Divergent Synthesis of CF3 -Substituted Allenyl Nitriles by Ligand-Controlled Radical 1,2- and 1,4-Addition to 1,3-Enynes

Asymmetric Cu-Catalyzed Intermolecular Trifluoromethylarylation of Styrenes: Enantioselective Arylation of Benzylic Radicals

(2017) Lianqian Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Copper-Catalyzed Intermolecular Aminoarylation of Styrenes: Efficient Access to Optical 2,2-Diarylethylamines

(2017) Dinghai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Decarboxylative Cyanation Employing Cooperative Photoredox Catalysis and Copper Catalysis

(2017) Dinghai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes: Bond Forming at a High-Valent Palladium Center

(2016) Guoyin Yin et al.   ACCOUNTS OF CHEMICAL RESEARCH

CuI-Catalyzed Synthesis of Propargyl Hydroperoxides Using Molec­ular Oxygen and Hydroxylamines

(2016) Matthew R. Miner et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-BINAP Catalyzed Alcohol C–H tert-Prenylation via 1,3-Enyne Transfer Hydrogenation: Beyond Stoichiometric Carbanions in Enantioselective Carbonyl Propargylation

(2016) Khoa D. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron(II)-Catalyzed Intermolecular Aminofluorination of Unfunctionalized Olefins Using Fluoride Ion

(2016) Deng-Fu Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes via Radical Process

(2016) Fei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective cyanation of benzylic C–H bonds via copper-catalyzed radical relay

(2016) Wen Zhang et al.   SCIENCE

Propargyl Radical Chemistry: Renaissance Instigated by Metal Coordination

(2015) Gagik G. Melikyan   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF3-Substituted Azirines and Aziridines

(2015) Fei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes

(2015) Rong Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mn-Catalyzed Highly Efficient Aerobic Oxidative Hydroxyazidation of Olefins: A Direct Approach to β-Azido Alcohols

(2015) Xiang Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Trifluoromethylazidation and Trifluoromethylthiocyanation of Allenes: Efficient Access to CF3-Containing Allyl Azides and Thiocyanates

(2015) Na Zhu et al.   ORGANIC LETTERS

Copper-Catalyzed Intermolecular Trifluoromethylthiocyanation of Alkenes: Convenient Access to CF3-Containing Alkyl Thiocyanates

(2015) Zhaoli Liang et al.   ORGANIC LETTERS

Copper(I)-Catalyzed Oxidation of Alkenes Using Molecular Oxygen and Hydroxylamines: Synthesis and Reactivity of α-Oxygenated Ketones

(2015) Alexander A. Andia et al.   ORGANIC LETTERS

Copper-Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF3-Containing Alkyl Azides

(2014) Fei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Radical Aminofluorination of Styrenes

(2014) Hongwei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single Electron Transfer in Radical Ion and Radical-Mediated Organic, Materials and Polymer Synthesis

(2014) Na Zhang et al.   CHEMICAL REVIEWS

Vicinal Difunctionalization of Alkenes with Iodine(III) Reagents and Catalysts

(2014) R. Martín Romero et al.   Chemistry-An Asian Journal

Copper-catalyzed intermolecular cyanotrifluoromethylation of alkenes: Convenient synthesis of CF3-containing alkyl nitriles

(2014) Zhaoli Liang et al.   JOURNAL OF FLUORINE CHEMISTRY

Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–Cu Complex

(2014) Fanke Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper- and Cobalt-Catalyzed Direct Coupling of sp3 α-Carbon of Alcohols with Alkenes and Hydroperoxides

(2014) Jun-Kee Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron(II)-Catalyzed Intermolecular Amino-Oxygenation of Olefins through the N–O Bond Cleavage of Functionalized Hydroxylamines

(2014) Deng-Fu Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Trifluoromethylarylation of Alkenes: Mutual Activation of Arylboronic Acid and CF3+ Reagent

(2014) Fei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation

(2014) Nathan D. Schley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper-Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes

(2013) Rong Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed Hydrotrifluoromethylation of Unactivated Alkenes with CF3SiMe3

(2013) Xinyue Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Directing-Group-Assisted Copper-Catalyzed Olefinic Trifluoromethylation of Electron-Deficient Alkenes

(2013) Chao Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethylation Reactions for the Synthesis of β-Trifluoromethylamines

(2013) Hiromichi Egami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-mediated C–H trifluoromethylation of quinones

(2013) Nadia O. Ilchenko et al.   CHEMICAL COMMUNICATIONS

Copper-Mediated Cyanotrifluoromethylation of Styrenes Using the Togni Reagent

(2013) Nadia O. Ilchenko et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Hydrotrifluoromethylation of Unactivated Alkenes

(2013) Satoshi Mizuta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes

(2013) Yu-Tao He et al.   ORGANIC LETTERS

Recent Advances in Transition-Metal-Catalyzed Trifluoromethylation and Related Transformations

(2013) Guosheng Liu et al.   SYNTHESIS-STUTTGART

Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts

(2012) Yusuke Yasu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A “Renaissance” in Radical Trifluoromethylation

(2012) Armido Studer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Trifluoromethylaminoxylation of Alkenes

(2012) Yi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

EPR Investigation of Zinc/Iodine Exchange between Propargyl Iodides and Diethylzinc: Detection of Propargyl Radical by Spin Trapping

(2012) Julien Maury et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Enantioselective Cross-Couplings of Racemic Secondary Electrophiles That Bear an Oxygen Leaving Group

(2012) Alexander J. Oelke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Oxytrifluoromethylation of Unactivated Alkenes

(2012) Rong Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilic Trifluoromethylation by Copper-Catalyzed Addition of CF3-Transfer Reagents to Alkenes and Alkynes

(2012) Pär G. Janson et al.   ORGANIC LETTERS

Copper-catalyzed olefinic trifluoromethylation of enamides at room temperature

(2012) Chao Feng et al.   Chemical Science

Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates

(2011) Yusuke Sasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Mild Oxidative Aryl Radical Addition into Alkenes by Aerobic Oxidation of Arylhydrazines

(2011) Tsuyoshi Taniguchi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Carbolithiation of Conjugated Enynes: A Flow Microreactor Enables the Use of Configurationally Unstable Intermediates before They Epimerize

(2011) Yutaka Tomida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heavier Alkaline Earth Catalysts for the Intermolecular Hydroamination of Vinylarenes, Dienes, and Alkynes

(2011) Christine Brinkmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of β-hydroxyphosphonates by iron-catalyzed oxidative addition of phosphonyl radicals to alkenes

(2011) Tsuyoshi Taniguchi et al.   TETRAHEDRON LETTERS

Iron-Catalyzed Oxidative Addition of Alkoxycarbonyl Radicals to Alkenes with Carbazates and Air

(2010) Tsuyoshi Taniguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst Regeneration in Transition-Metal-Mediated Atom-Transfer Radical Addition (ATRA) and Cyclization (ATRC) Reactions

(2010) Tomislav Pintauer   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Ni-catalyzed regioselective three-component coupling of alkyl halides, arylalkynes, or enynes with R–M (M = MgX′, ZnX′)

(2009) Jun Terao et al.   CHEMICAL COMMUNICATIONS

Nickel-Catalyzed Asymmetric Cross-Couplings of Racemic Propargylic Halides with Arylzinc Reagents

(2008) Sean W. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

(2008) Katrina H. Jensen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY