Half-Sandwich Rare Earth Metal Complexes as Novel Catalysts for Olefin Polymerization and Other Chemical Transformations

Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls

(2010) Masayoshi Nishiura et al.   Nature Chemistry

Reduction of Transition-Metal-Coordinated Carbon Monoxide by a Rare-Earth Hydride Cluster: Isolation of Well-Defined Heteromultimetallic Oxycarbene, Oxymethyl, Carbene, and Methyl Complexes

(2009) Yasumasa Takenaka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Scandium-Catalyzed Regio- and Stereospecific Methylalumination of Silyloxy/Alkoxy-Substituted Alkynes and Alkenes

(2009) Masanori Takimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alternating and Random Copolymerization of Isoprene and Ethylene Catalyzed by Cationic Half-Sandwich Scandium Alkyls

(2009) Xiaofang Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rare Earth/d-Transition Metal Heteromultimetallic Polyhydride Complexes Based on Half-Sandwich Rare Earth Moieties

(2009) Takanori Shima et al.   ORGANOMETALLICS

Rare-Earth-Metal/Platinum Heterobinuclear Complexes Containing Reactive Ln-alkyl groups (Ln = Y, Lu): Synthesis, Structural Characterization, and Reactivity

(2009) Yumiko Nakajima et al.   ORGANOMETALLICS

Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes

(2008) Wen-Xiong Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isoprene Polymerization with Yttrium Amidinate Catalysts: Switching the Regio- and Stereoselectivity by Addition of AlMe3

(2008) Lixin Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and styrene polymerisation catalysis of η5- and η1-pyrrolyl-ligated cationic rare earth metal aminobenzyl complexes

(2008) Masayoshi Nishiura et al.   CHEMICAL COMMUNICATIONS

Activation and Dehydrogenative Silylation of the C–H Bonds of Phosphine-coordinated Ruthenium in Lu/Ru Heteromultimetallic Hydride Complexes

(2008) Takanori Shima et al.   CHEMISTRY LETTERS

Cationic Scandium Allyl Complexes Bearing Mono(cyclopentadienyl) Ligands: Synthesis, Novel Structural Variety, and Olefin-Polymerization Catalysis

(2008) Nan Yu et al.   Chemistry-An Asian Journal

Neutron Diffraction Studies on a 4-Coordinate Hydrogen Atom in an Yttrium Cluster

(2008) Muhammed Yousufuddin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scandium-Catalyzed Syndiospecific Copolymerization of Styrene with Isoprene

(2008) Hao Zhang et al.   MACROMOLECULES

Catalytic addition of alkyne C–H, amine N–H, and phosphine P–H bonds to carbodiimides: an efficient route to propiolamidines, guanidines, and phosphaguanidines

(2008) Wen-Xiong Zhang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

1,2-Azaborolyl-Ligated Half-Sandwich Complexes of Scandium(III) and Lutetium(III): Synthesis, Structures, and Syndiotactic Polymerization of Styrene†

(2008) Xiangdong Fang et al.   ORGANOMETALLICS