV and Visible LEDs (385, 395, and 405 nm).
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- Visible light-mediated dehydrogenative β-arylsulfonylation of tertiary aliphatic amines with arylsulfonyl chlorides
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- Direct sp3 C–H acroleination of N-aryl-tetrahydroisoquinolines by merging photoredox catalysis with nucleophilic catalysis
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- Organic synthetic transformations using organic dyes as photoredox catalysts
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- Visible-Light-Promoted Radical C–H Trifluoromethylation of Free Anilines
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- Vicinal Difunctionalization of Alkenes: Chlorotrifluoromethylation with CF3SO2Cl by Photoredox Catalysis
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- Continuous Flow α-Trifluoromethylation of Ketones by Metal-Free Visible Light Photoredox Catalysis
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- Photocatalytic Decarboxylative Reduction of Carboxylic Acids and Its Application in Asymmetric Synthesis
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- Synthesis of 3-Acylindoles by Visible-Light Induced Intramolecular Oxidative Cyclization of o-Alkynylated N,N-Dialkylamines
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- Visible Light Photocatalyzed Direct Conversion of Aryl-/Heteroarylamines to Selenides at Room Temperature
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- Butyrolactone Synthesis via Polar Radical Crossover Cycloaddition Reactions: Diastereoselective Syntheses of Methylenolactocin and Protolichesterinic Acid
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- Visible-Light-Promoted Redox Neutral C–H Amidation of Heteroarenes with Hydroxylamine Derivatives
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- Photoredox-Induced Three-Component Azido- and Aminotrifluoromethylation of Alkenes
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- Photoredox-Catalyzed Tandem Radical Cyclization of N-Arylacrylamides: General Methods To Construct Fluorinated 3,3-Disubstituted 2-Oxindoles Using Fluoroalkylsulfonyl Chlorides
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- Visible Light-Mediated C–H Difluoromethylation of Electron-Rich Heteroarenes
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- Visible-Light-Driven Difluoroacetamidation of Unactive Arenes and Heteroarenes by Direct C–H Functionalization at Room Temperature
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- Photoredox-Induced Three-Component Oxy-, Amino-, and Carbotrifluoromethylation of Enecarbamates
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- ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp
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- Photo-induced copper-mediated polymerization of methyl acrylate in continuous flow reactors
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- Photoredox catalyst-mediated atom transfer radical addition for polymer functionalization under visible light
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- Visible light initiating systems for photopolymerization: status, development and challenges
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- Hierarchically porous π-conjugated polyHIPE as a heterogeneous photoinitiator for free radical polymerization under visible light
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- Reduction of aryl halides by consecutive visible light-induced electron transfer processes
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- A Dual-Catalysis Approach to Enantioselective [2 + 2] Photocycloadditions Using Visible Light
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- [3+2] Photooxygenation of aryl cyclopropanes via visible light photocatalysis
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- Visible-light-promoted aerobic oxidative cyclization to access 1,3,4-oxadiazoles from aldehydes and acylhydrazides
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- Photoinduced sequence-control via one pot living radical polymerization of acrylates
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- Highly efficient cycloreversion of photochromic dithienylethene compounds using visible light-driven photoredox catalysis
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- Aqueous photoinduced living/controlled polymerization: tailoring for bioconjugation
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- Sunlight photocatalyzed regioselective β-alkylation and acylation of cyclopentanones
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- Amine α-heteroarylation via photoredox catalysis: a homolytic aromatic substitution pathway
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- Aerobic Transition-Metal-Free Visible-Light Photoredox Indole C-3 Formylation Reaction
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- An approach to 6-trifluoromethyl-phenanthridines through visible-light-mediated intramolecular radical cyclization of trifluoroacetimidoyl chlorides
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- Facile and highly efficient “living” radical polymerization of hydrophilic vinyl monomers in water
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- Visible light driven photocatalytic oxidation of thiols to disulfides using iron phthalocyanine immobilized on graphene oxide as a catalyst under alkali free conditions
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- Dicyanopyrazine-derived push–pull chromophores for highly efficient photoredox catalysis
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- Photoredox catalytic organic reactions promoted with broadband visible light-absorbing Bodipy-iodo-aza-Bodipy triad photocatalyst
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- pH-sensitive membranes prepared with poly(methyl methacrylate) grafted poly(vinylidene fluoride) via ultraviolet irradiation-induced atom transfer radical polymerization
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- An easy access to unsymmetrical ureas: a photocatalytic approach to the Lossen rearrangement
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- Photoinduced Sequence-Controlled Copper-Mediated Polymerization: Synthesis of Decablock Copolymers
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- Controlled Radical Polymerization of Acrylates Regulated by Visible Light
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- Visible-Light Initiated Thiol-Michael Addition Photopolymerization Reactions
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- Combining Enzymatic Monomer Transformation with Photoinduced Electron Transfer − Reversible Addition–Fragmentation Chain Transfer for the Synthesis of Complex Multiblock Copolymers
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- Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds and carbon–carbon bond formation
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- Photopolymerization Reactions Using the Photoinitiated Copper (I)-Catalyzed Azide-Alkyne Cycloaddition (CuAAC) Reaction
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- Combining Visible Light Catalysis and Transition Metal Catalysis for the Alkylation of Secondary Amines
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- Controlled Trifluoromethylation Reactions of Alkynes through Visible-Light Photoredox Catalysis
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- Ambient-Light-Mediated Copper-Catalyzed CC and CN Bond Formation
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- Multicomponent Reactions in Polymer Synthesis
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- Fabrication of Complex Three-Dimensional Polymer Brush Nanostructures through Light-Mediated Living Radical Polymerization
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- Sequence Control in Polymer Chemistry through the Passerini Three-Component Reaction
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- Homogeneous Visible-Light Photoredox Catalysis
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- The Photoredox-Catalyzed Meerwein Addition Reaction: Intermolecular Amino-Arylation of Alkenes
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- The chemistry of amine radical cations produced by visible light photoredox catalysis
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- A novel copper containing photoinitiator, copper(ii) acylphosphinate, and its application in both the photomediated CuAAC reaction and in atom transfer radical polymerization
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- A room temperature decarboxylation/C–H functionalization cascade by visible-light photoredox catalysis
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- Synthesis of α,β-unsaturated carbonyl compounds via a visible-light-promoted organocatalytic aerobic oxidation
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- Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis
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- Visible light-mediated oxidative decarboxylation of arylacetic acids into benzyl radicals: addition to electron-deficient alkenes by using photoredox catalysts
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- Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis
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- Heterogeneous visible light photocatalysis for selective organic transformations
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- Visible Light-mediated Direct Arylation of Arenes and Heteroarenes Using Diaryliodonium Salts in the Presence and Absence of a Photocatalyst
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- Photocatalytic Hydrogen Evolution with a Self-Assembling Reductant-Sensitizer-Catalyst System
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- Phenanthrene Synthesis by Eosin Y-Catalyzed, Visible Light- Induced [4+2] Benzannulation of Biaryldiazonium Salts with Alkynes
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- Photo-controlled/living radical polymerization mediated by 2,2,6,6-tetramethylpiperidine-1-oxyl in inert atmospheres
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- Photochemically Mediated Atom Transfer Radical Polymerization of Methyl Methacrylate Using ppm Amounts of Catalyst
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- Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions
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- Photocatalytic alkoxylation of benzene with 3-cyano-1-methylquinolinium ion
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- Visible light photocatalysis of intramolecular radical cation Diels–Alder cycloadditions
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- Trifluoromethylation of heterocycles via visible light photoredox catalysis
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- Crossed intermolecular [2 + 2] cycloaddition of styrenes by visible light photocatalysis
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- Room temperature synthesis of isoquino[2,1-a][3,1]oxazine and isoquino[2,1-a]pyrimidine derivatives via visible light photoredox catalysis
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- Intermolecular [3+2] Cycloaddition of Cyclopropylamines with Olefins by Visible-Light Photocatalysis
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- Graft copolymerization of methyl methacrylate on polystyrene backbone through nitroxide-mediated photo-living radical polymerization
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- Nitroxide-mediated photo-controlled/living radical polymerization of ethyl acrylate
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- Nitroxide-mediated photo-controlled/living radical dispersion polymerization of methyl methacrylate
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- Dehydrogenative coupling reactions catalysed by Rose Bengal using visible light irradiation
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- Graphene oxide and Rose Bengal: oxidative C–H functionalisation of tertiary amines using visible light
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- Radical Cation Diels–Alder Cycloadditions by Visible Light Photocatalysis
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- Intermolecular Atom Transfer Radical Addition to Olefins Mediated by Oxidative Quenching of Photoredox Catalysts
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- Introducing Multicomponent Reactions to Polymer Science: Passerini Reactions of Renewable Monomers
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- Rapid UV Light-Triggered Macromolecular Click Conjugations via the Use of o-Quinodimethanes
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- Free Radical Polymerization Initiated and Controlled by Visible Light Photocatalysis at Ambient Temperature
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- Ambient Temperature Synthesis of Triblock Copolymers via Orthogonal Photochemically and Thermally Induced Modular Conjugation
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- ARGET ATRP of Methyl Acrylate with Inexpensive Ligands and ppm Concentrations of Catalyst
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- Spatial and temporal control of the alkyne–azide cycloaddition by photoinitiated Cu(II) reduction
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- Synthesis of oxindolesvia visible light photoredox catalysis
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- Functionally Diverse Nucleophilic Trapping of Iminium Intermediates Generated Utilizing Visible Light
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- Utilization of Natural Sunlight and Air in the Aerobic Oxidation of Benzyl Halides
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- Eosin Y Catalyzed Visible Light Oxidative C–C and C–P bond Formation
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- Synthetic and mechanistic inputs of photochemistry into the bis-acetylacetonatocobalt-mediated radical polymerization of n-butyl acrylate and vinyl acetate
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- Discovery of an -Amino C-H Arylation Reaction Using the Strategy of Accelerated Serendipity
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- Visible light photocatalysis of radical anion hetero-Diels–Alder cycloadditions
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- Photocatalytic reductive cyclizations of enones: Divergent reactivity of photogenerated radical and radical anion intermediates
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- Selective photocatalytic aerobic bromination with hydrogen bromide via an electron-transfer state of 9-mesityl-10-methylacridinium ion
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- Metal-Free, Cooperative Asymmetric Organophotoredox Catalysis with Visible Light
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- Stability of growing polymer chain ends for nitroxide-mediated photo-living radical polymerization
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- Organic dye photocatalyzed α-oxyamination through irradiation with visible light
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- Pyrromethene derivatives in three-component photoinitiating systems for free radical photopolymerization
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- Photoirradiated Atom Transfer Radical Polymerization with an Alkyl Dithiocarbamate at Ambient Temperature
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- Photophysics of Halogenated Fluoresceins: Involvement of Both Intramolecular Electron Transfer and Heavy Atom Effect in the Deactivation of Excited States
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- Highly efficient recyclable hydrated-clay supported catalytic system for atom transfer radical polymerization
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