Recent Advances and Perspectives in Transition Metal‐Catalyzed 1,4‐Functionalizations of Unactivated 1,3‐Enynes for the Synthesis of Allenes

Triple-Bond Insertion Triggers Highly Regioselective 1,4-Aminomethylamination of 1,3-Enynes with Aminals Enabled by Pd-Catalyzed C–N Bond Activation

(2019) Yanchen Zhang et al.   ORGANIC LETTERS

Nickel catalyzed functionalization of allenes

(2019) Yang Liu et al.   CHINESE JOURNAL OF CHEMISTRY

Nickel-Catalyzed Carbofluoroalkylation of 1,3-Enynes to Access Structurally Diverse Fluoroalkylated Allenes

(2019) Kai-Fan Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of Chiral Allenes through Pd-Catalyzed Intermolecular Hydroamination of Conjugated Enynes: Enantioselective Synthesis Enabled by Catalyst Design

(2019) Nathan J. Adamson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Negishi Coupling for Highly Selective Syntheses of Allenes via Ligand Effect and Mechanistic Study via SAESI‐MS/MS

(2019) Yangguangyan Zheng et al.   CHINESE JOURNAL OF CHEMISTRY

Divergent Synthesis of CF3 -Substituted Allenyl Nitriles by Ligand-Controlled Radical 1,2- and 1,4-Addition to 1,3-Enynes

(2018) Fei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Formation of Chiral Trisubstituted Allenes and Chiral Furan Derivatives

(2018) Pernille H. Poulsen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Trisubstituted Allenyl–B(pin) Compounds by Phosphine–Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu–Allenyl Intermediates

(2018) Youming Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic, Enantioselective Synthesis of Allenyl Boronates

(2018) De-Wei Gao et al.   ACS Catalysis

Copper-catalyzed asymmetric hydroboration of 1,3-enynes with pinacolborane to access chiral allenylboronates

(2018) Hui Leng Sang et al.   Organic Chemistry Frontiers

Copper-Catalyzed Radical 1,4-Difunctionalization of 1,3-Enynes with Alkyl Diacyl Peroxides and N-Fluorobenzenesulfonimide

(2018) Xiaotao Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in catalytic asymmetric synthesis of allenes

(2017) Wen-Dao Chu et al.   Catalysis Science & Technology

Propargyl Radical Chemistry: Renaissance Instigated by Metal Coordination

(2015) Gagik G. Melikyan   ACCOUNTS OF CHEMICAL RESEARCH

Conquering three-carbon axial chirality of allenes

(2014) Juntao Ye et al.   Organic Chemistry Frontiers

Ni-Catalyzed Three-component Coupling Reaction of Conjugated Enyne, Carbonyls, and Dimethylzinc to Construct Allenyl Alcohols

(2013) Yasuyuki Mori et al.   CHEMISTRY LETTERS

Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes

(2013) Hui Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in the Catalytic Syntheses of Allenes: A Critical Assessment

(2013) Robynne K. Neff et al.   ACS Catalysis

EPR Investigation of Zinc/Iodine Exchange between Propargyl Iodides and Diethylzinc: Detection of Propargyl Radical by Spin Trapping

(2012) Julien Maury et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Vinylation of Aminals with Simple Alkenes: A New Strategy To Construct Allylamines

(2012) Yinjun Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

How easy are the syntheses of allenes?

(2011) Shichao Yu et al.   CHEMICAL COMMUNICATIONS

Unexpected Electrophilic Rearrangements of Amides: A Stereoselective Entry to Challenging Substituted Lactones

(2010) Claire Madelaine et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoenzymatic Dynamic Kinetic Resolution of Axially Chiral Allenes

(2010) Jan Deska et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereoretentive Suzuki−Miyaura Coupling of Haloallenes Enables Fully Stereocontrolled Access to (−)-Peridinin

(2010) Eric M. Woerly et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Ligand Properties of a Persistent, All-Carbon Four-Membered-Ring Allene

(2009) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni-catalyzed regioselective three-component coupling of alkyl halides, arylalkynes, or enynes with R–M (M = MgX′, ZnX′)

(2009) Jun Terao et al.   CHEMICAL COMMUNICATIONS

Experimental and Theoretical Study of Tunable 1,3-Lithium Shift of Propargylic/Allenylic Species, Transmetallation, and Pd-Catalyzed Cross-Coupling Reactions

(2009) Jinbo Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Concise Synthesis of (-)- and (+)-trans-Whisky Lactones

(2009) Xinpeng Jiang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cationic Rhodium(I)−dppf Complex-Catalyzed Olefin Isomerization/Propargyl Claisen Rearrangement/Carbonyl Migration Cascade

(2009) Ken Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

DABCO-Catalyzed 1,4-Bromolactonization of Conjugated Enynes: Highly Stereoselective Formation of a Stereogenic Center and an Axially Chiral Allene

(2009) Wen Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Synthesis of 1,1-Difluoroallenes via the Difluorovinylidenation of Aldehydes and Ketones

(2009) Misaki Yokota et al.   ORGANIC LETTERS

Copper-CatalyzedN-Allenylation of Allylic Sulfonamides

(2009) Andreas K. Å. Persson et al.   ORGANIC LETTERS

Configurational Control of Benzyl Carbanion-Copper Complexes by Sulfinyl Groups: Synthesis of Optically Pure Allenes with Central and Axial Chirality

(2008) José Luis García Ruano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Ligand Properties of Stable Five‐Membered‐Ring Allenes Containing Only Second‐Row Elements

(2008) Vincent Lavallo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Efficient Double 1,2-Addition Reaction of 2,3-Allenoates with Allyl Magnesium Chloride

(2008) Bo Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Selective One-Pot Synthesis of Allenyl and Alkynyl Esters from β-Ketoesters

(2008) Pradip Maity et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Regio- and Stereoselective Cyclic Iodoetherification of 4,5-Alkadienols. An Efficient Preparation of 2-(1′(Z)-Iodoalkenyl)tetrahydrofurans

(2008) Bo Lü et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct and Stereospecific Synthesis of Allenes via Reduction of Propargylic Alcohols with Cp2Zr(H)Cl

(2008) Xiaotao Pu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multisubstituted Allenylboronates

(2008) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

New Metal-Free One-Pot Synthesis of Substituted Allenes from Enones

(2008) Meng Tang et al.   ORGANIC LETTERS

Highly Regioselective Synthesis of Trisubstituted Allenes via Lithiation of 1-Aryl-3-alkylpropadiene, Subsequent Transmetalation, and Pd-Catalyzed Negishi Coupling Reaction

(2008) Jinbo Zhao et al.   ORGANIC LETTERS

Silaborations of 1,3-Enynes − Substrate Controlled Allene/1,3-Diene Selectivity

(2008) Christina Moberg   ORGANIC LETTERS