An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry

Dizincation of a 2-Substituted Thiophene: Constructing a Cage with a [16]Crown-4 Zincocyclic Core

(2012) Liam Balloch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Higher-Order Zincates as Transmetalators in Alkyl-Alkyl Negishi Cross-Coupling

(2012) Lucas C. McCann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective heterohalogenation of 4-halo-anisoles via a series of sequential ortho-aluminations and electrophilic halogenations

(2012) Ben Conway et al.   CHEMICAL COMMUNICATIONS

Ambient temperature zincation of N-Boc pyrrolidine and its solvent dependency

(2012) Jennifer A. Garden et al.   CHEMICAL COMMUNICATIONS

Molecular early main group metal hydrides: synthetic challenge, structures and applications

(2012) Sjoerd Harder   CHEMICAL COMMUNICATIONS

A new polymeric alkyl/alkoxide magnesium–sodium inverse crown complex

(2011) Sharon E. Baillie et al.   ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS

A μ4-oxide-containing a dimeric variant of a sodium dialkyl(amido)zincate reagent

(2011) Liam Balloch et al.   ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS

“LiZn(TMP)3”, a Zincate or a Turbo-Lithium Amide Reagent? DOSY NMR Spectroscopic Evidence

(2011) Pablo García-Álvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Record-Breaking Magnesium Hydride Molecular Cluster: Implications for Hydrogen Storage

(2011) Eva Hevia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Chemoselective Metalation of Arenes and Heteroarenes Using Hindered Metal Amide Bases

(2011) Benjamin Haag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen Storage in Magnesium Hydride: The Molecular Approach

(2011) Sjoerd Harder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Meta-metallation ofN,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation

(2011) David R Armstrong et al.   Beilstein Journal of Organic Chemistry

New lithium-zincate approaches for the selective functionalisation of pyrazine: direct dideprotozincation vs. nucleophilic alkylation

(2011) Sharon E. Baillie et al.   CHEMICAL COMMUNICATIONS

Developing a Hetero-Alkali-Metal Chemistry of 2,2,6,6-Tetramethylpiperidide (TMP): Stoichiometric and Structural Diversity within a Series of Lithium/Sodium, Lithium/Potassium and Sodium/Potassium TMP Compounds

(2011) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

TMP-cadmiate: A Base for Efficient and Chemoselective Deprotonative Metallation Reactions of Aromatic Compounds

(2011) Florence Mongin et al.   CURRENT ORGANIC CHEMISTRY

After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne products

(2011) Elaine Crosbie et al.   DALTON TRANSACTIONS

Structurally Powered Synergic 2,2,6,6-Tetramethylpiperidine Bimetallics: New Reflections through Lithium-MediatedOrthoAluminations

(2011) Robert E. Mulvey et al.   INORGANIC CHEMISTRY

Ion Pair pKs of Some Amines: Extension of the Computed Lithium pK Scale

(2011) Andrew Streitwieser et al.   JOURNAL OF ORGANIC CHEMISTRY

Main Group Multiple C–H/N–H Bond Activation of a Diamine and Isolation of A Molecular Dilithium Zincate Hydride: Experimental and DFT Evidence for Alkali Metal–Zinc Synergistic Effects

(2011) Ross Campbell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-aryl pyrazoles: DFT calculations of CH acidity and deprotonative metallation using a combination of lithium and zinc amides

(2011) Floris Chevallier et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Structurally Stimulated Deprotonation/Alumination of the TMP Anion

(2010) Ben Conway et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structurally Engineered Deprotonation/Alumination of THF and THTP with Retention of Their Cycloanionic Structures

(2010) Elaine Crosbie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural elaboration of the surprising ortho-zincation of benzyl methyl ether

(2010) Liam Balloch et al.   CHEMICAL COMMUNICATIONS

Synergic Transformation of an Ethylenediamine to a Lithium 1,3-Diaza-2-zincacyclopentene via an Alkyllithium/Bis(alkyl)zinc Mixture

(2010) Ross Campbell et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sodium-Mediated Magnesiation of Thiophene and Tetrahydrothiophene: Structural Contrasts with Furan and Tetrahydrofuran

(2010) Victoria L. Blair et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structural Basis for Regioisomerization in the Alkali-Metal-Mediated Zincation (AMMZn) of Trifluoromethyl Benzene by Isolation of Kinetic and Thermodynamic Intermediates

(2010) David R. Armstrong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran

(2010) Robert E. Mulvey et al.   Nature Chemistry

Concerning the Structures of Alkali-Metal-MediatedorthoZincation of Benzamides and PhenylO-Carbamate

(2010) Liam Balloch et al.   ORGANOMETALLICS

Avant-Garde Metalating Agents: Structural Basis of Alkali-Metal-Mediated Metalation

(2009) Robert E. Mulvey   ACCOUNTS OF CHEMICAL RESEARCH

Aluminum Bases for the Highly Chemoselective Preparation of Aryl and Heteroaryl Aluminum Compounds

(2009) Stefan H. Wunderlich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct lateral metallation using alkali-metal mediated zincation (AMMZn): SiC–H vs.Si–O bond cleavage

(2009) Eva Hevia et al.   CHEMICAL COMMUNICATIONS

Synthetic and Structural Insights into the Zincation of Toluene: Direct Synergic Ring Metallation versus Indirect Nonsynergic Lateral Metallation

(2009) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates

(2009) William Clegg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergic Sedation of Sensitive Anions: Alkali-Mediated Zincation of Cyclic Ethers and Ethene

(2009) A. R. Kennedy et al.   SCIENCE

Deprotonative cadmation of functionalized aromatics

(2008) Jean-Martial L’Helgoual’ch et al.   CHEMICAL COMMUNICATIONS

Structural and Magnetic Insights into the Trinuclear Ferrocenophane and Unexpected Hydrido Inverse Crown Products of Alkali-Metal-Mediated Manganation(II) of Ferrocene

(2008) Victoria L. Blair et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Zincation of Functionalized Aromatics and Heterocycles by Using a Magnesium Base in the Presence of ZnCl2

(2008) Zhibing Dong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydride encapsulation by molecular alkali-metal clusters

(2008) Joanna Haywood et al.   DALTON TRANSACTIONS

A New Interpretation of the Reaction Pathway of Deprotonative Metalation with TMP−Zn-ate/TMEDA Complex [TMEDA·Na(μ-tBu)(μ-TMP)Zn(tBu)]

(2008) Daisuke Nobuto et al.   JOURNAL OF ORGANIC CHEMISTRY

Manganese(ii)–lithium and –sodium inverse crown ether (ICE) complexes

(2007) Alan R. Kennedy et al.   CHEMICAL COMMUNICATIONS