Chemoselective intramolecular allylic C–H amination versus CC aziridination through Co(ii)-based metalloradical catalysis

The radical mechanism of cobalt(ii) porphyrin-catalyzed olefin aziridination and the importance of cooperative H-bonding

(2011) Alma I. Olivos Suarez et al.   DALTON TRANSACTIONS

Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

(2011) Volodymyr Lyaskovskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation

(2011) Hongjian Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allene Functionalization via Bicyclic Methylene Aziridines

(2011) Luke A. Boralsky et al.   ORGANIC LETTERS

Characterization of Tunable Radical Metal–Carbenes: Key Intermediates in Catalytic Cyclopropanation

(2011) Jonathan L. Belof et al.   ORGANOMETALLICS

Mechanism of Cobalt-Porphyrin–Catalyzed Aziridination

(2011) Kathrin H. Hopmann et al.   ACS Catalysis

Modular Synthesis of 1,2-Diamine Derivatives by Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides

(2010) Richard I. McDonald et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Intramolecular CH Amination through the Metalloradical Activation of Azides: Synthesis of 1,3-Diamines under Neutral and Nonoxidative Conditions

(2010) Hongjian Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[Fe(F20TPP)Cl] catalyzed intramolecular C–N bond formation for alkaloid synthesis using aryl azides as nitrogen source

(2010) Yungen Liu et al.   CHEMICAL COMMUNICATIONS

[FeIII(F20-tpp)Cl] Is an Effective Catalyst for Nitrene Transfer Reactions and Amination of Saturated Hydrocarbons with Sulfonyl and Aryl Azides as Nitrogen Source under Thermal and Microwave-Assisted Conditions

(2010) Yungen Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Studies in catalytic C–H amination involving nitrene C–H insertion

(2010) Florence Collet et al.   DALTON TRANSACTIONS

Evolution of copper(II) as a new alkene amination promoter and catalyst

(2010) Sherry R. Chemler   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Ruthenium porphyrins-catalyzed atom-efficient amination of C-H bonds by arylazides

(2010) Daniela Intrieri et al.   JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation

(2010) Wojciech I. Dzik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope and Mechanism of Allylic C−H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)2Catalyst System: Insights into the Effect of Naphthoquinone

(2010) Guoyin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in transition metal-catalyzed N-atom transfer reactions of azides

(2010) Tom G. Driver   ORGANIC & BIOMOLECULAR CHEMISTRY

Cobalt(II)-Catalyzed Intramolecular C−H Amination with Phosphoryl Azides: Formation of 6- and 7-Membered Cyclophosphoramidates

(2010) Hongjian Lu et al.   ORGANIC LETTERS

Complementary Regioselectivity in the Cu(I)-Catalyzed Diamination of Conjugated Dienes To Form Cyclic Sulfamides

(2010) Richard G. Cornwall et al.   ORGANIC LETTERS

Synthesis of 1,3-Diamines Through Rhodium-Catalyzed CH Insertion

(2009) Toshiki Kurokawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic C–H amination: recent progress and future directions

(2009) Florence Collet et al.   CHEMICAL COMMUNICATIONS

The key intermediate in the amination of saturated C–H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)2 (Ar = 3,5-(CF3)2C6H3)

(2009) Simone Fantauzzi et al.   CHEMICAL COMMUNICATIONS

The role of sulfamide derivatives in medicinal chemistry: a patent review (2006 – 2008)

(2009) Allen B Reitz et al.   EXPERT OPINION ON THERAPEUTIC PATENTS

Examination of the Mechanism of Rh2(II)-Catalyzed Carbazole Formation Using Intramolecular Competition Experiments

(2009) Benjamin J. Stokes et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh2(II)-Catalyzed Synthesis of Carbazoles from Biaryl Azides

(2009) Benjamin J. Stokes et al.   JOURNAL OF ORGANIC CHEMISTRY

Intramolecular Ir(I)-Catalyzed Benzylic C−H Bond Amination ofortho-Substituted Aryl Azides

(2009) Ke Sun et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Intramolecular Amination Reactions of Aryl- and Vinylazides

(2009) Wang Ge Shou et al.   ORGANOMETALLICS

Cobalt(II)-Catalyzed Intermolecular Benzylic C−H Amination with 2,2,2-Trichloroethoxycarbonyl Azide (TrocN3)

(2009) Hongjian Lu et al.   ORGANOMETALLICS

Enantioselective CH Amination Using Cationic Ruthenium(II)-pybox Catalysts

(2008) Erika Milczek et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Intermolecular Aerobic Oxidative Amination of Terminal Alkenes: Efficient Synthesis of Linear Allylamine Derivatives

(2008) Guosheng Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Nitrene Complexes in Catalytic CH Amination

(2008) Yosra M. Badiei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dirhodium(II)-Catalyzed Intramolecular CH Amination of Aryl Azides

(2008) Meihua Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Allylic Amination and Aziridination of Olefins by Aryl Azides Catalyzed by CoII(tpp): A Synthetic and Mechanistic Study

(2008) Alessandro Caselli et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Catalytic C−H Amination for the Preparation of Substituted 1,2-Diamines

(2008) David E. Olson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Intermolecular Linear Allylic C−H Amination via Heterobimetallic Catalysis

(2008) Sean A. Reed et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Chiral Rhodium Carboxamidate Catalyst for Enantioselective C−H Amination

(2008) David N. Zalatan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Allylic and Homoallylic Diamination of Terminal Olefins via Formal C−H Activation

(2008) Haifeng Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Iron(II) Bromide-Catalyzed Synthesis of Benzimidazoles from Aryl Azides

(2008) Meihua Shen et al.   ORGANIC LETTERS

A Highly Effective Cobalt Catalyst for Olefin Aziridination with Azides: Hydrogen Bonding Guided Catalyst Design

(2008) Joshua V. Ruppel et al.   ORGANIC LETTERS

A mechanistic analysis of the Rh-catalyzed intramolecular C–H amination reaction

(2008) Kristin Williams Fiori et al.   TETRAHEDRON

Toward a Synthetically Useful Stereoselective C−H Amination of Hydrocarbons

(2007) Chungen Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY