Journal
CHEMISTRYSELECT
Volume 3, Issue 28, Pages 8291-8293Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201801480
Keywords
Bis-biaryl carboxylates; Esterification; Methylene-bridged; Multicomponent; Suzuki coupling
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Funding
- National Natural Science Foundation of China [21562024]
- Jiangxi Normal University [YJS2017022]
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The multicomponent reactions of iodobenzoic acids, aryl boronic acids, and dichloromethane (DCM) have been designed for the synthesis of various methylene-bridged bis-biaryl functionalized carboxylates. Under the catalysis of Pd(OAc)(2), the formation of the products involves the cascade Suzuki coupling and CH2Cl2-base bis-esterification. The present work offers a direct and practical route to the synthesis of novel carboxylate scaffolds with extended diversity.
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