Organometallic intermediate-based organic synthesis: organo-di-lithio reagents and beyond

Dual Gold Catalysis

(2014) A. Stephen K. Hashmi   ACCOUNTS OF CHEMICAL RESEARCH

Magnesiacyclopentadienes as Alkaline-Earth Metallacyclopentadienes: Facile Synthesis, Structural Characterization, and Synthetic Application

(2014) Junnian Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron Cyclopentadienone Complexes: Discovery, Properties, and Catalytic Reactivity

(2014) Adrien Quintard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

All-Carbon Quaternary Stereogenic Centers in Acyclic Systems through the Creation of Several C–C Bonds per Chemical Step

(2014) Ilan Marek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and applications of 1-iodo-4-MgCl-1,3-dienes and 1-iodovinyl phenylmagnesium chlorides

(2014) Junnian Wei et al.   Organic Chemistry Frontiers

Synthesis of semibullvalene derivatives via Co2(CO)8-mediated cyclodimerization of 1,4-dilithio-1,3-butadienes

(2014) Shaoguang Zhang et al.   Organic Chemistry Frontiers

Pyridine-Directed Palladium-Catalyzed Phosphonation of C(sp2)H Bonds

(2013) Changkun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Barium Dibenzopentalenide as a Main-Group Metal η8Complex: Facile Synthesis from 1,4-Dilithio-1,3-butadienes and Ba[N(SiMe3)2]2, Structural Characterization, and Reaction Chemistry

(2013) Heng Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkaline Earth Metallocenes Coordinated with Ester Pendants: Synthesis, Structural Characterization, and Application in Metathesis Reactions

(2013) Heng Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Asymmetric Intramolecular α-Arylation of Amides: Reaction Development and Mechanistic Studies

(2013) Dmitry Katayev et al.   CHEMISTRY-A EUROPEAN JOURNAL

Generation and reactivity of o-carborynes

(2013) Zaozao Qiu et al.   DALTON TRANSACTIONS

Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation

(2013) M. Alexander Düfert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Detailed Study of Acetate-Assisted C–H Activation at Palladium(IV) Centers

(2013) Ansis Maleckis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolable and Well-Defined Butadienyl Organocopper(I) Aggregates: Facile Synthesis, Structural Characterization, and Reaction Chemistry

(2013) Weizhi Geng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Polymerization of Epoxides Using Biaryl-Linked Bimetallic Cobalt Catalysts: A Mechanistic Study

(2013) Syud M. Ahmed et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Insights into the Gold(I)-Catalyzed Activation of Glycosyl ortho-Alkynylbenzoates for Glycosidation

(2013) Yu Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined Experimental and Theoretical Study on the Reductive Cleavage of Inert C–O Bonds with Silanes: Ruling out a Classical Ni(0)/Ni(II) Catalytic Couple and Evidence for Ni(I) Intermediates

(2013) Josep Cornella et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spiroketal-Based Diphosphine Ligands in Pd-Catalyzed Asymmetric Allylic Amination of Morita–Baylis–Hillman Adducts: Exceptionally High Efficiency and New Mechanism

(2013) Xiaoming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(II)-Catalyzed Direct Carboxylation of Alkenyl C–H Bonds with CO2

(2013) Kota Sasano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of Octaalkyl-Substituted and Decasubstituted all-cis-Octatetraenes via Linear Dimerization of 1,4-Dicopper-1,3-butadienes and Subsequent Cross-Coupling with Halides

(2013) Junnian Wei et al.   ORGANIC LETTERS

3-D Brick-Wall Polymeric Structure of TMEDA-Supported 1,4-Dilithio-1,3-Butadiene

(2013) Shaoguang Zhang et al.   ORGANOMETALLICS

A Remarkable Switch from a Diamination to a Hydrohydrazination Catalyst and Observation of an Unprecedented Catalyst Resting State

(2012) Andrew D. Schwarz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective CH Alkylation of Anisoles with Olefins Catalyzed by Cationic Half-Sandwich Rare Earth Alkyl Complexes

(2012) Juzo Oyamada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Allylic Alkylation Reaction with N-Aryl Phosphoramidite Ligands: Scope and Mechanistic Studies

(2012) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding Reactivity and Stereoselectivity in Palladium-Catalyzed Diastereoselective sp3 C–H Bond Activation: Intermediate Characterization and Computational Studies

(2012) Ramesh Giri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryl Methyl Sulfides as Substrates for Rhodium-Catalyzed Alkyne Carbothiolation: Arene Functionalization with Activating Group Recycling

(2012) Joel F. Hooper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,3-Butadienylzinc Trimer Formed via Transmetalation from 1,4-Dilithio-1,3-butadienes: Synthesis, Structural Characterization, and Application in Negishi Cross-Coupling

(2012) Yi Zhou et al.   ORGANOMETALLICS

Introduction to the Ennobling a Base Metal: Presenting Copper in Organometallic Chemistry Issue

(2012) Gerard van Koten et al.   ORGANOMETALLICS

Mechanistic understanding of Rh-catalyzed N-sulfonylaldimine insertion into aryl C–H bonds

(2012) Yang Li et al.   Chemical Science

Recent advances in the chemistry of heterometallacycles of group 4 metallocenes

(2012) Torsten Beweries et al.   Catalysis Science & Technology

Zirconocene and Si-Tethered Diynes: A Happy Match Directed toward Organometallic Chemistry and Organic Synthesis

(2011) Wen-Xiong Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct Palladium-Catalyzed Intermolecular Allylation of Highly Electron-Deficient Polyfluoroarenes

(2011) Shilu Fan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iterative Dianion Relay Along the Ring: Formation of gem-Bis(trimethylsilyl) Cyclopentenones from 2,5-Bis(trimethylsilyl) Oxy-cyclopentadienyl Dianions and Acid Chlorides

(2011) Heng Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Intermolecular Directed C−H Amidation of Aromatic Ketones

(2011) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,4-Dilithio-1,3-dienes: Reaction and Synthetic Applications

(2010) Zhenfeng Xi   ACCOUNTS OF CHEMICAL RESEARCH

Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution

(2010) John F. Hartwig et al.   ACCOUNTS OF CHEMICAL RESEARCH

Isolation of Catalytic Intermediates in Hydroamination Reactions: Insertion of Internal Alkynes into a Zirconium-Amido Bond

(2010) David C. Leitch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Half-Sandwich Rare Earth Metal Complexes as Novel Catalysts for Olefin Polymerization and Other Chemical Transformations

(2010) Masayoshi Nishiura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

1,4-Diiodo-1,3-dienes: Versatile Reagents in Organic Synthesis

(2010) Valentine P. Ananikov et al.   Chemistry-An Asian Journal

C−H vs C−C Bond Activation of Acetonitrile and Benzonitrile via Oxidative Addition: Rhodium vs Nickel and Cp* vs Tp′ (Tp′ = Hydrotris(3,5-dimethylpyrazol-1-yl)borate, Cp* = η5-Pentamethylcyclopentadienyl)

(2010) Meagan E. Evans et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls

(2010) Masayoshi Nishiura et al.   Nature Chemistry

Isolation, Structural Characterization, and Synthetic Application of Oxycyclopentadienyl Dianions

(2009) Lantao Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts†

(2009) Georgios C. Vougioukalakis et al.   CHEMICAL REVIEWS

C−H Bond Activation and Organometallic Intermediates on Isolated Metal Centers on Oxide Surfaces

(2009) Christophe Coperet   CHEMICAL REVIEWS

Scandium-Catalyzed Regio- and Stereospecific Methylalumination of Silyloxy/Alkoxy-Substituted Alkynes and Alkenes

(2009) Masanori Takimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Applications of 1-Alkenyl-1,1-Heterobimetallics in the Stereoselective Synthesis of Cyclopropylboronate Esters, Trisubstituted Cyclopropanols and 2,3-Disubstituted Cyclobutanones

(2009) Mahmud M. Hussain et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cleavage of C−N Bonds in Aniline Derivatives on a Ruthenium Center and Its Relevance to Catalytic C−C Bond Formation

(2009) Tetsuro Koreeda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Palladium Catalysis: Direct Observation of Pd(III)−Pd(III) Intermediates

(2009) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation and X-ray Structure of a Trimeric 1,4-Dilithio-1,3-butadiene and a Dimeric Me3Si-Substituted 1,4-Dilithio-1,3-butadiene

(2009) Lantao Liu et al.   ORGANOMETALLICS

CuCl-mediated tandem CO insertion and annulation of 1,4-dilithio-1,3-dienes: formation of multiply substituted cyclopentadienones and/or their head-to-head dimers

(2008) Qian Luo et al.   CHEMICAL COMMUNICATIONS

Introduction: Coinage Metals in Organic Synthesis

(2008) Bruce H. Lipshutz et al.   CHEMICAL REVIEWS

α-Substituted α-Lithiated Oxiranes: Useful Reactive Intermediates

(2008) Vito Capriati et al.   CHEMICAL REVIEWS

Diverse Reactions of 1,4-Dilithio-1,3-dienes with Nitriles: Facile Access to Tricyclic Δ1-Bipyrrolines, Multiply Substituted Pyridines, Siloles, and (Z,Z)-Dienylsilanes by Tuning of Substituents on the Butadienyl Skeleton

(2008) Nan Yu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkyl and Aryl Derivatives of the Alkali Metals: Strong Bases and Reactive Nucleophiles. 2. Wilhelm Schlenk’s Organoalkali-Metal Chemistry. The Metal Displacement and the Transmetalation Reactions. Metalation of Weakly Acidic Hydrocarbons. Superbases

(2008) Dietmar Seyferth   ORGANOMETALLICS