Well‐Defined Alkyne Metathesis Catalysts: Developments and Recent Applications

Silica-Supported Molybdenum Alkylidyne N-Heterocyclic Carbene Catalysts: Relevance of Site Isolation to Catalytic Performance

(2018) Philipp M. Hauser et al.   ChemCatChem

Unraveling the Mechanism of 1,3-Diyne Cross-Metathesis Catalyzed by Silanolate-Supported Tungsten Alkylidyne Complexes

(2018) Tobias M. Schnabel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chemistry of Metallacyclobutadienes

(2018) Mingxu Cui et al.   Chemistry-An Asian Journal

Syntheses of Re(V) Alkylidyne Complexes and Ligand Effect on the Reactivity of Re(V) Alkylidyne Complexes toward Alkynes

(2018) Wei Bai et al.   ORGANOMETALLICS

Efficient catalytic alkyne metathesis with a fluoroalkoxy-supported ditungsten(III) complex

(2018) Henrike Ehrhorn et al.   Beilstein Journal of Organic Chemistry

Through-Space Ultrafast Photoinduced Electron Transfer Dynamics of a C70-Encapsulated Bisporphyrin Covalent Organic Polyhedron in a Low-Dielectric Medium

(2017) Michael Ortiz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Termination Reagents for Ring-Opening Alkyne Metathesis Polymerization

(2017) Hyangsoo Jeong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Carbyne Transfer to Ring-Opening Alkyne Metathesis Initiators Gives Access to Telechelic Polymers

(2017) Stephen von Kugelgen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molecular and Silica-Supported Molybdenum Alkyne Metathesis Catalysts: Influence of Electronics and Dynamics on Activity Revealed by Kinetics, Solid-State NMR, and Chemical Shift Analysis

(2017) Deven P. Estes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning the Catalytic Alkyne Metathesis Activity of Molybdenum and Tungsten 2,4,6-Trimethylbenzylidyne Complexes with Fluoroalkoxide Ligands OC(CF3)nMe3–n (n = 0–3)

(2017) Celine Bittner et al.   ORGANOMETALLICS

Poly(aryleneethynylene)s: Properties, Applications and Synthesis Through Alkyne Metathesis

(2017) Michael Ortiz et al.   Topics in Current Chemistry

Designing Sequence Selectivity into a Ring-Opening Metathesis Polymerization Catalyst

(2016) Peter Chen   ACCOUNTS OF CHEMICAL RESEARCH

Organocatalytic, Asymmetric Total Synthesis of (−)-Haliclonin A

(2016) Lian-Dong Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cationic Silica-Supported N-Heterocyclic Carbene Tungsten Oxo Alkylidene Sites: Highly Active and Stable Catalysts for Olefin Metathesis

(2016) Margherita Pucino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkyne Metathesis with Silica-Supported and Molecular Catalysts at Parts-per-Million Loadings

(2016) Deven P. Estes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Constraining an Irregular Peptide Secondary Structure through Ring-Closing Alkyne Metathesis

(2016) Philipp M. Cromm et al.   CHEMBIOCHEM

Surface Organometallic and Coordination Chemistry toward Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities

(2016) Christophe Copéret et al.   CHEMICAL REVIEWS

Highly Active Multidentate Ligand-Based Alkyne Metathesis Catalysts

(2016) Ya Du et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Two-Component Alkyne Metathesis Catalyst System with an Improved Substrate Scope and Functional Group Tolerance: Development and Applications to Natural Product Synthesis

(2016) Sebastian Schaubach et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Cycloparaphenyleneacetylene via Alkyne Metathesis: C70 Complexation and Copper-Free Triple Click Reaction

(2016) Semin Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Initiator Control of Conjugated Polymer Topology in Ring-Opening Alkyne Metathesis Polymerization

(2016) Stephen von Kugelgen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetically Trapped Tetrahedral Cages via Alkyne Metathesis

(2016) Semin Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkyne Metathesis Reactions of Rhenium(V) Carbyne Complexes

(2016) Wei Bai et al.   ORGANOMETALLICS

Hydroxyl-Assisted trans-Reduction of 1,3-Enynes: Application to the Formal Synthesis of (+)-Aspicilin

(2016) Alois Fürstner et al.   SYNTHESIS-STUTTGART

Dynamic covalent synthesis of aryleneethynylene cages through alkyne metathesis: dimer, tetramer, or interlocked complex?

(2016) Qi Wang et al.   Chemical Science

Orthogonal ring-closing alkyne and olefin metathesis for the synthesis of small GTPase-targeting bicyclic peptides

(2016) Philipp M. Cromm et al.   Nature Communications

Solution-Phase Dynamic Assembly of Permanently Interlocked Aryleneethynylene Cages through Alkyne Metathesis

(2015) Qi Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inhibition of Ras Signaling by Blocking Ras-Effector Interactions with Cyclic Peptides

(2015) Punit Upadhyaya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Concise Total Synthesis of Enigmazole A

(2015) Andreas Ahlers et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Poly(aryleneethynylene)s (PAE) as paradigmatic sensor cores

(2015) Uwe H. F. Bunz et al.   CHEMICAL SOCIETY REVIEWS

Total Synthesis, Stereochemical Revision, and Biological Reassessment of Mandelalide A: Chemical Mimicry of Intrafamily Relationships

(2015) Jens Willwacher et al.   CHEMISTRY-A EUROPEAN JOURNAL

Concise Total Synthesis of Ivorenolide B

(2015) Felix Ungeheuer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Selective Molybdenum ONO Pincer Complex Initiates the Living Ring-Opening Metathesis Polymerization of Strained Alkynes with Exceptionally Low Polydispersity Indices

(2015) Donatela E. Bellone et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent developments and applications of the Cadiot–Chodkiewicz reaction

(2015) K. S. Sindhu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Identification of a Grain Beetle Macrolide Pheromone and Its Synthesis by Ring-Closing Metathesis Using a Terminal Alkyne

(2015) Susann Hötling et al.   ORGANIC LETTERS

Mesoporous 2D covalent organic frameworks based on shape-persistent arylene-ethynylene macrocycles

(2015) Haishen Yang et al.   Chemical Science

Isostructural Molecular and Surface Mimics of the Active Sites of the Industrial WO3/SiO2 Metathesis Catalysts

(2015) Victor Mougel et al.   ACS Catalysis

Synthesis of a conjugated porous Co(ii) porphyrinylene–ethynylene framework through alkyne metathesis and its catalytic activity study

(2015) Guolong Lu et al.   Journal of Materials Chemistry A

Dynamic Covalent Chemistry Approaches Toward Macrocycles, Molecular Cages, and Polymers

(2014) Yinghua Jin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Tungsten and Molybdenum 2,4,6-Trimethylbenzylidyne Complexes as Robust Pre-Catalysts for Alkyne Metathesis

(2014) Birte Haberlag et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalysis-Based Total Synthesis of Putative Mandelalide A

(2014) Jens Willwacher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Constraining Cyclic Peptides To Mimic Protein Structure Motifs

(2014) Timothy A. Hill et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Tetrameric Cage withD2hSymmetry through Alkyne Metathesis

(2014) Qi Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Olefin Metathesis Reactions with Fluorinated Substrates, Catalysts, and Solvents

(2014) Santos Fustero et al.   CHEMICAL REVIEWS

Identification and Synthesis of Macrolide Pheromones of the Grain BeetleOryzaephilus Surinamensisand the FrogSpinomantis Aglavei

(2014) Susann Hötling et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cross-Metathesis of Terminal Alkynes

(2014) Rudy Lhermet et al.   CHEMISTRY-A EUROPEAN JOURNAL

Concise Total Syntheses of Amphidinolides C and F

(2014) Gaëlle Valot et al.   CHEMISTRY-A EUROPEAN JOURNAL

Evolution of Catalytic Stereoselective Olefin Metathesis: From Ancillary Transformation to Purveyor of Stereochemical Identity

(2014) Amir H. Hoveyda   JOURNAL OF ORGANIC CHEMISTRY

Gold-Catalyzed Oxidative Cross-Coupling of Terminal Alkynes: Selective Synthesis of Unsymmetrical 1,3-Diynes

(2014) Haihui Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances and applications of Glaser coupling employing greener protocols

(2014) K. S. Sindhu et al.   RSC Advances

Multidentate Triphenolsilane-Based Alkyne Metathesis Catalysts

(2013) Haishen Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Alcohol-Promoted Ring-Opening Alkyne Metathesis Polymerization

(2013) Daniel W. Paley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkyne Metathesis on the Rise

(2013) Alois Fürstner   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of unsymmetrical 1,3-diynes via alkyne cross-metathesis

(2013) Sin Ting Li et al.   CHEMICAL COMMUNICATIONS

Aerobic Copper-Catalyzed Organic Reactions

(2013) Scott E. Allen et al.   CHEMICAL REVIEWS

Porous Poly(aryleneethynylene) Networks through Alkyne Metathesis

(2013) Youlong Zhu et al.   CHEMISTRY OF MATERIALS

Conjugated BODIPY DYEmers by Metathesis Reactions

(2013) Johannes Ahrens et al.   CHEMISTRY-A EUROPEAN JOURNAL

Increasing the Structural Span of Alkyne Metathesis

(2013) Peter Persich et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tungsten alkylidyne complexes with ancillary imidazolin-2-iminato and imidazolidin-2-iminato ligands and their use in catalytic alkyne metathesis

(2013) Sergej Lysenko et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis and structural characterization of the individual diastereoisomers of a cross-stapled alkene-bridged nisin DE-ring mimic

(2013) Jack C. Slootweg et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Solution processable polydiacetylenes (PDAs) through acyclic enediyne metathesis polymerization

(2013) Keda Hu et al.   Chemical Science

Well-defined silica-supported molybdenum nitride species: silica grafting triggers alkyne metathesis activity

(2013) Marie Genelot et al.   Chemical Science

Application of alkyne metathesis in polymer synthesis

(2013) Haishen Yang et al.   Journal of Materials Chemistry A

Getting in Shape: Controlling Peptide Bioactivity and Bioavailability Using Conformational Constraints

(2012) Jonathan E. Bock et al.   ACS Chemical Biology

Highly Active Multidentate Alkyne Metathesis Catalysts: Ligand-Activity Relationship and Their Applications in Efficient Synthesis of Porphyrin-Based Aryleneethynylene Polymers

(2012) Kuthanapillil Jyothish et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Metathesis of Conjugated Diynes

(2012) Sergej Lysenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Metathesis of Terminal Alkynes

(2012) Birte Haberlag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Neurymenolide A Based on a Gold-Catalyzed Synthesis of 4-Hydroxy-2-pyrones

(2012) Wojciech Chaładaj et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A C84 selective porphyrin macrocycle with an adaptable cavity constructed through alkyne metathesis

(2012) Chenxi Zhang et al.   CHEMICAL COMMUNICATIONS

Macrocyclic depolymerization of arylene-ethynylene copolymers: a dynamic combinatorial method

(2012) Dustin E. Gross et al.   CHEMICAL COMMUNICATIONS

Optimized Synthesis, Structural Investigations, Ligand Tuning and Synthetic Evaluation of Silyloxy-Based Alkyne Metathesis Catalysts

(2012) Johannes Heppekausen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unusually stable tungstenacyclobutadienes featuring an ONO trianionic pincer-type ligand

(2012) Matthew E. O'Reilly et al.   DALTON TRANSACTIONS

Biomimetic Total Synthesis of Cruentaren A via Aromatization of Diketodioxinones

(2012) Marianne Fouché et al.   JOURNAL OF ORGANIC CHEMISTRY

Impact of Water Coadsorption for Carbon Dioxide Capture in Microporous Polymer Sorbents

(2012) Robert Dawson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bidentate Phenoxides as Ideal Activating Ligands for Living Ring-Opening Alkyne Metathesis Polymerization

(2012) Danielle F. Sedbrook et al.   MACROMOLECULES

An efficient route to the musk odorant (R,Z)-5-muscenone via base-metal-catalysis

(2012) Konrad Lehr et al.   TETRAHEDRON

Heterogeneous Catalytic Homocoupling of Terminal Alkynes

(2012) Francisco Alonso et al.   ACS Catalysis

Conjugated Macrocycles: Concepts and Applications

(2011) Masahiko Iyoda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introducing A Podand Motif to Alkyne Metathesis Catalyst Design: A Highly Active Multidentate Molybdenum(VI) Catalyst that Resists Alkyne Polymerization

(2011) Kuthanapillil Jyothish et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Towards Highly Active and Robust Alkyne Metathesis Catalysts: Recent Developments in Catalyst Design

(2011) Kuthanapillil Jyothish et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in the development of alkyne metathesis catalysts

(2011) Xian Wu et al.   Beilstein Journal of Organic Chemistry

Total synthesis of (−)-nakadomarin A

(2011) Andrew F. Kyle et al.   CHEMICAL COMMUNICATIONS

Phosphoraneiminato tungsten alkylidyne complexes as highly efficient alkyne metathesis catalysts

(2011) Xian Wu et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Catalytic alkyne metathesis and stoichiometric metal–alkylidyne formation from NMo(OR)3 complexes promoted by Lewis acids

(2011) Andrea M. Geyer et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Improved Ruthenium Catalysts for Z-Selective Olefin Metathesis

(2011) Benjamin K. Keitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis-Based and Protecting-Group-Free Total Syntheses of the Marine Oxylipins Hybridalactone and the Ecklonialactones A, B, and C

(2011) Volker Hickmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly C70Selective Shape-Persistent Rectangular Prism Constructed through One-Step Alkyne Metathesis

(2011) Chenxi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Arylene–Ethynylene Macrocycles via Depolymerization–Macrocyclization

(2011) Dustin E. Gross et al.   MACROMOLECULES

Synthesis of macrocyclic natural products by catalyst-controlled stereoselective ring-closing metathesis

(2011) Miao Yu et al.   NATURE

Catalytic Z-selective olefin cross-metathesis for natural product synthesis

(2011) Simon J. Meek et al.   NATURE

Total synthesis of (−)-nakadomarin A: alkyne ring-closing metathesis

(2011) Pavol Jakubec et al.   TETRAHEDRON LETTERS

Total Synthesis of (±)-Haliclonacyclamine C

(2010) Brian J. Smith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design of Living Ring-Opening Alkyne Metathesis

(2010) Felix R. Fischer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Catalytic Alkyne Metathesis with a Tri(tert-butoxy)silanolate-Supported Tungsten Benzylidyne Complex

(2010) Sergej Lysenko et al.   ChemCatChem

The Fritsch–Buttenberg–Wiechell rearrangement: modern applications for an old reaction

(2010) Eike Jahnke et al.   CHEMICAL COMMUNICATIONS

Lewis acid activation of molybdenum nitrides for alkyne metathesis

(2010) Aaron D. Finke et al.   CHEMICAL COMMUNICATIONS

Arylethynyl receptors for neutral molecules and anions: emerging applications in cellular imaging

(2010) Calden N. Carroll et al.   CHEMICAL SOCIETY REVIEWS

Chromatic polydiacetylene with novel sensitivity

(2010) Xuemei Sun et al.   CHEMICAL SOCIETY REVIEWS

Preparation of Imidazolin-2-iminato Molybdenum and Tungsten Benzylidyne Complexes: A New Pathway to Highly Active Alkyne Metathesis Catalysts

(2010) Birte Haberlag et al.   CHEMISTRY-A EUROPEAN JOURNAL

Practical New Silyloxy-Based Alkyne Metathesis Catalysts with Optimized Activity and Selectivity Profiles

(2010) Johannes Heppekausen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of (−)-Nakadomarin A

(2010) Mark G. Nilson et al.   ORGANIC LETTERS

Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area

(2009) Teng Ben et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acetylenic Polymers: Syntheses, Structures, and Functions

(2009) Jianzhao Liu et al.   CHEMICAL REVIEWS

Ruthenium-Based Olefin Metathesis Catalysts BearingN-Heterocyclic Carbene Ligands

(2009) Cezary Samojłowicz et al.   CHEMICAL REVIEWS

Preparation, Modification, and Evaluation of Cruentaren A and Analogues

(2009) Martin Bindl et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molybdenum Nitride Complexes with Ph3SiO Ligands Are Exceedingly Practical and Tolerant Precatalysts for Alkyne Metathesis and Efficient Nitrogen Transfer Agents

(2009) Martin Bindl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Poly(aryleneethynylene)s

(2009) Uwe H. F. Bunz   MACROMOLECULAR RAPID COMMUNICATIONS

Nickel-Catalyzed Oxidative Coupling Reactions of Two Different Terminal Alkynes Using O2as the Oxidant at Room Temperature: Facile Syntheses of Unsymmetric 1,3-Diynes

(2009) Weiyan Yin et al.   ORGANIC LETTERS

Experimental and Theoretical Investigations of Catalytic Alkyne Cross-Metathesis with Imidazolin-2-iminato Tungsten Alkylidyne Complexes

(2009) Stephan Beer et al.   ORGANOMETALLICS

Synthesis of novel glycophanes derived from glucuronic acid by ring closing alkene and alkyne metathesis

(2008) Dearbhla Doyle et al.   CARBOHYDRATE RESEARCH

Total synthesis of polyyne natural products

(2008) Benjamin W. Gung   COMPTES RENDUS CHIMIE

Synthetic Applications with Use of a Silica-Supported Alkyne Metathesis Catalyst

(2008) Hyeon Mo Cho et al.   JOURNAL OF ORGANIC CHEMISTRY

Development of a well-defined silica-supported tungstenocarbyne complex as efficient heterogeneous catalyst for alkyne metathesis

(2008) Nicolas Merle et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthetic, Mechanistic, and Computational Investigations of Nitrile-Alkyne Cross-Metathesis

(2008) Andrea M. Geyer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of Cyclophanes by Room-Temperature Ring-Closing Alkyne Metathesis with Imidazolin-2-iminato Tungsten Alkylidyne Complexes

(2008) Stephan Beer et al.   ORGANIC LETTERS

Excitons in a perfect quasi-1D organic quantum wire, an isolated polydiacetylene chain

(2008) Laurent Legrand et al.   PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS

(4E,8Z)-12-Methyloxacyclotetradeca-4,8-dien-2-one and Its 7a-Homologue: Conformationally Constrained Double-Unsaturated Macrocyclic Musks by Ring-Closing Alkyne Metathesis

(2008) Philip Kraft et al.   SYNTHESIS-STUTTGART