Journal
CHEMICAL SCIENCE
Volume 6, Issue 2, Pages 1194-1198Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sc03092c
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Funding
- NIHGMS [RO1 GM073932]
- National Natural Science Foundation of China [21332005]
- Jiangsu Educational Innovation Team Program (P.R. China)
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM073932] Funding Source: NIH RePORTER
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A new method for the P-arylation of aryldiazonium salts with H-phosphonates via dual gold and photoredox catalysis is described. The reaction proceeds smoothly at room temperature in the absence of base and/or additives, and offers an efficient approach to arylphosphonates. The reaction is proposed to proceed through a photoredox-promoted generation of an electrophilic arylgold(III) intermediate that undergoes coupling with the H-phosphonate nucleophile.
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