Copper-catalyzed trifluoromethylation of aryl- and vinylboronic acids with generation of CF3-radicals

Fluoroform-Derived CuCF3for Low-Cost, Simple, Efficient, and Safe Trifluoromethylation of Aryl Boronic Acids in Air

(2012) Petr Novák et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tamed Arene and Heteroarene Trifluoromethylation

(2012) Tatiana Besset et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ortho-Trifluoromethylation of Functionalized Aromatic Triazenes

(2012) Andreas Hafner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental Sulfur

(2012) Chao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron(II)-Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates

(2012) Andrew T. Parsons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Trifluoromethylation of Arylboronates with Shelf-Stable Potassium (Trifluoromethyl)trimethoxyborate

(2012) Bilal A. Khan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Developments on the Trifluoromethylation of (Hetero)Arenes

(2012) Xiao-Feng Wu et al.   Chemistry-An Asian Journal

Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkynes and Aryl Boronic Acids Using (Trifluoromethyl)trimethylsilane

(2012) Xueliang Jiang et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd(II)-Catalyzed Ortho Trifluoromethylation of Arenes and Insights into the Coordination Mode of Acidic Amide Directing Groups

(2012) Xing-Guo Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature

(2012) Qingqing Qi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3I

(2012) Yingda Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Domino Approach of Heck Coupling for the Synthesis of β-Trifluoromethylstyrenes

(2012) G. K. Surya Prakash et al.   ORGANIC LETTERS

Practical Method for the Cu-Mediated Trifluoromethylation of Arylboronic Acids with CF3 Radicals Derived from NaSO2CF3 and tert-Butyl Hydroperoxide (TBHP)

(2012) Yingda Ye et al.   ORGANIC LETTERS

Towards a Practical and Efficient Copper-Catalyzed Trifluoromethylation of Aryl Halides

(2012) Thomas Schareina et al.   TOPICS IN CATALYSIS

Copper-catalyzed olefinic trifluoromethylation of enamides at room temperature

(2012) Chao Feng et al.   Chemical Science

Copper-Catalyzed Aromatic Trifluoromethylation via Group Transfer from Fluoral Derivatives

(2011) Hideaki Kondo et al.   ADVANCED SYNTHESIS & CATALYSIS

Efficient Trifluoromethylation of Activated and Non-Activated Alkenyl Halides by Using (Trifluoromethyl)trimethylsilane

(2011) Andreas Hafner et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Selective Trifluoromethylation of 1,3-Disubstituted Arenes through Iridium-Catalyzed Arene Borylation

(2011) Tianfei Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuRF]

(2011) Nichole D. Litvinas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simple, Stable, and Easily Accessible Well-Defined CuCF3 Aromatic Trifluoromethylating Agents

(2011) Olesya A. Tomashenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Broadly Applicable Copper Reagent for Trifluoromethylations and Perfluoroalkylations of Aryl Iodides and Bromides

(2011) Hiroyuki Morimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Mediated Trifluoromethylation of Heteroaromatic Compounds by Trifluoromethyl Sulfonium Salts

(2011) Cheng-Pan Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-mediated trifluoromethylation of arylboronic acids by trifluoromethyl sulfonium salts

(2011) Cheng-Pan Zhang et al.   CHEMICAL COMMUNICATIONS

A novel catalytic process for trifluoromethylation of bromoaromatic compounds

(2011) Bhupesh S. Samant et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed trifluoromethylation of aryl boronic acids using a CF3+ reagent

(2011) Jun Xu et al.   CHEMICAL COMMUNICATIONS

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Oxidative Trifluoromethylation of Indoles at Room Temperature

(2011) Xin Mu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Trifluoromethylation of Aryl Iodides with Potassium (Trifluoromethyl)trimethoxyborate

(2011) Thomas Knauber et al.   CHEMISTRY-A EUROPEAN JOURNAL

Room Temperature Aryl Trifluoromethylation via Copper-Mediated Oxidative Cross-Coupling

(2011) Todd D. Senecal et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature

(2011) Xin Mu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic and Computational Studies of Oxidatively-Induced Aryl−CF3Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation

(2011) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Cupration of Fluoroform

(2011) Alessandro Zanardi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Direct C–H Oxidative Trifluoromethylation of Heteroarenes

(2011) Lingling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light Photocatalysis

(2011) Dipannita Kalyani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis

(2011) David A. Nagib et al.   NATURE

Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent

(2011) Tianfei Liu et al.   ORGANIC LETTERS

Silver-Mediated Trifluoromethylation of Arenes Using TMSCF3

(2011) Yingda Ye et al.   ORGANIC LETTERS

Cooperative Effect of Silver in Copper-Catalyzed Trifluoromethylation of Aryl Iodides Using Me3SiCF3

(2011) Zhiqiang Weng et al.   ORGANOMETALLICS

Innate C-H trifluoromethylation of heterocycles

(2011) Y. Ji et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Ligand-Free Copper-Catalyzed Decarboxylative Trifluoromethylation of Aryliodides with Sodium Trifluoroacetate Using Ag2O as a Promoter

(2011) Yaming Li et al.   SYNLETT

Trifluoromethylation of aryl and heteroaryl halides

(2011) Sudipta Roy et al.   TETRAHEDRON

Transition-Metal-Catalyzed Trifluoromethylation of Aryl Halides

(2010) Rylan J. Lundgren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aryl−CF3Bond-Forming Reductive Elimination from Palladium(IV)

(2010) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzedortho-Trifluoromethylation of Arenes Using TFA as a Promoter

(2010) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of a Cyclometalated Pd(II) Dimer with “CF3+”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex

(2010) Yingda Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Oxidative Trifluoromethylation of Boronic Acids

(2010) Lingling Chu et al.   ORGANIC LETTERS

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

(2010) E. J. Cho et al.   SCIENCE

The Organometallic Fluorine Chemistry of Palladium and Rhodium: Studies toward Aromatic Fluorination

(2009) Vladimir V. Grushin   ACCOUNTS OF CHEMICAL RESEARCH

1,4-Bis(alkenyl)-2,5-dipiperidinobenzenes: Minimal Fluorophores Exhibiting Highly Efficient Emission in the Solid State

(2009) Masaki Shimizu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic trifluoromethylation catalytic in copper

(2009) Masahiro Oishi et al.   CHEMICAL COMMUNICATIONS

A Reverse Wittig Coupling with Trifluoroacetaldehyde: A Convenient One-Step Synthesis of Trifluoromethyl Alkenes

(2009) Shainaz Landge et al.   LETTERS IN ORGANIC CHEMISTRY

Palladium-Catalyzed Decarboxylative Arylation of C−H Bonds by Aryl Acylperoxides

(2009) Wing-Yiu Yu et al.   ORGANIC LETTERS

Regio- and stereo-specific preparation of (E)-1-aryl-3,3,3-trifluoro-1-iodo-propenes and their palladium-catalyzed reaction with terminal alkynes

(2008) Xing-Guo Zhang et al.   JOURNAL OF FLUORINE CHEMISTRY

The Many Roles for Fluorine in Medicinal Chemistry

(2008) William K. Hagmann   JOURNAL OF MEDICINAL CHEMISTRY

Active Trifluoromethylating Agents from Well-Defined Copper(I)−CF3Complexes

(2008) Galyna G. Dubinina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorination in Medicinal Chemistry: Methods, Strategies, and Recent Developments

(2008) Kenneth L. Kirk   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Structure of Bis(trifluoromethyl)cuprate and Its Role in Trifluoromethylation Reactions

(2008) Galyna G. Dubinina et al.   ORGANOMETALLICS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS