Synthesis of β-Trifluoromethylated Ketones from Propargylic Alcohols by Visible Light Photoredox Catalysis

Mechanisms and applications of cyclometalated Pt(ii) complexes in photoredox catalytic trifluoromethylation

(2015) Won Joon Choi et al.   Chemical Science

Visible Light-Induced Aromatic Difluoroalkylation

(2014) Jaehun Jung et al.   ADVANCED SYNTHESIS & CATALYSIS

Rapid Access to β-Trifluoromethyl-Substituted Ketones: Harnessing Inductive Effects in Wacker-Type Oxidations of Internal Alkenes

(2014) Michael M. Lerch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combining Photoredox-Catalyzed Trifluoromethylation and Oxidation with DMSO: Facile Synthesis of α-Trifluoromethylated Ketones from Aromatic Alkenes

(2014) Ren Tomita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Addition of CF3 across unsaturated moieties: a powerful functionalization tool

(2014) Estíbaliz Merino et al.   CHEMICAL SOCIETY REVIEWS

Rapid Trifluoromethylation and Perfluoroalkylation of Five-Membered Heterocycles by Photoredox Catalysis in Continuous Flow

(2014) Natan J. W. Straathof et al.   ChemSusChem

Synthesis of α-Trifluoromethyl Ketones via the Cu-Catalyzed Trifluoromethylation of Silyl Enol Ethers Using an Electrophilic Trifluoromethylating Agent

(2014) Lun Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Photoredox-Induced Three-Component Oxy-, Amino-, and Carbotrifluoromethylation of Enecarbamates

(2014) Aude Carboni et al.   ORGANIC LETTERS

Trifluoromethylation by Visible-Light-Driven Photoredox Catalysis

(2014) Takashi Koike et al.   TOPICS IN CATALYSIS

Ruthenium-Catalyzed One-Pot Tandem Isomerization-Transfer Hydrogenation Reactions of γ-Trifluoromethylated Allylic Alcohols and β-Trifluoromethylated Enones

(2013) Vincent Bizet et al.   ADVANCED SYNTHESIS & CATALYSIS

Controlled Trifluoromethylation Reactions of Alkynes through Visible-Light Photoredox Catalysis

(2013) Naeem Iqbal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PhI(OAc)2-Mediated Radical Trifluoromethylation of Vinyl Azides with Me3SiCF3

(2013) Yi-Feng Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Trifluoromethylation of Unactivated Olefins: An Efficient and Practical Synthesis of α-Trifluoromethyl-Substituted Ketones

(2013) Arghya Deb et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective 1,4-trifluoromethylation of α,β-unsaturated ketones via aS-(trifluoromethyl)diphenylsulfonium salts/copper system

(2013) Satoshi Okusu et al.   Beilstein Journal of Organic Chemistry

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Generation of CF3-Containing Epoxides and Aziridines by Visible-Light-Driven Trifluoromethylation of Allylic Alcohols and Amines

(2013) Eunjin Kim et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sulfonation and Trifluoromethylation of Enol Acetates with Sulfonyl Chlorides Using Visible-Light Photoredox Catalysis

(2013) Heng Jiang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of β-CF3 ketones from trifluoromethylated allylic alcohols by ruthenium catalyzed isomerization

(2013) Vincent Bizet et al.   JOURNAL OF FLUORINE CHEMISTRY

Iron(II) complexes are suitable catalysts for the isomerization of trifluoromethylated allylic alcohols. Synthesis of trifluoromethylated dihydrochalcones

(2013) Dominique Cahard et al.   JOURNAL OF FLUORINE CHEMISTRY

Catalytic Hydrotrifluoromethylation of Unactivated Alkenes

(2013) Satoshi Mizuta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethylation of Allylsilanes under Photoredox Catalysis

(2013) Satoshi Mizuta et al.   ORGANIC LETTERS

Photocatalytic Synthesis of Allylic Trifluoromethyl Substituted Styrene Derivatives in Batch and Flow

(2013) Lukas M. Kreis et al.   ORGANIC LETTERS

Intermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox Catalysis

(2013) Yusuke Yasu et al.   ORGANIC LETTERS

Catalytic hydrotrifluoromethylation of styrenes and unactivated aliphatic alkenes via an organic photoredox system

(2013) Dale J. Wilger et al.   Chemical Science

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts

(2012) Yusuke Yasu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A “Renaissance” in Radical Trifluoromethylation

(2012) Armido Studer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Induced Photocatalytic Reductive Transformations of Organohalides

(2012) Hyejin Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Redox Isomerization of Trifluoromethylated Allylic Alcohols: Mechanistic Evidence for an Enantiospecific Pathway

(2012) Vincent Bizet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Synthesis of Trifluoromethyl-substituted Diarylpyrrolines: Enantioselective Conjugate Cyanation of β-Aryl-β-trifluoromethyl-disubstituted Enones

(2012) Hiroyuki Kawai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pyrazolopyrimidines as dual Akt/p70S6K inhibitors

(2012) Kenneth D. Rice et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I

(2012) Yingda Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible Light-Mediated Atom Transfer Radical Addition via Oxidative and Reductive Quenching of Photocatalysts

(2012) Carl-Johan Wallentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethylation of heterocycles via visible light photoredox catalysis

(2012) Naeem Iqbal et al.   TETRAHEDRON LETTERS

Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α-Trifluoromethyl Carbonyl Compounds

(2011) Phong V. Pham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes

(2011) Cheng-Pan Zhang et al.   CHEMICAL COMMUNICATIONS

Highly enantioselective yttrium(iii)-catalyzed Friedel–Crafts alkylation of β-trichloro(trifluoro)methyl aryl enones with indoles

(2011) Wentao Wang et al.   CHEMICAL COMMUNICATIONS

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Enantioselective Friedel−Crafts Alkylation of Indoles with Trifluoroethylidene Malonates by Copper−Bis(oxazoline) Complexes: Construction of Trifluoromethyl-Substituted Stereogenic Tertiary Carbon Center

(2011) Lele Wen et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis

(2011) David A. Nagib et al.   NATURE

Photocatalytic reductive cyclizations of enones: Divergent reactivity of photogenerated radical and radical anion intermediates

(2011) Juana Du et al.   Chemical Science

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of Functionalized Indoles with a Trifluoromethyl-Substituted Stereogenic Tertiary Carbon Atom Through an Enantioselective Friedel-Crafts Alkylation with β-Trifluoromethyl-α,β-enones

(2010) Gonzalo Blay et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Productive Merger of Iodonium Salts and Organocatalysis: A Non-photolytic Approach to the Enantioselective α-Trifluoromethylation of Aldehydes

(2010) Anna E. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible light photocatalysis as a greener approach to photochemical synthesis

(2010) Tehshik P. Yoon et al.   Nature Chemistry

Enantioselective Friedel−Crafts Reaction of β-Trifluoromethylated Acrylates with Pyrroles and Its Application to the Synthesis of Trifluorinated Heliotridane

(2010) Yiyong Huang et al.   ORGANIC LETTERS

Nucleophilic trifluoromethylation of arylidene Meldrum’s acids

(2009) Artem A. Zemtsov et al.   TETRAHEDRON LETTERS

A first high enantiocontrol of an asymmetric tertiary carbon center attached with a fluoroalkyl group via Rh(I)-catalyzed conjugate addition reaction

(2008) Tsutomu Konno et al.   TETRAHEDRON LETTERS