Switchable Synthesis of α,α‐Dihalomethyl and α,α,α‐Trihalomethyl Ketones by Metal‐Free Decomposition of Enaminone C=C Double Bond

Visible Light-Induced Thiocyanation of Enaminone C-H Bond to Access Polyfunctionalized Alkenes and Thiocyano Chromones

(2019) Yong Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Domino C-H Sulfonylation and Pyrazole Annulation for Fully Substituted Pyrazole Synthesis in Water Using Hydrophilic Enaminones

(2019) Yanhui Guo et al.   JOURNAL OF ORGANIC CHEMISTRY

Transient and Recyclable Halogenation Coupling (TRHC) for Isoflavonoid Synthesis with Site‐Selective Arylation

(2019) Jie‐Ping Wan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Free C=C Double Bond Cleavage on Enaminones for the Synthesis of α-Ketoamides by Free-Radical Aerobic Oxygenation

(2019) Yiming Yang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

C3‐Functionalized Chromones Synthesis by Tandem C−H Elaboration and Chromone Annulation of Enaminones

(2019) Leiqing Fu et al.   Asian Journal of Organic Chemistry

Synthesis of Functionalized α-Vinyl Aldehydes from Enaminones

(2019) Jie Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thermo‐Induced Free‐Radical Cleavage of Enaminone C=C Double Bond for α‐Acyloxyl Ketone Synthesis

(2019) Lihong Tian et al.   Asian Journal of Organic Chemistry

Redox neutral [4+2] benzannulation of dienals and tertiary enaminones for benzaldehyde synthesis

(2018) Lu Yang et al.   CHEMICAL COMMUNICATIONS

Recent Advances in Ring-Opening Functionalization of Cycloalkanols by C-C σ-Bond Cleavage

(2018) Xinxin Wu et al.   CHEMICAL RECORD

Palladium-Catalyzed Intermolecular Oxidative Coupling Reactions of (Z )-Enamines with Isocyanides through Selective β-C(sp2 )-H and/or C=C Bond Cleavage

(2018) Weigao Hu et al.   CHINESE JOURNAL OF CHEMISTRY

Convenient synthesis of quinoline-4-carboxylate derivatives via the Bi(OTf)3-catalyzed domino cyclization/esterification reaction of isatins with enaminones in alcohols

(2018) Pan Zhou et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Highly Site-Selective Metal-Free C–H Acyloxylation of Stable Enamines

(2018) Fei Wang et al.   ORGANIC LETTERS

(Diacetoxyiodo)benzene-mediated Selective Synthesis of α-Azido Ketones or Acyl Azides from β-Keto Acids

(2018) Zhao-Jing Zheng et al.   Asian Journal of Organic Chemistry

Decarboxylative Tribromination for the Selective Synthesis of Tribromomethyl Ketone and Tribromovinyl Derivatives

(2018) Aravindan Jayaraman et al.   ADVANCED SYNTHESIS & CATALYSIS

Alkyl propiolates participated [3+2] annulation for the switchable synthesis of 1,5- and 1,4-disubstituted 1,2,3-triazoles containing ester side chain

(2018) Shuo Cao et al.   ChemCatChem

Direct Synthesis of Methylene-Bridged Bis-biaryl Carboxylates via Cascade Suzuki Coupling and CH2 Cl2 -Based Bis-esterification

(2018) Jin Xiong et al.   ChemistrySelect

Domino Reactions Initiated by Copper‐Catalyzed Aryl‐I Bond Thiolation For the Switchable Synthesis of 2,3‐Dihydrobenzothiazinones and Benzoisothiazolones

(2018) Jin Xiong et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of α-Keto Thioamides by Metal-Free C═C Bond Cleavage in Enaminones Using Elemental Sulfur

(2018) Lu Gan et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Radical 1,4-Difunctionalization of 1,3-Enynes with Alkyl Diacyl Peroxides and N-Fluorobenzenesulfonimide

(2018) Xiaotao Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Water-controlled selective preparation of α-mono or α,α′-dihalo ketones via catalytic cascade reaction of unactivated alkynes with 1,3-dihalo-5,5-dimethylhydantoin

(2017) Chao Wu et al.   GREEN CHEMISTRY

Mn(OAc)3-Promoted Oxidative Csp3–P Bond Formation through Csp2–Csp2 and P–H Bond Cleavage: Access to β-Ketophosphonates

(2017) Pan Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-catalyzed synthesis of benzo[d][1,3]dioxin-4-ones via tandem Ar–halogen bond hydroxylation and dichloromethane-based double Williamson etherification

(2017) Yunyun Liu et al.   NEW JOURNAL OF CHEMISTRY

Copper-catalyzed tandem aryl–halogen hydroxylation and CH2Cl2-based N,O-acetalization toward the synthesis of 2,3-dihydrobenzoxazinones

(2017) Xuwen Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ultrasound-assisted tandem reaction of alkynes and trihaloisocyanuric acids by thiourea as catalyst in water

(2017) Xingyu Zhang et al.   TETRAHEDRON

One-pot syntheses of α,α-dibromoacetophenones from aromatic alkenes with 1,3-dibromo-5,5-dimethylhydantoin

(2017) Ping Wu et al.   TETRAHEDRON LETTERS

Reduction of Trichloromethyl to gem -Dichloromethyl Group with Triphenylphosphine and Water in Ethyl Acetate

(2017) Rafael Díaz-Hernández et al.   ChemistrySelect

Oxidative Coupling of Enamines and DisulfidesviaTetrabutylammonium Iodide/tert-Butyl Hydroperoxide-Mediated Intermolecular Oxidative C(sp2)S Bond Formation Under Transition Metal-Free Conditions

(2016) Jiyun Sun et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-catalyzed, hypervalent iodine mediated CC bond activation of enaminones for the synthesis of α-keto amides

(2016) Jie-Ping Wan et al.   CHEMICAL COMMUNICATIONS

Domino Reactions Based on Combinatorial Bond Transformations in Electron-Deficient Tertiary Enamines

(2016) Jie-Ping Wan et al.   CHEMICAL RECORD

Recent Advances in Transition-Metal-Free Oxygenation of Alkene C=C Double Bonds for Carbonyl Generation

(2016) Jie-Ping Wan et al.   Chemistry-An Asian Journal

Chemoselective Reduction of Trichloromethyl Compounds to gem-Dichloromethyl Groups Following Appel’s Reaction Protocol

(2016) Moises A. Romero-Reyes et al.   JOURNAL OF ORGANIC CHEMISTRY

KIO3-Catalyzed Aerobic Cross-Coupling Reactions of Enaminones and Thiophenols: Synthesis of Polyfunctionalized Alkenes by Metal-Free C–H Sulfenylation

(2016) Jie-Ping Wan et al.   ORGANIC LETTERS

Recent advances in radical-mediated fluorination through C–H and C–C bond cleavage

(2016) Hong Yan et al.   Science China-Chemistry

Visible-Light-Induced CC Bond Cleavage of Enaminones for the Synthesis of 1,2-Diketones and Quinoxalines in Sustainable Medium

(2015) Shuo Cao et al.   ChemCatChem

Synthesis of enaminones and their difluoroboron complexes through domino aryl migration

(2015) Zheng Yang et al.   CHEMICAL COMMUNICATIONS

Synthesis of 2-Keto(hetero)aryl Benzox(thio)azoles through Base Promoted Cyclization of 2-Amino(thio)phenols with α,α-Dihaloketones

(2015) Jun Jiang et al.   JOURNAL OF ORGANIC CHEMISTRY

Intermolecular atom transfer radical addition of α,α,α-trichloromethyl ketones and alkenes mediated by a CuCl/bpy system

(2015) Abulikemu Abudu Rexit et al.   TETRAHEDRON

Expanding the Scope of Alcohol Dehydrogenases towards Bulkier Substrates: Stereo- and Enantiopreference for α,α-Dihalogenated Ketones

(2014) Kinga Kędziora et al.   ChemCatChem

Recent Advances in Transition-Metal-Catalyzed Functionalization of Unstrained Carbon–Carbon Bonds

(2014) Feng Chen et al.   CHEMICAL REVIEWS

A simple, mild, and efficient method for the preparation of α,α-dichloroketones with DCDMH catalyzed by ammonium chloride

(2014) Zubiao Zheng et al.   TETRAHEDRON

Trichloromethyl ketones: asymmetric transfer hydrogenation and subsequent Jocic-type reactions with amines

(2013) Michael S. Perryman et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Cascade Reactions of Isocyanides with Enaminones: Synthesis of 4-Aminoquinoline Derivatives

(2013) Zheng-Yang Gu et al.   ACS Catalysis

Platinum on Carbon-Catalyzed Precise Reduction Control of Trichloromethyl to Geminal-Dichloromethyl Groups

(2012) Takahiro Imanishi et al.   ADVANCED SYNTHESIS & CATALYSIS

Brominated Methanes as Photoresponsive Molecular Storage of Elemental Br2

(2012) Kazumitsu Kawakami et al.   Chemistry-An Asian Journal

Organocatalytic selective benzoylation of alcohols with trichloromethyl phenyl ketone: inverse selectivity in benzoylation of alcohols containing phenol or aromatic amine functionality

(2012) Ram N. Ram et al.   TETRAHEDRON

α,α-Dibromoacetophenones mediated synthesis of some new 7H-7-alkoxy-3-alkyl/phenyl-6-aryl-s-triazolo[3,4-b][1,3,4]thiadiazines and their antimicrobial evaluation

(2011) Rashmi Pundeer et al.   MEDICINAL CHEMISTRY RESEARCH

Selective 1,2-dihalogenation and oxy-1,1-dihalogenation of alkynes by N-halosuccinimides

(2011) Jinhua Liu et al.   TETRAHEDRON LETTERS

Simple and efficient methods for selective preparation of α-mono or α,α-dichloro ketones and β-ketoesters by using DCDMH

(2008) Zizhan Chen et al.   GREEN CHEMISTRY

Homotyrosine-Containing Cyanopeptolins 880 and 960 and Anabaenopeptins 908 and 915 fromPlanktothrix agardhiiCYA 126/8

(2008) Hilary S. Okumura et al.   JOURNAL OF NATURAL PRODUCTS