A Remarkable Switch from a Diamination to a Hydrohydrazination Catalyst and Observation of an Unprecedented Catalyst Resting State

Stitching together SNx units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite

(2012) Thorsten Gehrmann et al.   CHEMICAL COMMUNICATIONS

Alternative Reaction Pathways in Domino Reactions of Hydrazinediidozirconium Complexes with Alkynes

(2012) Thorsten Gehrmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Site selectivity and reversibility in the reactions of titanium hydrazides with Si–H, Si–X, C–X and H+ reagents: TiNα 1,2-silane addition, Nβ alkylation, Nα protonation and σ-bond metathesis

(2012) Pei Jen Tiong et al.   DALTON TRANSACTIONS

A Highly Enantioselective Zirconium Catalyst for Intramolecular Alkene Hydroamination: Significant Isotope Effects on Rate and Stereoselectivity

(2011) Kuntal Manna et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Titanium alkoxyimido (TiN–OR) complexes: reductive N–O bond cleavage at the boundary between hydrazide and peroxide ligands

(2011) Andrew D. Schwarz et al.   CHEMICAL COMMUNICATIONS

Single-step synthesis of pyrazoles using titanium catalysis

(2011) Amila A. Dissanayake et al.   CHEMICAL COMMUNICATIONS

Titaniumtert-Butoxyimido Compounds

(2011) Andrew D. Schwarz et al.   INORGANIC CHEMISTRY

Mechanistic Elucidation of Intramolecular Aminoalkene Hydroamination Catalyzed by a Tethered Bis(ureate) Complex: Evidence for Proton-Assisted C–N Bond Formation at Zirconium

(2011) David C. Leitch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of Catalytic Intermediates in Hydroamination Reactions: Insertion of Internal Alkynes into a Zirconium-Amido Bond

(2010) David C. Leitch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction Site Diversity in the Reactions of Titanium Hydrazides with Organic Nitriles, Isonitriles and Isocyanates: TiNα Cycloaddition, TiNα Insertion and NαNβ Bond Cleavage

(2010) A. Daniel Schofield et al.   CHEMISTRY-A EUROPEAN JOURNAL

M═NαCycloaddition and Nα−NβInsertion in the Reactions of Titanium Hydrazido Compounds with Alkynes: A Combined Experimental and Computational Study

(2010) A. Daniel Schofield et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Catalytic Cyclohydroamination by Zirconium Salicyloxazoline Complexes

(2010) Laura E. N. Allan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Assembly of an R3N52−Chain by Cycloaddition of a Hydrazinediide and an Azide at Zirconium and its Thermal Fragmentation

(2009) Thorsten Gehrmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single and double substrate insertion into the TiNαbonds of terminal titanium hydrazides

(2009) Pei-Jen Tiong et al.   CHEMICAL COMMUNICATIONS

Titanium Hydrazinediido Half-Sandwich Complexes: Highly Active Catalysts for the Hydrohydrazination of Terminal Alkynes at Ambient Temperature

(2009) Katharina Weitershaus et al.   ORGANOMETALLICS

Early Transition-Metal Hydrazido Complexes: Masked Metallanitrenes from NN Bond Scission

(2008) Daniel J. Mindiola   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroamination: Direct Addition of Amines to Alkenes and Alkynes

(2008) Thomas E. Müller et al.   CHEMICAL REVIEWS

Mechanism of the Intramolecular Hydroamination of Alkenes Catalyzed by Neutral Indenyltitanium Complexes: A DFT Study

(2008) Carsten Müller et al.   CHEMISTRY-A EUROPEAN JOURNAL

Is an MN σ-Bond Insertion Route a Viable Alternative to the MN [2+2] Cycloaddition Route in Intramolecular Aminoallene Hydroamination/Cyclisation Catalysed by Neutral Zirconium Bis(amido) Complexes? A Computational Mechanistic Study

(2008) Sven Tobisch   CHEMISTRY-A EUROPEAN JOURNAL

Group-4 Dipyrrolylmethane Complexes in Intramolecular Olefin Hydroamination

(2008) Supriyo Majumder et al.   ORGANOMETALLICS

Titanium-Catalyzed Hydrohydrazination with Monosubstituted Hydrazines: Catalyst Design, Synthesis, and Reactivity

(2008) Sanjukta Banerjee et al.   ORGANOMETALLICS

Titanium Hydrazides Supported by Diamide-Amine and Related Ligands: A Combined Experimental and DFT Study

(2008) Jonathan D. Selby et al.   ORGANOMETALLICS