Palladium-Catalyzed Trifluoromethylation of (Hetero)Arenes with CF3 Br

Visible-Light Photoredox-Catalyzed Semipinacol-Type Rearrangement: Trifluoromethylation/Ring Expansion by a Radical-Polar Mechanism

(2015) Basudev Sahoo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterogeneous Platinum-Catalyzed CH Perfluoroalkylation of Arenes and Heteroarenes

(2015) Lin He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Well-Defined CuC2F5Complexes and Pentafluoroethylation of Acid Chlorides

(2015) Liubov I. Panferova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Condensed-Phase, Halogen-Bonded CF3I and C2F5I Adducts for Perfluoroalkylation Reactions

(2015) Filippo Sladojevich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction: Fluorine Chemistry

(2015) Veronique Gouverneur et al.   CHEMICAL REVIEWS

Carbon Trifluoromethylation Reactions of Hydrocarbon Derivatives and Heteroarenes

(2015) Concepción Alonso et al.   CHEMICAL REVIEWS

Transition-Metal-Free Trifluoromethylthiolation of N-Heteroarenes

(2015) Roman Honeker et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Promoted Trifluoromethanesulfonylation and Trifluoromethylation of Arenediazonium Tetrafluoroborates with NaSO2CF3

(2015) Ke Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation

(2015) Jian Zheng et al.   ORGANIC LETTERS

Copper-Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF3-Containing Alkyl Azides

(2014) Fei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Controlled Selectivity in the Synthesis of Linear and Angular Fused Quinazolinones by a Palladium-Catalyzed Carbonylation/Nucleophilic Aromatic Substitution Sequence

(2014) Jianbin Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exceedingly Fast Copper(II)-Promotedortho CH Trifluoromethylation of Arenes using TMSCF3

(2014) Ming Shang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Carbonylations of Aryl Bromides using Paraformaldehyde: Synthesis of Aldehydes and Esters

(2014) Kishore Natte et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethylation of arenediazonium salts with fluoroform-derived CuCF3in aqueous media

(2014) Anton Lishchynskyi et al.   CHEMICAL COMMUNICATIONS

Trifluoromethyltrimethylsilane: Nucleophilic Trifluoromethylation and Beyond

(2014) Xiao Liu et al.   CHEMICAL REVIEWS

Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

(2014) Julie Charpentier et al.   CHEMICAL REVIEWS

Rapid Trifluoromethylation and Perfluoroalkylation of Five-Membered Heterocycles by Photoredox Catalysis in Continuous Flow

(2014) Natan J. W. Straathof et al.   ChemSusChem

Copper-Catalyzed Aminotrifluoromethylation of Unactivated Alkenes with (TMS)CF3: Construction of Trifluoromethylated Azaheterocycles

(2014) Jin-Shun Lin et al.   JOURNAL OF ORGANIC CHEMISTRY

1-Trifluoromethylated isoquinolines via radical trifluoromethylation of isonitriles

(2014) Bo Zhang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Efficient palladium-catalyzed double carbonylation of o-dibromobenzenes: synthesis of thalidomide

(2014) Jianbin Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Efficient Copper-Catalyzed Trifluoromethylation of Aromatic and Heteroaromatic Iodides: The Beneficial Anchoring Effect of Borates

(2014) Zsombor Gonda et al.   ORGANIC LETTERS

Silver-Catalyzed C–H Trifluoromethylation of Arenes Using Trifluoroacetic Acid as the Trifluoromethylating Reagent

(2014) Guangfa Shi et al.   ORGANIC LETTERS

Regioselective trifluoromethylation of N-heteroaromatic compounds using trifluoromethyldifluoroborane activator

(2014) Tomoaki Nishida et al.   Nature Communications

Metal-Free Direct CH Perfluoroalkylation of Arenes and Heteroarenes Using a Photoredox Organocatalyst

(2013) Lei Cui et al.   ADVANCED SYNTHESIS & CATALYSIS

Sandmeyer Trifluoromethylation of Arenediazonium Tetrafluoroborates

(2013) Grégory Danoun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rapid and Efficient Trifluoromethylation of Aromatic and Heteroaromatic Compounds Using Potassium Trifluoroacetate Enabled by a Flow System

(2013) Mao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-catalysed trifluoromethylation of arenes at room temperature

(2013) Sangwon Seo et al.   CHEMICAL COMMUNICATIONS

CuCl-catalyzed ortho trifluoromethylation of arenes and heteroarenes with a pivalamido directing group

(2013) Shangjun Cai et al.   CHEMICAL COMMUNICATIONS

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Trifluoromethylation of heterocycles in water at room temperature

(2013) James C. Fennewald et al.   GREEN CHEMISTRY

Copper-Promoted Sandmeyer Trifluoromethylation Reaction

(2013) Jian-Jun Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluoromethyl Group

(2013) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ortho-Trifluoromethylation of Functionalized Aromatic Triazenes

(2012) Andreas Hafner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed trifluoromethylation of aryl- and vinylboronic acids with generation of CF3-radicals

(2012) Yang Li et al.   CHEMICAL COMMUNICATIONS

Recent Developments on the Trifluoromethylation of (Hetero)Arenes

(2012) Xiao-Feng Wu et al.   Chemistry-An Asian Journal

Pd(II)-Catalyzed Ortho Trifluoromethylation of Arenes and Insights into the Coordination Mode of Acidic Amide Directing Groups

(2012) Xing-Guo Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I

(2012) Yingda Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical Method for the Cu-Mediated Trifluoromethylation of Arylboronic Acids with CF3 Radicals Derived from NaSO2CF3 and tert-Butyl Hydroperoxide (TBHP)

(2012) Yingda Ye et al.   ORGANIC LETTERS

Trifluoromethylation of heterocycles via visible light photoredox catalysis

(2012) Naeem Iqbal et al.   TETRAHEDRON LETTERS

Towards a Practical and Efficient Copper-Catalyzed Trifluoromethylation of Aryl Halides

(2012) Thomas Schareina et al.   TOPICS IN CATALYSIS

Rhenium-Catalyzed Trifluoromethylation of Arenes and Heteroarenes by Hypervalent Iodine Reagents

(2012) Esteban Mejía et al.   ACS Catalysis

Simple, Stable, and Easily Accessible Well-Defined CuCF3 Aromatic Trifluoromethylating Agents

(2011) Olesya A. Tomashenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Broadly Applicable Copper Reagent for Trifluoromethylations and Perfluoroalkylations of Aryl Iodides and Bromides

(2011) Hiroyuki Morimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Mediated Trifluoromethylation of Heteroaromatic Compounds by Trifluoromethyl Sulfonium Salts

(2011) Cheng-Pan Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Oxidative Trifluoromethylation of Indoles at Room Temperature

(2011) Xin Mu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Trifluoromethylation of Aryl Iodides with Potassium (Trifluoromethyl)trimethoxyborate

(2011) Thomas Knauber et al.   CHEMISTRY-A EUROPEAN JOURNAL

Room Temperature Aryl Trifluoromethylation via Copper-Mediated Oxidative Cross-Coupling

(2011) Todd D. Senecal et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature

(2011) Xin Mu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic and Computational Studies of Oxidatively-Induced Aryl−CF3Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation

(2011) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Direct C–H Oxidative Trifluoromethylation of Heteroarenes

(2011) Lingling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis

(2011) David A. Nagib et al.   NATURE

Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent

(2011) Tianfei Liu et al.   ORGANIC LETTERS

Silver-Mediated Trifluoromethylation of Arenes Using TMSCF3

(2011) Yingda Ye et al.   ORGANIC LETTERS

Palladium-Catalyzed C–H Perfluoroalkylation of Arenes

(2011) Rebecca N. Loy et al.   ORGANIC LETTERS

Innate C-H trifluoromethylation of heterocycles

(2011) Y. Ji et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Decarboxylative trifluoromethylation of aryl halides using well-defined copper–trifluoroacetate and –chlorodifluoroacetate precursors

(2010) Kristen A. McReynolds et al.   JOURNAL OF FLUORINE CHEMISTRY

Electrophilic trifluoromethylation of arenes and N-heteroarenes using hypervalent iodine reagents

(2010) Matthias S. Wiehn et al.   JOURNAL OF FLUORINE CHEMISTRY

Pd(II)-Catalyzedortho-Trifluoromethylation of Arenes Using TFA as a Promoter

(2010) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of a Cyclometalated Pd(II) Dimer with “CF3+”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex

(2010) Yingda Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

(2010) E. J. Cho et al.   SCIENCE

Direct C2-trifluoromethylation of indole derivatives catalyzed by copper acetate

(2010) Ryo Shimizu et al.   TETRAHEDRON LETTERS

Aromatic trifluoromethylation catalytic in copper

(2009) Masahiro Oishi et al.   CHEMICAL COMMUNICATIONS

Trifluoromethylation of various aromatic compounds by CF3I in the presence of Fe(II) compound, H2O2 and dimethylsulfoxide

(2009) Tatsuhito Kino et al.   JOURNAL OF FLUORINE CHEMISTRY

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS