Synthesis of Chiral Aldehyde Catalysts by Pd-Catalyzed Atroposelective C−H Naphthylation

Enantioselective Synthesis of Atropisomers Featuring Pentatomic Heteroaromatics by Pd-Catalyzed C–H Alkynylation

(2019) Shuo Zhang et al.   ACS Catalysis

Combining Chiral Aldehyde Catalysis and Transition-Metal Catalysis for Enantioselective α-Allylic Alkylation of Amino Acid Esters

(2019) Lei Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Biaryl Atropisomers via Pd-Catalyzed C-H Olefination using Chiral Spiro Phosphoric Acid Ligands

(2019) Jun Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introducing the Chiral Transient Directing Group Strategy to Rhodium(III)‐Catalyzed Asymmetric C−H Activation

(2019) Guozhu Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Construction of Axially Chiral Compounds via Asymmetric Organocatalysis

(2018) Yong-Bin Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Axially Chiral Dibenzazepinones via a Pd(0)-Catalyzed Atropo-enantioselective C-H Arylation

(2018) Nicolai Cramer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Scalable, Stereocontrolled Formal Syntheses of (+)-Isoschizandrin and (+)-Steganone: Development and Applications of Palladium(II)-Catalyzed Atroposelective C−H Alkynylation

(2018) Gang Liao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Two Stereoinduction Events in One C−H Activation Step: A Route towards Terphenyl Ligands with Two Atropisomeric Axes

(2018) Quentin Dherbassy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed enantioselective C(sp2)–H arylation of ferrocenyl ketones enabled by a chiral transient directing group

(2018) Jiancong Xu et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed ortho C−H Arylation of Benzaldehydes Using ortho -Sulfinyl Aniline as Transient Auxiliary

(2018) Delong Mu et al.   Chemistry-An Asian Journal

Total Synthesis of Boletopsin 11 Enabled by Directed ortho-C(sp2)–H Arylation

(2018) Meng Yao Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Aldehyde Catalysis for the Catalytic Asymmetric Activation of Glycine Esters

(2018) Wei Wen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlling Pd(iv) reductive elimination pathways enables Pd(ii)-catalysed enantioselective C(sp3)−H fluorination

(2018) Hojoon Park et al.   Nature Chemistry

Direct Dehydrogenative Arylation of Benzaldehydes with Arenes Using Transient Directing Groups

(2018) Da-Yu Wang et al.   ORGANIC LETTERS

Enantioselective C(sp3)‒H bond activation by chiral transition metal catalysts

(2018) Tyler G. Saint-Denis et al.   SCIENCE

Carbonyl catalysis enables a biomimetic asymmetric Mannich reaction

(2018) Jianfeng Chen et al.   SCIENCE

Catalyst-Controlled Stereoselective Synthesis of Atropisomers

(2018) Bouthayna Zilate et al.   ACS Catalysis

Enantioselective Carbonyl Catalysis Enabled by Chiral Aldehydes

(2018) Shuli You et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to P - and Axially Chiral Biaryl Phosphine Oxides by Enantioselective Cpx IrIII -Catalyzed C−H Arylations

(2018) Yun-Suk Jang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral aldehyde catalysis: a highly promising concept in asymmetric catalysis

(2018) Liu-Zhu Gong   Science China-Chemistry

Aldehyde Catalysis: New Options for Asymmetric Organocatalytic Reactions

(2018) Sun Li et al.   Chem

Pd-Catalyzed Atroposelective C−H Allylation through β-O Elimination: Diverse Synthesis of Axially Chiral Biaryls

(2018) Gang Liao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diverse ortho-C(sp2)–H Functionalization of Benzaldehydes Using Transient Directing Groups

(2017) Xi-Hai Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Ortho C–H Hydroxylation of Benzaldehydes Using a Transient Directing Group

(2017) Xiao-Yang Chen et al.   ORGANIC LETTERS

P(O)R2-Directed Enantioselective C–H Olefination toward Chiral Atropoisomeric Phosphine–Olefin Compounds

(2017) Shi-Xia Li et al.   ORGANIC LETTERS

Enantioselective Synthesis of Indole-Based Biaryl Atropisomers via Palladium-Catalyzed Dynamic Kinetic Intramolecular C–H Cyclization

(2017) Congfa He et al.   ACS Catalysis

Cobalt-Catalyzed Mild Ring-Opening Addition of Arenes C−H Bond to 7-Oxabicyclic Alkenes

(2016) Krishnamoorthy Muralirajan et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C–H activation and ring scission

(2016) Fen Wang et al.   CHEMICAL SOCIETY REVIEWS

Cobalt(III)-Catalyzed C–C Coupling of Arenes with 7-Oxabenzonorbornadiene and 2-Vinyloxirane via C–H Activation

(2016) Lingheng Kong et al.   ORGANIC LETTERS

Functionalization of C(sp3)-H bonds using a transient directing group

(2016) F.-L. Zhang et al.   SCIENCE

Recent advances and new concepts for the synthesis of axially stereoenriched biaryls

(2015) J. Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Kinetic Resolution of Biaryl Compounds

(2015) Gaoyuan Ma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral Pyridoxal-Catalyzed Asymmetric Biomimetic Transamination of α-Keto Acids

(2015) Limin Shi et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Direct Coupling of Arylphosphine Derivatives with Heterobicyclic Alkenes: A Concise Route to Biarylphosphines and Dibenzophosphole Derivatives

(2015) Yuto Unoh et al.   ACS Catalysis

Aldehyde-Assisted Ruthenium(II)-Catalyzed CH Oxygenations

(2014) Fanzhi Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes

(2014) Jun Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Axially Chiral Biaryls through Sulfoxide-Directed Asymmetric Mild CH Activation and Dynamic Kinetic Resolution

(2014) Chinmoy Kumar Hazra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Catalytic asymmetric direct α-alkylation of amino esters by aldehydes via imine activation

(2014) Biao Xu et al.   Chemical Science

Pd(II)-Catalyzed Intermolecular Direct C–H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution

(2014) De-Wei Gao et al.   ACS Catalysis

Rhodium(III)-Catalyzed Coupling of Arenes with 7-Oxa/Azabenzonorbornadienes by CH Activation

(2013) Zisong Qi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric C(sp2)H Activation

(2013) Joanna Wencel-Delord et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent development of direct asymmetric functionalization of inert C–H bonds

(2013) Chao Zheng et al.   RSC Advances

Brønsted-Acid-Catalyzed Asymmetric Multicomponent Reactions for the Facile Synthesis of Highly Enantioenriched Structurally Diverse Nitrogenous Heterocycles

(2011) Jie Yu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Revealing Atropisomer Axial Chirality in Drug Discovery

(2011) Steven R. LaPlante et al.   ChemMedChem

Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

(2010) Gerhard Bringmann et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed Synthesis of Hydroxylated Arenes

(2010) Diego A. Alonso et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dynamic Kinetic Resolution of Biaryl Atropisomers via Peptide-Catalyzed Asymmetric Bromination

(2010) J. L. Gustafson et al.   SCIENCE

The Challenge of Atropisomerism in Drug Discovery

(2009) Jonathan Clayden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

(2009) Marisa C. Kozlowski et al.   CHEMICAL SOCIETY REVIEWS

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

(2009) Ramesh Giri et al.   CHEMICAL SOCIETY REVIEWS