Cobalt mediated C–H bond functionalization: emerging tools for organic synthesis

Cobalt-Catalyzed Intramolecular Olefin Hydroarylation Leading to Dihydropyrroloindoles and Tetrahydropyridoindoles

(2013) Zhenhua Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cationic High-Valent Cp*CoIIIComplex for the Catalytic Generation of Nucleophilic Organometallic Species: Directed CH Bond Activation

(2013) Tatsuhiko Yoshino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed C4-Selective Direct Alkylation of Pyridines

(2013) Takashi Andou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mixed AggregAte (MAA): A Single Concept for All Dipolar Organometallic Aggregates. 1. Structural Data

(2013) Anne Harrison-Marchand et al.   CHEMICAL REVIEWS

Bimetallic Combinations for Dehalogenative Metalation Involving Organic Compounds

(2013) David Tilly et al.   CHEMICAL REVIEWS

Mixed AggregAte (MAA): A Single Concept for All Dipolar Organometallic Aggregates. 2. Syntheses and Reactivities of Homo/HeteroMAAs

(2013) Florence Mongin et al.   CHEMICAL REVIEWS

Computed CH Acidity of Biaryl Compounds and Their Deprotonative Metalation by Using a Mixed Lithium/Zinc-TMP Base

(2013) Raghu Ram Kadiyala et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed Hydrosilation/Hydrogen-Transfer Cascade Reaction: A New Route to Silyl Enol Ethers

(2013) Thomas W. Lyons et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed CH Bond Functionalizations with Aryl and Alkyl Chlorides

(2013) Benudhar Punji et al.   CHEMISTRY-A EUROPEAN JOURNAL

An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry

(2013) Robert E. Mulvey   DALTON TRANSACTIONS

Cobalt induced CH bond activation and C8-arylation of caffeine with aryl bromides

(2013) Tingting Zheng et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Cobalt-Catalyzed Ortho Alkylation of Aromatic Imines with Primary and Secondary Alkyl Halides

(2013) Ke Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-catalyzed ortho-alkenylation of aromatic aldimines via chelation-assisted C–H bond activation

(2013) Takeshi Yamakawa et al.   TETRAHEDRON

Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization

(2012) Sharon R. Neufeldt et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt-Catalyzed Direct Arylation and Benzylation by CH/CO Cleavage with Sulfamates, Carbamates, and Phosphates

(2012) Weifeng Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aldimine-Directed Branched-Selective Hydroarylation of Styrenes

(2012) Pin-Sheng Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Addition of Arylzinc Reagents to Alkynes to Form ortho-Alkenylarylzinc Species through 1,4-Cobalt Migration

(2012) Boon-Hong Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild and Efficient C2-Alkenylation of Indoles with Alkynes Catalyzed by a Cobalt Complex

(2012) Zhenhua Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C2-Alkylation ofN-pyrimidylindole with vinylsilane via cobalt-catalyzed C–H bond activation

(2012) Zhenhua Ding et al.   Beilstein Journal of Organic Chemistry

Cobalt-catalyzed arylation of aldimines via directed C–H bond functionalization: addition of 2-arylpyridines and self-coupling of aromatic aldimines

(2012) Ke Gao et al.   CHEMICAL COMMUNICATIONS

Direct Arylation of Benzene with Aryl Bromides using High-Temperature/High-Pressure Process Windows: Expanding the Scope of CH Activation Chemistry

(2012) Bartholomäus Pieber et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrothermal synthesis of an ortho-metallated Co(iii) complex anchored by a carboxylate group with a selective oxidation catalytic property

(2012) Shi-Yuan Zhang et al.   DALTON TRANSACTIONS

Enantioselective Metalation ofN,N-Diisopropylferrocenecarboxamide and Methyl Ferrocenecarboxylate Using Lithium-Metal Chiral Bases

(2012) Gandrath Dayaker et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Recent Progress in Nickel-Catalyzed Biaryl Coupling

(2012) Junichiro Yamaguchi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Activation of C–H Bond in 1,1′-Ferrocene Derived Schiff Base by Cobalt(I) Complex Supported by Trimethylphosphine. X-ray Crystal Structure of η2[N,C]-(1-N-naphthyl ferrocenylideneamine) tris(trimethylphosphine) cobalt(I)

(2012) Qibao Wang et al.   JOURNAL OF CHEMICAL CRYSTALLOGRAPHY

Co(porphyrin)-catalysed amination of 1,2-dihydronaphthalene derivatives by aryl azides

(2012) Paolo Zardi et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Stereoselective Radical Amination of Electron-Deficient C(sp3)–H Bonds by Co(II)-Based Metalloradical Catalysis: Direct Synthesis of α-Amino Acid Derivatives via α-C–H Amination

(2012) Hongjian Lu et al.   ORGANIC LETTERS

Cobalt-Catalyzed Ortho-Arylation of Aromatic Imines with Aryl Chlorides

(2012) Ke Gao et al.   ORGANIC LETTERS

Annulation of α,β-Unsaturated Imines and Alkynes via Cobalt-Catalyzed Olefinic C–H Activation

(2012) Takeshi Yamakawa et al.   ORGANIC LETTERS

(Chiral) lithium–(magnesium–)zinc and lithium–cobalt combinations as dual reagents for aromatic deproto-metalation and aryl transfer to aldehydes

(2012) David Tilly et al.   TETRAHEDRON

Catalytic C–H arylation of unactivated heteroaromatics with aryl halides by cobalt porphyrin

(2012) Ying Ying Qian et al.   TETRAHEDRON LETTERS

Co2(CO)8-mediated cycloisomerization of arylene 1,7-enynes

(2012) Ping Xing et al.   TETRAHEDRON LETTERS

Opening the black box of mixed-metal TMP metallating reagents: direct cadmation or lithium–cadmium transmetallation?

(2012) David R. Armstrong et al.   Chemical Science

Synthesis of both enantiomers of ferrocene[1,2-c]1H-quinolin-2-one by diastereoselective deproto-zincation of sugar-derived ferrocene esters

(2012) Aare Sreeshailam et al.   RSC Advances

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt-Phenanthroline Catalysts for the ortho Alkylation of Aromatic Imines under Mild Reaction Conditions

(2011) Ke Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

“LiZn(TMP)3”, a Zincate or a Turbo-Lithium Amide Reagent? DOSY NMR Spectroscopic Evidence

(2011) Pablo García-Álvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel- and Cobalt-Catalyzed Direct Alkylation of Azoles with N-Tosylhydrazones Bearing Unactivated Alkyl Groups

(2011) Tomoyuki Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Direct Addition of Aryl CH Bonds to N-Sulfonyl Aldimines

(2011) Yang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron oxide mediated direct C–H arylation/alkylation at α-position of cyclic aliphatic ethers

(2011) Parvinder Pal Singh et al.   CHEMICAL COMMUNICATIONS

Development of more labile low electron count Co(i) sources: mild, catalytic functionalization of activated alkanes using a [(Cp*Co)2-μ-(η4:η4-arene)] complex

(2011) Fernando Hung-Low et al.   CHEMICAL COMMUNICATIONS

Hydroarylation of alkynes catalyzed by nickel

(2011) Yoshiaki Nakao   CHEMICAL RECORD

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

The Catalytic Ability of Various Transition Metals in the Direct Functionalization of Aromatic CH Bonds

(2011) Hu Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed Direct Arylation of Unactivated Arenes with Aryl Halides

(2011) Wei Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electronic Effects of Ligands on the Cobalt(II)-Porphyrin-Catalyzed Direct C-H Arylation of Benzene

(2011) Tek Long Chan et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Diastereoselective Deprotonative Metalation of Sugar-Derived Ferrocene Esters Using Mixed Lithium-Cadmium Combinations

(2011) Aare Sreeshailam et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Functionalization of (Un)protected Tetrahydroisoquinoline and Isochroman under Iron and Copper Catalysis: Two Metals, Two Mechanisms

(2011) Michael Ghobrial et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis and properties of novel ortho-metalated cobalt(I) and iron(II) complexes through Csp2–H bond activation of dibenzylphenylphosphine

(2011) Nazhen Liu et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Chemoselective Insertion of Alkene into the Ortho C−H Bond of Benzamide

(2011) Laurean Ilies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Arylation of Boc-Imines via C−H Bond Functionalization

(2011) Andy S. Tsai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed, Room-Temperature Addition of Aromatic Imines to Alkynes via Directed C–H Bond Activation

(2011) Pin-Sheng Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Coupling of Alkyl Grignard Reagent with Benzamide and 2-Phenylpyridine Derivatives through Directed C–H Bond Activation under Air

(2011) Quan Chen et al.   ORGANIC LETTERS

Cobalt-Catalyzed, Chelation-Assisted C-H Bond Functionalization

(2011) Naohiko Yoshikai   SYNLETT

Cobalt-catalyzed benzylic C–H amination via dehydrogenative-coupling reaction

(2011) Yang-Hong Ye et al.   TETRAHEDRON

Chemoselective intramolecular allylic C–H amination versus CC aziridination through Co(ii)-based metalloradical catalysis

(2011) Hongjian Lu et al.   Chemical Science

Cobalt- and Manganese-Catalyzed Direct Amination of Azoles under Mild Reaction Conditions and the Mechanistic Details

(2010) Ji Young Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Cross-Coupling of CH Bonds with Grignard Reagents through Cobalt Catalysis

(2010) Bin Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Intramolecular CH Amination through the Metalloradical Activation of Azides: Synthesis of 1,3-Diamines under Neutral and Nonoxidative Conditions

(2010) Hongjian Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation

(2010) Chang-Liang Sun et al.   CHEMICAL COMMUNICATIONS

Deprotonative metallation of ferrocenes using mixed lithium–zinc and lithium–cadmium combinations

(2010) Gandrath Dayaker et al.   CHEMICAL COMMUNICATIONS

Cobalt-Catalyzed Cross-Coupling Reactions

(2010) Gérard Cahiez et al.   CHEMICAL REVIEWS

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed Cross-Coupling Reactions of Aryl Halides

(2010) Corinne Gosmini et al.   ISRAEL JOURNAL OF CHEMISTRY

Low-Valent Iron-Catalyzed C−C Bond Formation−Addition, Substitution, and C−H Bond Activation

(2010) Eiichi Nakamura et al.   JOURNAL OF ORGANIC CHEMISTRY

Effect of anchoring group and valent of cobalt center on the competitive cleavage of C–F or C–H bond activation

(2010) Tingting Zheng et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

A Direct Intramolecular C−H Amination Reaction Cocatalyzed by Copper(II) and Iron(III) as Part of an Efficient Route for the Synthesis of Pyrido[1,2-a]benzimidazoles fromN-Aryl-2-aminopyridines

(2010) Honggen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Hydroarylation of Alkynes through Chelation-Assisted C−H Bond Activation

(2010) Ke Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed C−C Bond Formation at α-Position of Aliphatic Amines via C−H Bond Activation through 1,5-Hydrogen Transfer

(2010) Naohiko Yoshikai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Intermolecular Hydroarylation of Alkynes

(2010) Derek J. Schipper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselectivity-Switchable Hydroarylation of Styrenes

(2010) Ke Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzedortho-Alkylation of Secondary Benzamide with Alkyl Chloride through Directed C−H Bond Activation

(2010) Quan Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Addition of Azoles to Alkynes

(2010) Zhenhua Ding et al.   ORGANIC LETTERS

Cobalt(II)-Catalyzed Intramolecular C−H Amination with Phosphoryl Azides: Formation of 6- and 7-Membered Cyclophosphoramidates

(2010) Hongjian Lu et al.   ORGANIC LETTERS

Nickel, Manganese, Cobalt, and Iron-Catalyzed Deprotonative Arene Dimerization

(2010) Thanh Truong et al.   ORGANIC LETTERS

Deprotonative metalation of substituted aromatics using mixed lithium–cobalt combinations

(2010) Gandrath Dayaker et al.   TETRAHEDRON

C–H arylation of unactivated arenes with aryl halides catalyzed by cobalt porphyrin

(2010) Ching Tat To et al.   TETRAHEDRON LETTERS

Iron-Catalyzed Chemoselective ortho Arylation of Aryl Imines by Directed CH Bond Activation

(2009) Naohiko Yoshikai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Direct C Arylation of Heterocycles with Aryl Bromides: Discovery of Fluorescent Core Frameworks

(2009) Dongbing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Direct Alkenylation ofN-Iminopyridinium Ylides

(2009) James J. Mousseau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Hydroformylation of Alkenes: Generation and Recycling of the Carbonyl Species, and Catalytic Cycle

(2009) Frédéric Hebrard et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends

(2009) Martin Albrecht   CHEMICAL REVIEWS

Recent advances in aryl–aryl bond formation by direct arylation

(2009) Gerard P. McGlacken et al.   CHEMICAL SOCIETY REVIEWS

Cobalt-Catalyzed Formation of Symmetrical Biaryls and Its Mechanism

(2009) Aurélien Moncomble et al.   CHEMISTRY-A EUROPEAN JOURNAL

Construction of Nitrogen-Containing Heterocycles by CH Bond Functionalization

(2009) Praew Thansandote et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt Induced Tandem C−H Activation/Decarbonylation of Various Aromatic Aldehydes and Related Benzylic Alcohols Forming Mononuclear Aryl Monocarbonyl Complexes

(2009) Robert Beck et al.   INORGANIC CHEMISTRY

Cobalt(II)-Catalyzed Intermolecular Benzylic C−H Amination with 2,2,2-Trichloroethoxycarbonyl Azide (TrocN3)

(2009) Hongjian Lu et al.   ORGANOMETALLICS

Regioselectiveortho-Metallation of 2-Diphenylphosphanylpyridine and (2-(2-Diphenylphosphanyl)phenyl)-1-3-dioxalane with Methyltetrakis(trimethylphosphane)cobalt(I)

(2009) Robert Beck et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation

(2008) Jared C. Lewis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Iron-Mediated Direct Arylation of Unactivated Arenes

(2008) Jun Wen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Cobalt-Catalyzed Formation of Unsymmetrical Biaryl Compounds and Its Application in the Synthesis of a Sartan Intermediate

(2008) Muriel Amatore et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-catalyzed cross-coupling reactions

(2008) Corinne Gosmini et al.   CHEMICAL COMMUNICATIONS

First regioselective cyclometalation reactions of cobalt in arylketones: C–H versus C–F activation

(2008) Sebnem Camadanli et al.   DALTON TRANSACTIONS

Four- and five-membered cobaltacycles by regioselective cyclometallation of benzyl sulfide derivatives via Co(v) intermediates

(2008) Robert Beck et al.   DALTON TRANSACTIONS

Allylic Amination and Aziridination of Olefins by Aryl Azides Catalyzed by CoII(tpp): A Synthetic and Mechanistic Study

(2008) Alessandro Caselli et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cyclometalation of Thiobenzophenones with Mononuclear Methyliron and ‐cobalt Complexes

(2008) Robert Beck et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A General Method for Copper-Catalyzed Arylation of Arene C−H Bonds

(2008) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation, Structure, and Reactivity of Nonstabilized Organoiron Compounds. Implications for Iron-Catalyzed Cross Coupling Reactions

(2008) Alois Fürstner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Assisted Carbon−Hydrogen Bond Activation by Cobalt(I) Complexes

(2008) Aichen Wang et al.   ORGANOMETALLICS