Searching for Practically Useful P-Chirogenic Phosphine Ligands

Highly Enantioselective Rhodium-Catalyzed Addition of Arylboroxines to Simple Aryl Ketones: Efficient Synthesis of Escitalopram

(2016) Linwei Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh-Catalyzed One-Pot Sequential Asymmetric Hydrogenation of α-Dehydroamino Ketones for the Synthesis of Chiral Cyclic trans-β-Amino Alcohols

(2016) Qiupeng Hu et al.   ORGANIC LETTERS

Enantioselection mechanism in Rh-catalyzed asymmetric hydrogenation

(2016) I. D. Gridnev et al.   RUSSIAN CHEMICAL BULLETIN

Catalytic Enantioselective Intramolecular Aza-Diels-Alder Reactions

(2015) Chang Min et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed Asymmetric Hydrogenation of α-Dehydroamino Ketones: A General Approach to Chiral α-amino Ketones

(2015) Wenchao Gao et al.   Chemistry-An Asian Journal

P-Stereogenic pincer iridium complexes: Synthesis, structural characterization and application in asymmetric hydrogenation

(2015) Zehua Yang et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Enantioselective Synthesis of Hemiaminals via Pd-Catalyzed C–N Coupling with Chiral Bisphosphine Mono-oxides

(2015) Hongming Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Enantioselective Cross-Coupling Reactions of α-Chloroesters with Aryl Grignard Reagents

(2015) Masayoshi Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Diarylation of Alkenes

(2015) Wei You et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

P-stereogenic PNP pincer-Pd catalyzed intramolecular hydroamination of amino-1,3-dienes

(2015) Zehua Yang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Highly Efficient Synthesis of Chiral α-CF3 Amines via Rh-Catalyzed Asymmetric Hydrogenation

(2015) Jun Jiang et al.   ORGANIC LETTERS

Synthesis and Structural Characterization of Nickel Complexes Possessing P-Stereogenic Pincer Scaffolds and Their Application in Asymmetric Aza-Michael Reactions

(2015) Zehua Yang et al.   ORGANOMETALLICS

Utilization of optically active secondary phosphine–boranes: synthesis of P-chiral diphosphines and their enantioinduction ability in rhodium-catalyzed asymmetric hydrogenation

(2015) Tsuneo Imamoto et al.   TETRAHEDRON

Asymmetric Michael addition of diphenylphosphine to β,γ-unsaturated α-keto esters catalyzed by a P-stereogenic pincer-Pd complex

(2015) Yang Xu et al.   TETRAHEDRON

Challenging the Major/Minor Concept in Rh-Catalyzed Asymmetric Hydrogenation

(2015) Ilya D. Gridnev et al.   ACS Catalysis

MaxPHOS Ligand: PH/NH Tautomerism and Rhodium- Catalyzed Asymmetric Hydrogenations

(2014) Edgar Cristóbal-Lecina et al.   ADVANCED SYNTHESIS & CATALYSIS

ZnCl2-Promoted Asymmetric Hydrogenation of β-Secondary-Amino Ketones Catalyzed by a P-Chiral Rh-Bisphosphine Complex

(2014) Qiupeng Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Experimental and Computational Studies of the Mechanisms of Enantioselection in Asymmetric Catalytic Reactions

(2014) Ilya D. Gridnev   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

Copper(I)-Catalyzed Enantioselective Synthesis of α-Chiral Linear or Carbocyclic (E)-(γ-Alkoxyallyl)boronates

(2014) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Synthesis of Chiral Cyclic Allylic Amines via Rh-Catalyzed Asymmetric Hydrogenation

(2014) Ming Zhou et al.   ORGANIC LETTERS

Rhodium Asymmetric Hydrogenation Observed during its Exponential Growth Phase

(2014) John M. Brown   ORGANOMETALLICS

Regio- and Enantioselective Monoborylation of Alkenylsilanes Catalyzed by an Electron-Donating Chiral Phosphine-Copper(I) Complex

(2013) Koji Kubota et al.   ADVANCED SYNTHESIS & CATALYSIS

Design of Phosphorus Ligands with Deep Chiral Pockets: Practical Synthesis of Chiral β-Arylamines by Asymmetric Hydrogenation

(2013) Guodu Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Chiral Aliphatic Amines through Asymmetric Hydrogenation

(2013) Tang-Lin Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Optically Pure 2-Trifluoromethyl Lactic Acid by Asymmetric Hydroformylation

(2013) Xiao Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

o-(Hydroxyalkyl)phenyl P-Chirogenic Phosphines as Functional Chiral Lewis Bases

(2013) Emmanuelle Rémond et al.   ORGANIC LETTERS

P-Stereogenic PCP Pincer–Pd Complexes: Synthesis and Application in Asymmetric Addition of Diarylphosphines to Nitroalkenes

(2013) Boqiang Ding et al.   ORGANIC LETTERS

Cobalt Precursors for High-Throughput Discovery of Base Metal Asymmetric Alkene Hydrogenation Catalysts

(2013) M. R. Friedfeld et al.   SCIENCE

Search for Ideal P-Chiral Phosphorus Ligands for Practical Asymmetric Hydrogenation and Asymmetric Suzuki–Miyaura Coupling

(2013) Wenjun Tang et al.   SYNLETT

Mechanism of Asymmetric Hydrogenation of β-Dehydroamino Acids Catalyzed by Rhodium Complexes: Large-Scale Experimental and Computational Study

(2013) Ilya D. Gridnev et al.   ACS Catalysis

Enantioselective β-Arylation of Ketones Enabled by Lithiation/Borylation/1,4-Addition Sequence Under Flow Conditions

(2012) Wei Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes

(2012) Takahiro Sawano et al.   CHEMICAL COMMUNICATIONS

Three-Hindered Quadrant Phosphine Ligands with an Aromatic Ring Backbone for the Rhodium-Catalyzed Asymmetric Hydrogenation of Functionalized Alkenes

(2012) Zhenfeng Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Synthesis of o-Bromo (or Iodo)aryl P-Chirogenic Phosphines Based on Aryne Chemistry

(2012) Jérôme Bayardon et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Carbon–Silicon Bond Activation for Synthesis of Benzosilole Derivatives

(2012) Masahiro Onoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent developments in the asymmetric synthesis of Р-chiral phosphorus compounds

(2012) Oleg I. Kolodiazhnyi   TETRAHEDRON-ASYMMETRY

New Synthetic Strategy for High-Enantiopurity N-Protected α-Amino Ketones and their Derivatives by Asymmetric Hydrogenation

(2011) Tian Sun et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates

(2011) Yusuke Sasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereocontrol in Asymmetric Allyl–Allyl Cross-Coupling: Stereocontrolled Reaction of Prochiral Allylboronates with Prochiral Allyl Chlorides

(2011) Laura A. Brozek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Asymmetric Hydroformylation of Functionalized 1,1-Disubstituted Olefins

(2011) Xiao Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rigid P-Chiral Phosphine Ligands with tert-Butylmethylphosphino Groups for Rhodium-Catalyzed Asymmetric Hydrogenation of Functionalized Alkenes

(2011) Tsuneo Imamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Profiling the tuneable R-SMS-Phos structure in the rhodium(i)-catalyzed hydrogenation of olefins: the last stand?

(2011) Michel Stephan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Asymmetric 1,4-Hydroboration of Coumarins with Pinacolborane: Asymmetric Synthesis of Dihydrocoumarins

(2010) Hyohyun Kim et al.   ADVANCED SYNTHESIS & CATALYSIS

Electron-Donating and Rigid P-Stereogenic Bisphospholane Ligands for Highly Enantioselective Rhodium-Catalyzed Asymmetric Hydrogenations

(2010) Xiaowei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Primary and Secondary Aminophosphines as Novel P-Stereogenic Building Blocks for Ligand Synthesis

(2010) Marc Revés et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation

(2010) Kexuan Huang et al.   CHEMICAL COMMUNICATIONS

Highly Efficient RhI-Catalyzed Asymmetric Hydrogenation of β-Amino Acrylonitriles

(2010) Miaofeng Ma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Conjugate Boration of β,β-Disubstituted Unsaturated Esters: Asymmetric Synthesis of Functionalized Chiral Tertiary Organoboronic Esters

(2010) Xinhui Feng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of Optically Pure β-Amino Ketones and γ-Aryl Amines by Rh-Catalyzed Asymmetric Hydrogenation

(2010) Huiling Geng et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Nitroso Aldol Reaction Catalyzed by QuinoxP*·Silver(I) Complex and Tin Methoxide

(2010) Akira Yanagisawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct enantio-convergent transformation of racemic substrates without racemization or symmetrization

(2010) Hajime Ito et al.   Nature Chemistry

Enantiopure 1,2-Bis(tert-butylmethylphosphino)benzene as a Highly Efficient Ligand in Rhodium-Catalyzed Asymmetric Hydrogenation

(2010) Ken Tamura et al.   ORGANIC LETTERS

Heavyweight “R-SMS-Phos” Ligands in the Olefins’ Hydrogenation Arena

(2010) Borut Zupančič et al.   ORGANIC LETTERS

Impact on Hydrogenation Catalytic Cycle of the R Groups’ Cyclic Feature in “R-SMS-Phos”

(2010) Borut Zupančič et al.   ORGANIC LETTERS

Novel and Efficient Chiral Bisphosphorus Ligands for Rhodium-Catalyzed Asymmetric Hydrogenation

(2010) Wenjun Tang et al.   ORGANIC LETTERS

Improved synthetic routes to methylene-bridged P-chiral diphosphine ligands via secondary phosphine–boranes

(2010) Tsuneo Imamoto et al.   TETRAHEDRON-ASYMMETRY

DiPAMP’s Big Brother “i-Pr-SMS-Phos” Exhibits Exceptional Features Enhancing Rhodium(I)-Catalyzed Hydrogenation of Olefins

(2009) Michel Stephan et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Enantioselective Synthesis of Chiral Tetraphenylenes: Consecutive Inter- and Intramolecular Cycloadditions of Two Triynes

(2009) Takanori Shibata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes

(2009) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Enantioselective and Diastereoselective Hydrogenation of β-Ketoenamides: Efficient Access toanti1,3-Amino Alcohols

(2009) Huiling Geng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of enantioselection in Rh-catalyzed asymmetric hydrogenation. The origin of utmost catalytic performance

(2009) Ilya D. Gridnev et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes

(2009) Yu Shibata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters through Conjugate Boration of β-Substituted Cyclic Enones

(2009) I-Hon Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Novel, Tunable, and Efficient Chiral Bisdihydrobenzooxaphosphole Ligands for Asymmetric Hydrogenation

(2009) Wenjun Tang et al.   ORGANIC LETTERS

Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative

(2008) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Synthesis of Chiral β-Arylisopropylamines by Using Catalytic Asymmetric Hydrogenation

(2008) Jian Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Hydrogenation Catalyzed by a Rhodium Complex of (R)-(tert-Butylmethylphosphino)(di-tert-butylphosphino)methane:  Scope of Enantioselectivity and Mechanistic Study

(2008) Ilya D. Gridnev et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Convenient Synthesis and the Asymmetric Hydrogenation ofN-Phthaloyl Dehydroamino Acid Esters

(2008) Jian Chen et al.   ORGANIC LETTERS

Development of a new class of C1-symmetric bisphosphine ligands for rhodium-catalyzed asymmetric hydrogenation

(2008) Qian Dai et al.   TETRAHEDRON