Recent advances in radical-mediated fluorination through C–H and C–C bond cleavage

Fluorodecarboxylation for the Synthesis of Trifluoromethyl Aryl Ethers

(2016) Qing-Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Uranyl Cation as a Visible-Light Photocatalyst for C(sp3)−H Fluorination

(2016) Julian G. West et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modern Transition-Metal-Catalyzed Carbon–Halogen Bond Formation

(2016) David A. Petrone et al.   CHEMICAL REVIEWS

Aminofluorination of Cyclopropanes: A Multifold Approach through a Common, Catalytically Generated Intermediate

(2016) Cody Ross Pitts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Targeted Fluorination with the Fluoride Ion by Manganese-Catalyzed Decarboxylation

(2015) Xiongyi Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct photocatalytic fluorination of benzylic C–H bonds with N-fluorobenzenesulfonimide

(2015) Matthew B. Nodwell et al.   CHEMICAL COMMUNICATIONS

Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes

(2015) Xinxin Wu et al.   CHEMICAL COMMUNICATIONS

Ring-opening Fluorination of Cyclobutanols and Cyclopropanols Catalyzed by Silver

(2015) Naoki Ishida et al.   CHEMISTRY LETTERS

Site-Selective Approach to β-Fluorination: Photocatalyzed Ring Opening of Cyclopropanols

(2015) Steven Bloom et al.   CHEMISTRY-A EUROPEAN JOURNAL

Radical Decarboxylative Fluorination of Aryloxyacetic Acids UsingN-Fluorobenzenesulfonimide and a Photosensitizer

(2015) Joe C. T. Leung et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Silver-Mediated Decarboxylative Fluorination of Paraconic Acids: A Direct Entry to β-Fluorinated γ-Butyrolactones

(2015) Supasorn Phae-nok et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis

(2015) Sandrine Ventre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Ring-Opening Strategy for the Synthesis of β- and γ-Fluorinated Ketones

(2015) Huijun Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Enabled Stereoselective β-C(sp3)–H Fluorination: Synthesis of Unnatural Enantiopure anti-β-Fluoro-α-amino Acids

(2015) Ru-Yi Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of Chiral β-Fluoro α-Amino Acids via Pd(II)-Catalyzed Fluorination of Unactivated Methylene C(sp3)–H Bonds: Scope and Mechanistic Studies

(2015) Qi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron- or silver-catalyzed oxidative fluorination of cyclopropanols for the synthesis of β-fluoroketones

(2015) Shichao Ren et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed Site-Selective Fluorination of Unactivated C(sp3)–H Bonds

(2015) Jinmin Miao et al.   ORGANIC LETTERS

Development of a Direct Photocatalytic C–H Fluorination for the Preparative Synthesis of Odanacatib

(2015) Shira D. Halperin et al.   ORGANIC LETTERS

Recent Advances in Radical Fluorination

(2015) Jean-François Paquin et al.   SYNTHESIS-STUTTGART

Unstrained C–C bond activation and directed fluorination through photocatalytically-generated radical cations

(2015) Cody Ross Pitts et al.   Chemical Science

Transition-metal free oxidative aliphatic C–H fluorination

(2015) Xiaofei Zhang et al.   Organic Chemistry Frontiers

A Convenient Photocatalytic Fluorination of Unactivated CH Bonds

(2014) Shira D. Halperin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed Oxidative Activation of Benzylic CH Bonds for the Synthesis of Difluoromethylated Arenes

(2014) Peng Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible light-promoted metal-free sp3-C–H fluorination

(2014) Ji-Bao Xia et al.   CHEMICAL COMMUNICATIONS

Selective fluorination of alkyl C–H bonds via photocatalysis

(2014) Choon Wee Kee et al.   CHEMICAL COMMUNICATIONS

A Continuous-Flow Protocol for Light-Induced Benzylic Fluorinations

(2014) David Cantillo et al.   JOURNAL OF ORGANIC CHEMISTRY

Triethylborane-Initiated Radical Chain Fluorination: A Synthetic Method Derived from Mechanistic Insight

(2014) Cody Ross Pitts et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct C–F Bond Formation Using Photoredox Catalysis

(2014) Montserrat Rueda-Becerril et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct, Catalytic Monofluorination of sp3 C–H Bonds: A Radical-Based Mechanism with Ionic Selectivity

(2014) Cody Ross Pitts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Late Stage Benzylic C–H Fluorination with [18F]Fluoride for PET Imaging

(2014) Xiongyi Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalyzed Benzylic Fluorination: Shedding “Light” on the Involvement of Electron Transfer

(2014) Steven Bloom et al.   ORGANIC LETTERS

A photocatalyzed aliphatic fluorination

(2014) Steven Bloom et al.   Chemical Science

Vanadium-catalyzed C(sp3)–H fluorination reactions

(2014) Ji-Bao Xia et al.   Organic Chemistry Frontiers

Catalytic fluorination of unactivated C(sp3)–H bonds

(2014) Jun-An Ma et al.   Organic Chemistry Frontiers

C sp 3F Bond Formation: A Free-Radical Approach

(2013) Mukund P. Sibi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Benzylic Fluorination as a Synthetic Equivalent to 1,4-Conjugate Addition of Fluoride

(2013) Steven Bloom et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible Light-Promoted Metal-Free C–H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination

(2013) Ji-Bao Xia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Fluorination of C(sp3)–H Bonds Using a Catalytic N-Oxyl Radical

(2013) Yuuki Amaoka et al.   ORGANIC LETTERS

Catalytic Decarboxylative Fluorination for the Synthesis of Tri- and Difluoromethyl Arenes

(2013) Satoshi Mizuta et al.   ORGANIC LETTERS

Photo-fluorodecarboxylation of 2-Aryloxy and 2-Aryl Carboxylic Acids

(2012) Joe C. T. Leung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Polycomponent Metal-Catalyzed Aliphatic, Allylic, and Benzylic Fluorination

(2012) Steven Bloom et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine Transfer to Alkyl Radicals

(2012) Montserrat Rueda-Becerril et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution

(2012) Feng Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin

(2012) W. Liu et al.   SCIENCE

Fluoro-silsesquioxane-urethane Hybrid for Thin Film Applications

(2009) Aravindaraj G Kannan et al.   ACS Applied Materials & Interfaces

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS