Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 12, Pages 1553-1574Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200801240
Keywords
Tripodal ligands; S ligands; Scorpionate ligands; Imidazole-2-thione; Metal complexes; Transition metals; Coordination modes
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This review describes the development. of the anionic soft scorpionate ligand hydrotris(methimazolyl)borate (Tm-Mc), its N-alkyl and N-aryl congeners and draws comparisons where appropriate with its close relatives, the dihydrobis(methimazolyl)borates (Bm(R)). Key features of the interaction of these species with metal centres, including bonding modes, electron-donor properties, M center dot center dot center dot H-B interactions, ligand degradation and metallaboratrane formation are addressed and a summary of the coordination chemistry of these species with both main (Foul) and transition metals is given. ((C) Wiley-VCH Velag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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