Synthesis and Reactivity Studies of Amido‐Substituted Germanium(I)/Tin(I) Dimers and Clusters

A stable free tetragermacyclobutadiene incorporating fused-ring bulky EMind groups

(2018) Katsunori Suzuki et al.   CHEMICAL COMMUNICATIONS

Oxidative Addition and Reductive Elimination at Main-Group Element Centers

(2018) Terry Chu et al.   CHEMICAL REVIEWS

Low-valent group 14 element hydride chemistry: towards catalysis

(2018) Terrance J. Hadlington et al.   CHEMICAL SOCIETY REVIEWS

Redox transmetallation approaches to the synthesis of extremely bulky amido-lanthanoid(ii) and -calcium(ii) complexes

(2018) Caspar N. de Bruin-Dickason et al.   DALTON TRANSACTIONS

The Road Travelled: After Main-Group Elements as Transition Metals

(2018) Catherine Weetman et al.   ChemCatChem

Efficient Reduction of Carbon Dioxide to Methanol Equivalents Catalyzed by Two-Coordinate Amido–Germanium(II) and −Tin(II) Hydride Complexes

(2017) Terrance J. Hadlington et al.   ACS Catalysis

Dimeric magnesium(I) β-diketiminates: a new class of quasi-universal reducing agent

(2017) Cameron Jones   Nature Reviews Chemistry

Stabilization of a two-coordinate, acyclic diaminosilylene (ADASi): completion of the series of isolable diaminotetrylenes, :E(NR2)2 (E = group 14 element)

(2016) Terrance J. Hadlington et al.   CHEMICAL COMMUNICATIONS

Amide α,β-Dehydrogenation Using Allyl-Palladium Catalysis and a Hindered Monodentate Anilide

(2016) Yifeng Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Two-coordinate hydrido-germylenes

(2015) Terrance J. Hadlington et al.   CHEMICAL COMMUNICATIONS

Reaction Mechanism of the Symmetry-Forbidden [2+2] Addition of Ethylene and Acetylene to Amido-Substituted Digermynes and Distannynes Ph2NEENPh2, (E=Ge, Sn): A Theoretical Study

(2015) Lili Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactivity of Amido-Digermynes, LGeGeL (L = Bulky Amide), toward Olefins and Related Molecules: Facile Reduction, C–H Activation, and Reversible Cycloaddition of Unsaturated Substrates

(2015) Terrance J. Hadlington et al.   ORGANOMETALLICS

Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes

(2015) Terrance J. Hadlington et al.   Chemical Science

A singly bonded amido-distannyne: H2 activation and isocyanide coordination

(2014) Terrance J. Hadlington et al.   CHEMICAL COMMUNICATIONS

Reaction Mechanisms of Small-Molecule Activation by Amidoditetrylynes R2N–EE–NR2 (E = Si, Ge, Sn)

(2014) Markus Hermann et al.   INORGANIC CHEMISTRY

Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds

(2014) Terrance J. Hadlington et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of H2by a Multiply Bonded Amido-Digermyne: Evidence for the Formation of a Hydrido-Germylene

(2013) Terrance J. Hadlington et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Extremely Bulky Amido and Amidinato Complexes of Boron and Aluminium Halides: Synthesis and Reduction Studies

(2013) Edwin W.Y. Wong et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Zwitterionic Base-Stabilized Digermadistannacyclobutadiene and Tetragermacyclobutadiene

(2013) Hui-Xian Yeong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reaction Pathways for Addition of H2 to Amido-Ditetrylynes R2N–EE–NR2 (E = Si, Ge, Sn). A Theoretical Study

(2013) Markus Hermann et al.   ORGANOMETALLICS

Heavier Main Group Dimetallene Reactivity: Effects of Frontier Orbital Symmetry

(2013) Christine A. Caputo et al.   ORGANOMETALLICS

The Facile Reduction of Carbon Dioxide to Carbon Monoxide with an Amido-Digermyne

(2012) Jiaye Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Generic One-Pot Route to Acyclic Two-Coordinate Silylenes from Silicon(IV) Precursors: Synthesis and Structural Characterization of a Silylsilylene

(2012) Andrey V. Protchenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Contrasting reductions of group 14 metal(ii) chloride complexes: synthesis of a β-diketiminato tin(i) dimer

(2012) Sam L. Choong et al.   CHEMICAL COMMUNICATIONS

Preparation of Stable Low-Oxidation-State Group 14 Element Amidohydrides and Hydride-Mediated Ring-Expansion Chemistry of N-Heterocyclic Carbenes

(2012) S. M. Ibrahim Al-Rafia et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Utilizing Steric Bulk to Stabilize Molybdenum Aminogermylyne and Aminogermylene Complexes

(2012) Jamie Hicks et al.   ORGANOMETALLICS

Interaction of Multiple Bonded and Unsaturated Heavier Main Group Compounds with Hydrogen, Ammonia, Olefins, and Related Molecules

(2011) Philip P. Power   ACCOUNTS OF CHEMICAL RESEARCH

Extremely bulky amido-group 14 element chloride complexes: Potential synthons for low oxidation state main group chemistry

(2011) Jiaye Li et al.   DALTON TRANSACTIONS

Preparation, Characterization, and Theoretical Analysis of Group 14 Element(I) Dimers: A Case Study of Magnesium(I) Compounds as Reducing Agents in Inorganic Synthesis

(2011) Cameron Jones et al.   INORGANIC CHEMISTRY

A Digermyne with a Ge–Ge Single Bond That Activates Dihydrogen in the Solid State

(2011) Jiaye Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemistry of functionalized silylenes

(2011) Sakya S. Sen et al.   Chemical Science

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

Structures and Properties of Metalloid Al and Ga Clusters Open Our Eyes to the Diversity and Complexity of Fundamental Chemical and Physical Processes during Formation and Dissolution of Metals†

(2010) Hansgeorg Schnöckel   CHEMICAL REVIEWS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Substituent effects in ditetrel alkyne analogues: multiple vs. single bonded isomers

(2010) Yang Peng et al.   Chemical Science

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

β-Diketiminate-Stabilized Magnesium(I) Dimers and Magnesium(II) Hydride Complexes: Synthesis, Characterization, Adduct Formation, and Reactivity Studies

(2009) Simon J. Bonyhady et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reversible Reactions of Ethylene with Distannynes Under Ambient Conditions

(2009) Y. Peng et al.   SCIENCE

Persistent Radicals of Trivalent Tin and Lead

(2008) Marco Becker et al.   INORGANIC CHEMISTRY

Synthesis and Reactions of a Stable 1,2-Diaryl-1,2-dibromodisilene: A Precursor for Substituted Disilenes and a 1,2-Diaryldisilyne

(2008) Takahiro Sasamori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry

(2008) Akira Sekiguchi   PURE AND APPLIED CHEMISTRY