Journal
APPLIED CATALYSIS A-GENERAL
Volume 404, Issue 1-2, Pages 87-92Publisher
ELSEVIER
DOI: 10.1016/j.apcata.2011.07.016
Keywords
Formamides; Carbonylation; Amines; Hydrogen carbonate; Ionic liquids
Categories
Funding
- Carbon Dioxide Reduction & Sequestration Research Center [AC3-101]
- Ministry of Science and Technology of Korean government
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1-Butyl-3-methylimidazolium hydrogen carbonate ([BMIm][HCO3]), prepared from the reaction of [BMIm]Cl with K2CO3 in methanol, exhibits high activity for the carbonylation of amines to produce formamides. Computational calculation results on the carbonylation reaction of methylamine implies that such high activity of [BMIm][HCO3] could be ascribed to the bi-functional actions of [HCO3](-) as a hydrogen atom acceptor and a donor. (C) 2011 Elsevier B.V. All rights reserved.
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