Functional group migrations between boron and metal centres within transition metal–borane and –boryl complexes and cleavage of H–H, E–H and E–E′ bonds

Coordination- and Redox-Noninnocent Behavior of Ambiphilic Ligands Containing Antimony

(2016) J. Stuart Jones et al.   ACCOUNTS OF CHEMICAL RESEARCH

Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex

(2016) Pablo Ríos et al.   CHEMICAL COMMUNICATIONS

Main Group Lewis Acid-Mediated Transformations of Transition-Metal Hydride Complexes

(2016) Ayan Maity et al.   CHEMICAL REVIEWS

Complexes of ambiphilic ligands: reactivity and catalytic applications

(2016) Ghenwa Bouhadir et al.   CHEMICAL SOCIETY REVIEWS

Insertion Reactions of Neutral Phosphidozirconocene Complexes as a Convenient Entry into Frustrated Lewis Pair Territory

(2016) Adrien T. Normand et al.   CHEMISTRY-A EUROPEAN JOURNAL

Scorpionate Compounds

(2016) Claudio Pettinari   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Facile Insertion of Rh and Ir into a Boron–Phenyl Bond, Leading to Boryl/Bis(phosphine) PBP Pincer Complexes

(2016) Wei-Chun Shih et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal- and Ligand-Centered Reactivity of meta-Carboranyl-Backbone Pincer Complexes of Rhodium

(2016) Bennett J. Eleazer et al.   ORGANOMETALLICS

General H2 Activation Modes for Lewis Acid–Transition Metal Bifunctional Catalysts

(2016) Yinwu Li et al.   ACS Catalysis

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Ligand Cooperation

(2015) Julia R. Khusnutdinova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis pair behavior of monomeric (boryl)iminomethanes accessed from isocyanide 1,1-hydroboration

(2015) Brandon R. Barnett et al.   CHEMICAL COMMUNICATIONS

Neutral organoantimony(III) and organobismuth(III) ligands as acceptors in transition metal complexes – Role of substituents and co-ligands

(2015) Sophie L. Benjamin et al.   COORDINATION CHEMISTRY REVIEWS

A theoretical analysis of ambivalent and ambiphilic Lewis acid/bases with symmetry signatures

(2015) D. Michael P. Mingos   COORDINATION CHEMISTRY REVIEWS

Evaluating Molecular Cobalt Complexes for the Conversion of N2 to NH3

(2015) Trevor J. Del Castillo et al.   INORGANIC CHEMISTRY

E–H Bond Activations and Hydrosilylation Catalysis with Iron and Cobalt Metalloboranes

(2015) Mark A. Nesbit et al.   ORGANOMETALLICS

Nickel and Palladium Complexes of Ferrocene-Backbone Bisphosphine-Borane and Trisphosphine Ligands

(2015) Bradley E. Cowie et al.   ORGANOMETALLICS

Synthesis of Pincer Iridium Complexes Bearing a Boron Atom and iPr-Substituted Phosphorus Atoms: Application to Catalytic Transfer Dehydrogenation of Alkanes

(2015) Keita Tanoue et al.   ORGANOMETALLICS

Synthesis and Reactivity of Palladium Complexes Featuring a Diphosphinoborane Ligand

(2015) Tobias Schindler et al.   ORGANOMETALLICS

Bis-hydrocarbyl Platinum(II) Ambiphilic Ligand Complexes: Alkyl–Aryl Exchange between Platinum and Boron

(2015) Bradley E. Cowie et al.   ORGANOMETALLICS

Theoretical Studies on the Mechanism of Homogeneous Catalytic Olefin Hydrogenation and Amine–Borane Dehydrogenation by a Versatile Boryl-Ligand-Based Cobalt Catalyst

(2015) Gaurab Ganguly et al.   ACS Catalysis

Synthesis and Platinum Complexes of an Alane-Appended 1,1′-Bis(phosphino)ferrocene Ligand

(2014) Bradley E. Cowie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperation between Transition Metals and Lewis Acids: A Way To Activate H2and HE bonds

(2014) Marc Devillard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox and Anion Exchange Chemistry of a Stibine-Nickel Complex: Writing the L, X, Z Ligand Alphabet with a Single Element

(2014) James S. Jones et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boryl-assisted hydrogenolysis of a nickel–methyl bond

(2014) Natalia Curado et al.   CHEMICAL COMMUNICATIONS

Ru-η6-Arene Cations [{(Ph2PC6H4)2B(η6-Ph)}RuX]+(X=Cl, H) as Lewis Acids

(2014) Michael P. Boone et al.   CHEMISTRY-A EUROPEAN JOURNAL

Platinum Complexes of a Borane-Appended Analogue of 1,1′-Bis(diphenylphosphino)ferrocene: Flexible Borane Coordination Modes and in situ Vinylborane Formation

(2014) Bradley E. Cowie et al.   CHEMISTRY-A EUROPEAN JOURNAL

Free H2 Rotation vs Jahn–Teller Constraints in the Nonclassical Trigonal (TPB)Co–H2 Complex

(2014) William A. Gunderson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative Transition Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)iminomethane Complex: A Significant Metal–Borane Interaction Promoted by a Small Bite-Angle LZ Chelate

(2014) Brandon R. Barnett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boryl–Metal Bonds Facilitate Cobalt/Nickel-Catalyzed Olefin Hydrogenation

(2014) Tzu-Pin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Bonding Properties of Ruthenium Complexes Possessing a Boron-Based PBP Pincer Ligand and Their Application for Catalytic Hydrogenation

(2014) Takuma Miyada et al.   ORGANOMETALLICS

A brief history of scorpionates

(2013) Glenn P. A. Yap   ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS

A d10Ni-(H2) Adduct as an Intermediate in HH Oxidative Addition across a NiB Bond

(2013) W. Hill Harman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative C(sp3)–H bond cleavage, C–C and CC coupling at a boron center with O2 as the oxidant mediated by platinum(ii)

(2013) S. Pal et al.   CHEMICAL COMMUNICATIONS

Recent Developments in the Coordination Chemistry of Multidentate Ligands Featuring a Boron Moiety

(2013) Hajime Kameo et al.   Chemistry-An Asian Journal

Reactions of dimethylzirconocene complexes with a vicinal frustrated P/B Lewis pair

(2013) Silke Frömel et al.   DALTON TRANSACTIONS

Benzannulated tris(2-mercapto-1-imidazolyl)hydroborato ligands: tetradentate κ4-S3H binding and access to monomeric monovalent thallium in an [S3] coordination environment

(2013) Yi Rong et al.   DALTON TRANSACTIONS

Unexpected Electronic Process of H2 Activation by a New Nickel Borane Complex: Comparison with the Usual Homolytic and Heterolytic Activations

(2013) Guixiang Zeng et al.   INORGANIC CHEMISTRY

H–H and Si–H Bond Addition to Fe≡NNR2 Intermediates Derived from N2

(2013) Daniel L. M. Suess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A CO-Derived Iron Dicarbyne That Releases Olefin upon Hydrogenation

(2013) Daniel L. M. Suess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boryl-Mediated Reversible H2 Activation at Cobalt: Catalytic Hydrogenation, Dehydrogenation, and Transfer Hydrogenation

(2013) Tzu-Pin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Oxygenation of a Ruthenium Complex Bearing a PBP-Pincer Ligand Inducing the Formation of a Boronato Ligand with a Weak Ru–O Bond

(2013) Takuma Miyada et al.   ORGANOMETALLICS

Insight into the Hydrogen Migration Processes Involved in the Formation of Metal–Borane Complexes: Importance of the Third Arm of the Scorpionate Ligand

(2013) Nikolaos Tsoureas et al.   ORGANOMETALLICS

Bridging Rhodium–Iron Borataaminocarbyne Complexes Formed by Intramolecular Isonitrile–Borane Coordination

(2013) Bradley E. Cowie et al.   ORGANOMETALLICS

Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane

(2013) Henry Fong et al.   ORGANOMETALLICS

Facile Si–H bond activation and hydrosilylation catalysis mediated by a nickel–borane complex

(2013) Samantha N. MacMillan et al.   Chemical Science

Isolation of a PBP-Pincer Rhodium Complex Stabilized by an Intermolecular CH σ Coordination as the Fourth Ligand

(2012) Maki Hasegawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Only Lewis Pairs with Transition Metal Lewis Bases

(2012) Jürgen Bauer et al.   CHEMICAL REVIEWS

Hydrogen atom storage upon Z-class borane ligand functions: an alternative approach to ligand cooperation

(2012) Gareth R. Owen   CHEMICAL SOCIETY REVIEWS

Oxidation of dimethyldi(2-pyridyl)borato PtIIMen complexes, n = 1, 0, with H2O2: tandem B-to-Pt methyl group migration and formation of C–O bond

(2012) Shrinwantu Pal et al.   DALTON TRANSACTIONS

Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene

(2012) Hayato Ogawa et al.   DALTON TRANSACTIONS

Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis

(2012) W. Hill Harman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Outer sphere hydrogenation catalysis

(2012) Odile Eisenstein et al.   NEW JOURNAL OF CHEMISTRY

Synthesis of Rhodaboratranes Bearing Phosphine-Tethered Boranes: Evaluation of the Metal–Boron Interaction

(2012) Hajime Kameo et al.   ORGANOMETALLICS

Synthesis of a Rhodium Complex Featuring the Rh–H–B Linkage via a Hydride Migration from Rhodium to Borane: Study on the Electronic Deviation Induced by the Presence of the Boron Moiety

(2012) Hajime Kameo et al.   ORGANOMETALLICS

Thermally stable N2 and H2 adducts of cationic nickel(ii)

(2012) Charlene Tsay et al.   Chemical Science

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Alfred Werner’s Coordination Chemistry: New Insights from Old Samples

(2011) Karl-Heinz Ernst et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Abstraction of β-hydrogenvs.alkyl groups in reactions of dialkylzinc compounds and bis(oxazolinyl)borane

(2011) Jing Zhu et al.   CHEMICAL COMMUNICATIONS

Synthesis and characterisation of group nine transition metal complexes containing new mesityl and naphthyl based azaindole scorpionate ligands

(2011) Gareth R. Owen et al.   DALTON TRANSACTIONS

Organometallic frustrated Lewis pair chemistry

(2011) Gerhard Erker   DALTON TRANSACTIONS

Novel Pyridazine Based Scorpionate Ligands in Cobalt and Nickel Boratrane Compounds

(2011) Gernot Nuss et al.   INORGANIC CHEMISTRY

Scorpionate Ligands Based on 2-Mercaptopyridine: A Ligand with a Greater Propensity To Sting?

(2011) Gavin Dyson et al.   ORGANOMETALLICS

σ-Acceptor, Z-type ligands for transition metals

(2010) Abderrahmane Amgoune et al.   CHEMICAL COMMUNICATIONS

Double addition of H2to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres

(2010) Nikolaos Tsoureas et al.   CHEMICAL COMMUNICATIONS

Electron-Precise Coordination Modes of Boron-Centered Ligands

(2010) Holger Braunschweig et al.   CHEMICAL REVIEWS

Isomerism in rhodium(i) N,S-donor heteroscorpionates: ring substituent and ancillary ligand effects

(2010) Robin J. Blagg et al.   DALTON TRANSACTIONS

Fluxional rhodium scorpionate complexes of the hydrotris(methimazolyl)borate (Tm) ligand and their static boratrane derivatives

(2010) María J. López-Gómez et al.   DALTON TRANSACTIONS

Transition metals as Lewis bases: “Z-type” boron ligands and metal-to-boron dative bonding

(2010) Holger Braunschweig et al.   DALTON TRANSACTIONS

Analogies between Metallaboratranes, Triboronates, and Boron Pincer Ligand Complexes†

(2010) Anthony F. Hill et al.   ORGANOMETALLICS

The Give and Take of Alcohol Activation

(2010) A. J. A. Watson et al.   SCIENCE

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A new family of metallaboratrane complexes based on 7-azaindole: B–H activation mediated by carbon monoxide

(2009) Nikolaos Tsoureas et al.   CHEMICAL COMMUNICATIONS

A novel route to rhodaboratranes [Rh(CO)(PR3){B(taz)3}]+via the redox activation of scorpionate complexes [RhLL′Tt]

(2009) Robin J. Blagg et al.   DALTON TRANSACTIONS

Soft Scorpionate Ligands Based on Imidazole-2-thione Donors

(2009) Mark D. Spicer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand

(2009) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diphenylphosphino- or Dicyclohexylphosphino-Tethered Boryl Pincer Ligands: Syntheses of PBP Iridium(III) Complexes and Their Conversion to Iridium−Ethylene Complexes

(2009) Yasutomo Segawa et al.   ORGANOMETALLICS

Further Exploring the “Sting of the Scorpion”: Hydride Migration and Subsequent Rearrangement of Norbornadiene to Nortricyclyl on Rhodium(I)

(2009) Nikolaos Tsoureas et al.   ORGANOMETALLICS

Crystal field arguments to explain the trans labilisation within transition metal–borane complexes

(2009) Gareth R. Owen   TRANSITION METAL CHEMISTRY

Reactivity of the Ni→B dative σ-bond in the nickel boratrane compounds [κ4-B(mimBut)3]NiX (X = Cl, OAc, NCS, N3): synthesis of a series of B-functionalized tris(2-mercapto-1-tert-butylimidazolyl)borato complexes, [YTmBut]NiZ

(2008) Keliang Pang et al.   CHEMICAL COMMUNICATIONS

A ‘sting’ on Grubbs’ catalyst: an insight into hydride migration between boron and a transition metal

(2008) Georg C. Rudolf et al.   CHEMICAL COMMUNICATIONS

Multidentate ligand systems featuring dual functionality

(2008) Istemi Kuzu et al.   DALTON TRANSACTIONS

Flexible scorpionates for transfer hydrogenation: the first example of their catalytic application

(2008) Nikolaos Tsoureas et al.   DALTON TRANSACTIONS

β-Phosphinoethylboranes as Ambiphilic Ligands in Nickel−Methyl Complexes

(2008) Andreas Fischbach et al.   ORGANOMETALLICS

Unlocking the metallaboratrane cage: reversible B–H activation in platinaboratranes

(2007) Ian R. Crossley et al.   DALTON TRANSACTIONS