Alkyne Metathesis on the Rise

Highly Active Multidentate Alkyne Metathesis Catalysts: Ligand-Activity Relationship and Their Applications in Efficient Synthesis of Porphyrin-Based Aryleneethynylene Polymers

(2012) Kuthanapillil Jyothish et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Metathesis of Conjugated Diynes

(2012) Sergej Lysenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Metathesis of Terminal Alkynes

(2012) Birte Haberlag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Functional-Group-Tolerant Catalytictrans Hydrogenation of Alkynes

(2012) Karin Radkowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Neurymenolide A Based on a Gold-Catalyzed Synthesis of 4-Hydroxy-2-pyrones

(2012) Wojciech Chaładaj et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent Total Synthesis of the Antimitotic Agent Leiodermatolide

(2012) Jens Willwacher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Macrocyclic depolymerization of arylene-ethynylene copolymers: a dynamic combinatorial method

(2012) Dustin E. Gross et al.   CHEMICAL COMMUNICATIONS

Suzuki reactions of extended scope: the ‘9-MeO-9-BBN variant’ as a complementary format for cross-coupling

(2012) Günter Seidel et al.   CHEMICAL COMMUNICATIONS

Optimized Synthesis, Structural Investigations, Ligand Tuning and Synthetic Evaluation of Silyloxy-Based Alkyne Metathesis Catalysts

(2012) Johannes Heppekausen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Biomimetic Total Synthesis of Cruentaren A via Aromatization of Diketodioxinones

(2012) Marianne Fouché et al.   JOURNAL OF ORGANIC CHEMISTRY

An OCO3– Trianionic Pincer Tungsten(VI) Alkylidyne: Rational Design of a Highly Active Alkyne Polymerization Catalyst

(2012) Soumya Sarkar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,3-Metal–Carbon Bonding and Alkyne Metathesis: DFT Investigations on Model Complexes of Group 4, 5, and 6 Transition Metals

(2012) Cherumuttathu H. Suresh et al.   ORGANOMETALLICS

An efficient route to the musk odorant (R,Z)-5-muscenone via base-metal-catalysis

(2012) Konrad Lehr et al.   TETRAHEDRON

Introducing A Podand Motif to Alkyne Metathesis Catalyst Design: A Highly Active Multidentate Molybdenum(VI) Catalyst that Resists Alkyne Polymerization

(2011) Kuthanapillil Jyothish et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Second-Generation Total Synthesis of Spirastrellolide F Methyl Ester: The Alkyne Route

(2011) Stefan Benson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rendering Schrock-type Molybdenum Alkylidene Complexes Air Stable: User-Friendly Precatalysts for Alkene Metathesis

(2011) Johannes Heppekausen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Tulearin C

(2011) Konrad Lehr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in the development of alkyne metathesis catalysts

(2011) Xian Wu et al.   Beilstein Journal of Organic Chemistry

Ene–yne cross-metathesis with ruthenium carbene catalysts

(2011) Cédric Fischmeister et al.   Beilstein Journal of Organic Chemistry

Metathesis in total synthesis

(2011) Alois Fürstner   CHEMICAL COMMUNICATIONS

Total synthesis of (−)-nakadomarin A

(2011) Andrew F. Kyle et al.   CHEMICAL COMMUNICATIONS

Role of Siloxides in Transition Metal Chemistry and Homogeneous Catalysis

(2011) Clemens Krempner   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis of Molybdenum Nitrido Complexes for Triple-Bond Metathesis of Alkynes and Nitriles

(2011) Eric S. Wiedner et al.   INORGANIC CHEMISTRY

Strategy Evolution in the Total Synthesis of Spirastrellolide A Methyl Ester

(2011) Ian Paterson et al.   ISRAEL JOURNAL OF CHEMISTRY

From Total Synthesis to Diverted Total Synthesis: Case Studies in the Amphidinolide Series

(2011) Alois Fürstner   ISRAEL JOURNAL OF CHEMISTRY

Phosphoraneiminato tungsten alkylidyne complexes as highly efficient alkyne metathesis catalysts

(2011) Xian Wu et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Catalytic alkyne metathesis and stoichiometric metal–alkylidyne formation from NMo(OR)3 complexes promoted by Lewis acids

(2011) Andrea M. Geyer et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Improved Ruthenium Catalysts for Z-Selective Olefin Metathesis

(2011) Benjamin K. Keitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Engineering Solid-State Morphologies in Carbazole–Ethynylene Macrocycles

(2011) Aaron D. Finke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis ofE,Z-Configured 1,3-Dienes by Ring-Closing Metathesis. Application to the Total Synthesis of Lactimidomycin

(2011) Daniel Gallenkamp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis-Based and Protecting-Group-Free Total Syntheses of the Marine Oxylipins Hybridalactone and the Ecklonialactones A, B, and C

(2011) Volker Hickmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Arylene–Ethynylene Macrocycles via Depolymerization–Macrocyclization

(2011) Dustin E. Gross et al.   MACROMOLECULES

Synthesis of macrocyclic natural products by catalyst-controlled stereoselective ring-closing metathesis

(2011) Miao Yu et al.   NATURE

Catalytic Z-selective olefin cross-metathesis for natural product synthesis

(2011) Simon J. Meek et al.   NATURE

Total synthesis of (−)-nakadomarin A: alkyne ring-closing metathesis

(2011) Pavol Jakubec et al.   TETRAHEDRON LETTERS

Total Synthesis of (±)-Haliclonacyclamine C

(2010) Brian J. Smith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the Reach of Chemical Synthesis: Creation of a Mini-Pipeline from an Academic Laboratory

(2010) Rebecca M. Wilson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design of Living Ring-Opening Alkyne Metathesis

(2010) Felix R. Fischer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Probing the Biology of Natural Products: Molecular Editing by Diverted Total Synthesis

(2010) Alex M. Szpilman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Catalytic Alkyne Metathesis with a Tri(tert-butoxy)silanolate-Supported Tungsten Benzylidyne Complex

(2010) Sergej Lysenko et al.   ChemCatChem

Lewis acid activation of molybdenum nitrides for alkyne metathesis

(2010) Aaron D. Finke et al.   CHEMICAL COMMUNICATIONS

Preparation of Imidazolin-2-iminato Molybdenum and Tungsten Benzylidyne Complexes: A New Pathway to Highly Active Alkyne Metathesis Catalysts

(2010) Birte Haberlag et al.   CHEMISTRY-A EUROPEAN JOURNAL

Concise Total Synthesis of the Potent Translation and Cell Migration Inhibitor Lactimidomycin

(2010) Kevin Micoine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical New Silyloxy-Based Alkyne Metathesis Catalysts with Optimized Activity and Selectivity Profiles

(2010) Johannes Heppekausen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Protecting-Group-Free and Catalysis-Based Total Synthesis of the Ecklonialactones

(2010) Volker Hickmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of (−)-Nakadomarin A

(2010) Mark G. Nilson et al.   ORGANIC LETTERS

Direct 1−3 Metal−Carbon Bonding and Planar Tetracoordinated Carbon in Group 6 Metallacyclobutadienes†

(2010) Cherumuttathu H. Suresh et al.   ORGANOMETALLICS

Total Synthesis of Spirastrellolide F Methyl Ester—Part 1: Strategic Considerations and Revised Approach to the Southern Hemisphere

(2009) Gregory W. O'Neil et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Spirastrellolide F Methyl Ester—Part 2: Macrocyclization and Completion of the Synthesis

(2009) Stefan Benson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold and platinum catalysis—a convenient tool for generating molecular complexity

(2009) Alois Fürstner   CHEMICAL SOCIETY REVIEWS

Preparation, Modification, and Evaluation of Cruentaren A and Analogues

(2009) Martin Bindl et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Synthesis and Biological Evaluation of Amphidinolide V and Analogues

(2009) Alois Fürstner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molybdenum Nitride Complexes with Ph3SiO Ligands Are Exceedingly Practical and Tolerant Precatalysts for Alkyne Metathesis and Efficient Nitrogen Transfer Agents

(2009) Martin Bindl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Versatile Route to the Tulearin Class of Macrolactones: Synthesis of a Stereoisomer of Tulearin A

(2009) Alexander L. Mandel et al.   ORGANIC LETTERS

Experimental and Theoretical Investigations of Catalytic Alkyne Cross-Metathesis with Imidazolin-2-iminato Tungsten Alkylidyne Complexes

(2009) Stephan Beer et al.   ORGANOMETALLICS

Synthesis of novel glycophanes derived from glucuronic acid by ring closing alkene and alkyne metathesis

(2008) Dearbhla Doyle et al.   CARBOHYDRATE RESEARCH

Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective

(2008) Eloísa Jiménez-Núñez et al.   CHEMICAL REVIEWS

Synthesis and Biological Evaluation of Cruentaren A Analogues

(2008) Viktor V. Vintonyak et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mo-Catalyzed Cross-Metathesis Reaction of Propynylferrocene

(2008) Tomáš Bobula et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Room-Temperature Alkyne-Nitrile Metathesis and Unambiguous Proof for the Existence of a High-Valent Iron-Nitrido Dication in the Gas Phase. Short Communication

(2008) John P. Boyd et al.   HELVETICA CHIMICA ACTA

Synthetic Applications with Use of a Silica-Supported Alkyne Metathesis Catalyst

(2008) Hyeon Mo Cho et al.   JOURNAL OF ORGANIC CHEMISTRY

Development of a well-defined silica-supported tungstenocarbyne complex as efficient heterogeneous catalyst for alkyne metathesis

(2008) Nicolas Merle et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthetic, Mechanistic, and Computational Investigations of Nitrile-Alkyne Cross-Metathesis

(2008) Andrea M. Geyer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions of Strained Hydrocarbons with Alkene and Alkyne Metathesis Catalysts

(2008) Matthew Carnes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of Cyclophanes by Room-Temperature Ring-Closing Alkyne Metathesis with Imidazolin-2-iminato Tungsten Alkylidyne Complexes

(2008) Stephan Beer et al.   ORGANIC LETTERS

Synthesis of Macrocycle Isomers via Metathesis Cyclization and Their Self-Assembly from Aqueous Solutions

(2008) Jing Jiang et al.   ORGANIC LETTERS

(4E,8Z)-12-Methyloxacyclotetradeca-4,8-dien-2-one and Its 7a-Homologue: Conformationally Constrained Double-Unsaturated Macrocyclic Musks by Ring-Closing Alkyne Metathesis

(2008) Philip Kraft et al.   SYNTHESIS-STUTTGART